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Preparation process of special halogen-free flame-retardant master batch for polypropylene

A flame-retardant masterbatch and preparation technology, which is applied in the preparation process of polypropylene-specific halogen-free flame-retardant masterbatch, can solve the problems of difficult dispersion and low flame-retardant efficiency, and achieve the effect of easy dispersion and improved flame-retardant efficiency

Active Publication Date: 2015-04-29
江苏玖川纳米材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] In order to overcome the technical problems of the existing inorganic flame retardants in the prior art, which are not easy to disperse and have low flame retardant efficiency when applied to polypropylene, the inventors have conducted a lot of in-depth research, thus providing a special halogen-free flame retardant for polypropylene Preparation process of flame retardant masterbatch

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  • Preparation process of special halogen-free flame-retardant master batch for polypropylene

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Embodiment 1

[0026] This embodiment relates to a preparation process of a special halogen-free flame retardant masterbatch for polypropylene, including the following steps:

[0027] Step (1), after mixing attapulgite, montmorillonite and kaolinite raw ore in a weight ratio of 2:1:1, use a crusher to coarsely crush until the particle diameter is 3 ± 2mm to obtain a small particle mixture, and the The small particle mixture is sprayed with water to adjust the moisture content to 40 ± 3% by weight, and extruded with a three-roll mill with a distance of ≦ 2mm to obtain a flake mixture;

[0028] Step (2), stacking the flake mixture for more than 3 days, putting the flake mixture and water into a stainless steel beating tank at a weight ratio of 1:10, and then adding dispersing powder equivalent to 2% by weight of the flake mixture dispersant composition and antimony trioxide equivalent to 5% of the weight of the flake mixture, then beating, high-speed shearing for 2 hours, and high-pressure 70M...

Embodiment 2

[0034] This embodiment relates to a preparation process of a special halogen-free flame retardant masterbatch for polypropylene, including the following steps:

[0035] Step (1), after mixing attapulgite, montmorillonite and kaolinite raw ore in a weight ratio of 1:1:1, use a crusher to coarsely crush until the particle diameter is 3 ± 2mm to obtain a small particle mixture, and the The small particle mixture is sprayed with water to adjust the moisture content to 40 ± 3% by weight, and extruded with a three-roll mill with a distance of ≦ 2mm to obtain a flake mixture;

[0036] In step (2), the flake mixture is stacked for more than 4 days, and the flake mixture and water are put into a stainless steel beating tank at a weight ratio of 1:10, and then dispersing powder equivalent to 3% by weight of the flake mixture is added. dispersant composition and antimony trioxide equivalent to 3% of the weight of the flake mixture, then beating, high-speed shearing for 1 hour, and high-p...

Embodiment 3

[0042]This embodiment relates to a preparation process of a special halogen-free flame retardant masterbatch for polypropylene, including the following steps:

[0043] Step (1), after mixing attapulgite, montmorillonite and kaolinite raw ore in a weight ratio of 1.5:1:1, use a crusher to coarsely crush until the particle diameter is 3 ± 2mm to obtain a small particle mixture, and the The small particle mixture is sprayed with water to adjust the moisture content to 40 ± 3% by weight, and extruded with a three-roll mill with a distance of ≦ 2mm to obtain a flake mixture;

[0044] In step (2), the flake mixture is stacked for more than 5 days, and the flake mixture and water are put into a stainless steel beating tank at a weight ratio of 1:10, and then dispersing powder equivalent to 1% by weight of the flake mixture is added. dispersant composition and antimony trioxide equivalent to 4% of the weight of the flake mixture, then beating, high-speed shearing for 2 hours, and high...

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Abstract

The invention relates to a preparation process of a special halogen-free flame-retardant master batch for polypropylene. The preparation process comprises the following steps: (1) mixing attapulgite, montmorillonite and kaolinite raw ores, and carrying out coarse crushing, water spraying and extrusion, so as to obtain a sheet-shaped mixture; (2) pulping the sheet-shaped mixture, water, a dispersing agent composition and antimonous oxide, shearing, and carrying out high pressure homogenization, so as to obtain an emulsion; (3) dehydrating the emulsion, so as to obtain a cake material; (4) drying and crushing the cake material, adding cake material, grinding into powder, and carrying out air jet pulverization, so as to obtain a modified mineral composition; (5) mixing the modified mineral composition with polypropylene, injecting liquid paraffin, and uniformly mixing, so as to obtain a premix; and (6) fusing and granulating the premix, so as to obtain the master batch. According to the preparation process, the mineral composition is modified and is used as a flame retardant to be applied to polypropylene, so that the flame retardance efficiency of the halogen-free flame-retardant master batch is beneficially improved.

Description

technical field [0001] The invention relates to a preparation process of a halogen-free flame-retardant master batch, in particular to a preparation process of a halogen-free flame-retardant master batch special for polypropylene. Background technique [0002] PP has become one of the most widely used general-purpose plastics due to its excellent comprehensive performance, but its poor low-temperature toughness, non-wear resistance, easy aging, general heat resistance and flame retardancy limit its application in electronics, automobiles, construction, etc. , transportation and household appliances and other industries. Over the years, in order to improve the above-mentioned shortcomings of PP, polymer material workers have been working on toughening and flame-retardant modification of it. However, most flame retardants contain halogens, which generate a lot of smoke and pollute the environment when burned. Therefore, it is very necessary to seek a low-smoke, halogen-free ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L91/06C08K13/06C08K9/04C08K7/10C08K3/34C08K3/22C08K3/32C08J3/22
CPCC08J3/226C08J2323/12C08J2491/06C08K2201/014C08L23/12C08L2201/02C08L2201/22C08L91/06C08K13/06C08K9/04C08K3/346C08K3/2279C08K3/32C08K2003/324
Inventor 沈培友梁丽芹刘文霞严华海孟凡霞张善志李业伟郑礼根陈伟陈智
Owner 江苏玖川纳米材料科技有限公司