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A method for preparing dispersion-strengthened iron-based material by ultrasonic dispersion method

An iron-based material and dispersion strengthening technology, applied in the field of powder metallurgy, can solve the problems of easy pollution of oxide dispersion-strengthened iron-based materials, easy agglomeration of oxides, complex control process, etc., to achieve superior performance, simple preparation process, and dispersion effect Good results

Active Publication Date: 2017-01-11
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The present invention aims at the problems of easy pollution, complex control process, and easy agglomeration of oxides in the preparation of oxide dispersion-strengthened iron-based materials by existing mechanical alloying and chemical methods, and provides a method for preparing dispersion-strengthened iron-based materials by ultrasonic dispersion

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Preparation of 0.5(wt)%TiO 2 Dispersion strengthened iron-based materials, the process is as follows:

[0034] (1) Under ultrasonic conditions, TiO with particle size less than or equal to 10nm 2 Raw material powder (anatase type), added to the ethanol-free solution, and ultrasonically oscillated for 15 minutes to make TiO 2 The powder is evenly dispersed, and a suspension liquid with a raw material powder concentration of 18g / L is obtained, and the frequency of the ultrasonic wave is 30kHz;

[0035](2) While maintaining ultrasonic conditions, use a funnel to lift and release the iron-based powder with a particle size of less than or equal to 150 μm from the bottom of the vessel at a uniform speed, and spread it layer by layer into the prepared suspension liquid until the iron-based powder and the liquid surface In parallel, the mixture is obtained; in the process of powder feeding, the frequency and power of the original ultrasonic wave are maintained, so that the so...

Embodiment 2

[0039] Preparation of 1% (wt) Y 2 o 3 Dispersion strengthened iron, the process is:

[0040] (1) Configure Y with a concentration of 36g / L 2 o 3 Ethanol solution, where Y 2 o 3 The particle size is less than or equal to 30nm, and the prepared solution is ultrasonically oscillated by an ultrasonic instrument for 15 minutes to make the nanometer Y 2 o 3 Uniform dispersion; ultrasonic frequency is 40kHz;

[0041] (2) While maintaining ultrasonic conditions, use a funnel to spread the iron-based powder with a particle size of less than or equal to 75 μm into the prepared suspension liquid layer by layer at a constant speed from the bottom of the vessel until the upper surface of the iron-based powder reaches the height of the liquid level and is in contact with the The liquid surface is parallel; keep the ultrasonic oscillation for 10 minutes; then gradually reduce the ultrasonic frequency and power until the ultrasonic is stopped;

[0042] (3) Put the mixture prepared in ...

Embodiment 3

[0047] Preparation of 0.5(wt)% Y 2 o 3 Dispersion strengthened iron, the process is:

[0048] (1) Under ultrasonic conditions, the particle size is less than or equal to -10nm Y 2 o 3 The raw material powder is added to the absolute alcohol liquid, and ultrasonically oscillated for 15 minutes to make Y 2 o 3 The powder is evenly dispersed, and a suspension liquid with a raw material powder concentration of 18g / L is obtained, and the frequency of the ultrasonic wave is 30kHz;

[0049] (2) While maintaining ultrasonic conditions, use a funnel to spread the iron-based powder with a particle size of less than or equal to 75 μm into the prepared suspension liquid layer by layer from the bottom of the vessel at a constant speed until the upper surface of the iron-based powder reaches the liquid level and Parallel to the liquid surface to obtain a mixture; in the process of powder feeding, the frequency and power of the original ultrasonic wave should be maintained, so that the ...

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Abstract

The invention relates to a method for preparing a dispersion-strengthened iron-based material by adopting an ultrasonic dispersion method, belonging to the technical field of powder metallurgy. The method disclosed by the invention comprises the following steps of: putting a certain amount of nanometer oxide powder in alcoholic solution, uniformly dispersing by adopting ultrasonic wave, then, adding iron powder so that the upper surface of the iron powder achieves the height of the liquid level and is parallel to the liquid level, drying in vacuum by putting in a vacuum drying oven to obtain powder with uniformly dispersed nanometer oxide, pressing and forming the powder, sintering at high temperature in vacuum, hot rolling or hot forging so as to obtain a blocky material with uniformly dispersed oxide. By utilizing the simple and convenient ultrasonic dispersion method, nanometer oxide particles in the alcoholic solution are effectively depolymerised and uniformly dispersed, and adsorbed and precipitated on the surface of iron powder in the drying process, so that a uniform mixture is formed; and the method is simple to operate and good in oxide dispersion effect and is applied to large-scale industrial application.

Description

technical field [0001] The invention relates to a method for preparing a dispersion-strengthened iron-based material by using an ultrasonic dispersion method, and belongs to the technical field of powder metallurgy. Background technique [0002] Oxide dispersion strengthening is a very effective means to improve the strength and creep properties of metal materials. Mechanical alloying (MA) is the main method for preparing oxide dispersion strengthening materials, but this method has low production efficiency, high production cost, and is easy to pollute. . [0003] Aiming at the problems of the MA method, a series of methods for preparing oxide dispersion-strengthened materials have been developed. Chinese patent CN1664145A discloses a method for preparing oxide dispersion-strengthened ferrite alloys by chemical infiltration, using Y(NO 3 ) 3 ·6H 2 O solution infiltrates the pre-alloyed powder, after drying, hydrogen atmosphere protects and heats it to decompose into Y ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C33/02
Inventor 刘祖铭黄立清麻梦梅郭薇苏鹏飞陈仕奇
Owner CENT SOUTH UNIV