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Polyacrylate emulsion capable of postponing dye transfer and preparation method thereof

A technology of polyacrylate emulsion and hydroxyethyl acrylate, which is applied in the field of textile printing and dyeing, can solve the problems of affecting the water resistance of the emulsion film, serious dye migration, and low elongation at break, so as to delay dye migration, reduce solubility, Reduce the effect of migration

Active Publication Date: 2015-09-16
DONGGUAN CTL NEW MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage of this method is that the amount of sodium salt polymerizable emulsifier COPS-1 and SVS in the emulsification system is too high, which affects the water resistance of the emulsion film, and the dye migration of the emulsion film is serious in a humid environment; and HA, SIPOMER WAMⅡ, V-70M composed of one or more crosslinking systems, the emulsion prepared by it has slow self-crosslinking speed at room temperature and low elongation at break, which is not suitable for application in textile pigment printing

Method used

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  • Polyacrylate emulsion capable of postponing dye transfer and preparation method thereof
  • Polyacrylate emulsion capable of postponing dye transfer and preparation method thereof
  • Polyacrylate emulsion capable of postponing dye transfer and preparation method thereof

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Embodiment Construction

[0052] For better illustrating the present invention, facilitate understanding technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:

[0053] Embodiments 1 to 4 provide polyacrylate emulsions that delay dye migration, and the specific composition and content are as shown in Table 1:

[0054] The composition of the polyacrylate emulsion that table 1 embodiment 1~4 provides

[0055]

[0056]

[0057] Comparative Examples 1 to 4 provide comparative examples of polyacrylate emulsions that delay dye migration, and the specific composition and content are shown in Table 2:

[0058] The composition of the polyacrylate emulsion that table 2 comparative example 1~4 provides

[0059]

[0060]

[0061]

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Abstract

The invention relates to a polyacrylate emulsion capable of postponing dye transfer, which comprises an anti-dye-transfer functional monomer, a crosslinking monomer A, a crosslinking monomer B, a post-crosslinking monomer C, an anionic ammonium salt emulsifier, a sodium salt emulsifier, a polymerizable monomer, a buffering agent, an initiator, a post remover, a pH regulator and deionized water, wherein the crosslinking monomer B is any one or at least two of ethyl acetoacetate methacrylate and diacetone acrylamide; and the post-crossliking monomer C is any one or at least two of diamidohydrazine adipate and hexamethylendiamine. By using the polyacrylate emulsion capable of postponing dye transfer, the printing coat can not generate color spots or stripes due to dye transfer on terylene and other fabrics with severe dye transfer in the textile use period; and the polyacrylate emulsion can keep the color completeness of the coat, and has favorable application prospects in the fields of leather, textiles, paints and the like.

Description

technical field [0001] The invention belongs to the field of printing and dyeing of textiles, and in particular relates to a polyacrylate emulsion for delaying dye migration and a preparation method thereof. Background technique [0002] With the development of the textile industry, various pigment printings emerge in endlessly, and the quality is also uneven. Pigment printing uses adhesives to bond insoluble pigments and fillers to textiles to form coatings with different patterns and shapes. It has the advantages of convenient operation, complete color spectrum, energy saving and environmental protection. In the actual production process, when printing polyester and polyester / cotton fabrics, dye migration will occur during curing in the drying tunnel, which will cause yellow spots, black spots or other color patterns on the coating, which will seriously affect the printing coating. The appearance is commonly called "sublimation" in the printing material industry. The rea...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/18C08F220/06C08F222/02C08F220/28C08F220/58C08F220/14C08F220/46C08F2/26D06P1/52
Inventor 卢开平陈镜宏卢泽俭赵文爱
Owner DONGGUAN CTL NEW MATERIAL TECH
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