Extrusion molding preparation method of gradient material in static magnetic field
A technology of extrusion molding and gradient materials, which is applied in the direction of magnetic properties of inorganic materials, can solve the problems of sudden changes in composition, complexity, and difficulty in achieving continuous and uniform changes in material components, and achieve the effects of simplified procedures and reduced costs
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Embodiment 1
[0021] 1) Mud preparation
[0022] Combine strong magnetic metal Fe and weak magnetic ZrO in the mud refining machine 2 The ceramic mixed powder is added with organic solvent ethanol, dispersant herring oil and binder vinyl butyral, and uniformly mixed to obtain mud. The volume fraction of the organic solvent is 20% of the mud, the volume fraction of the dispersant is 0.2%, and the mass fraction of the adhesive is 10% of the mud;
[0023] 2) Extrusion molding in a static magnetic field
[0024] Extrude the mud in the extruder, the extrusion pressure is 0.2MPa, apply a static magnetic field at the extrusion port, and the magnetic field strength is 2T, and then obtain a green body;
[0025] 3) Drying and sintering
[0026] After drying at 20°C, sintering is carried out in a protective environment of argon at a sintering temperature of 1200°C, kept for 4 hours, and then cooled with the furnace.
Embodiment 2
[0028] 1) Mud preparation
[0029] Mix strong magnetic metal Co and weak magnetic SiC ceramic powder in a mud mill, add organic solvent methyl ethyl ketone, dispersant phosphate and binder polyvinyl alcohol, and mix uniformly to obtain mud. The volume fraction of the organic solvent is 30% of the mud, the volume fraction of the dispersant is 1%, and the mass fraction of the adhesive is 15% of the mud;
[0030] 2) Extrusion molding in a static magnetic field
[0031] Extrude the mud in the extruder, the extrusion pressure is 0.4MPa, apply a static magnetic field at the extrusion port, and the magnetic field strength is 1.2T, and then obtain a green body;
[0032] 3) Drying and sintering
[0033] After drying at 30°C, sintering is carried out in a nitrogen protective environment at a sintering temperature of 1300°C, kept for 4 hours, and then cooled with the furnace.
Embodiment 3
[0035] 1) Mud preparation
[0036] Strong magnetic metal Ni and weak magnetic Si 3 N 4 The ceramic mixed powder is added with organic solvent butanone, dispersant triolein and binder vinyl butyral, and uniformly mixed to obtain mud. The volume fraction of the organic solvent is 40% of the mud, the volume fraction of the dispersant is 2%, and the mass fraction of the adhesive is 20% of the mud;
[0037] 2) Extrusion molding in a static magnetic field
[0038] Extrude the mud in the extruder, the extrusion pressure is 0.5MPa, apply a static magnetic field at the extrusion port, and the magnetic field strength is 0.8T, and then obtain a green body;
[0039] 3) Drying and sintering
[0040] After drying at 40°C, sintering is carried out in a nitrogen protective environment at a sintering temperature of 1400°C, kept for 4 hours, and then cooled with the furnace.
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