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Selective water blocking agent made from oil residue or oily sludge and preparation method thereof

A water blocking agent and selective technology, applied in the field of selective water blocking agent and its preparation, can solve the problems of expensive extraction agent, secondary pollution, complicated operation, etc., to expand the swept volume of injected water, increase seepage resistance, The effect of simple preparation process

Active Publication Date: 2017-12-05
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The hot water washing process is easy to implement, low in investment costs, and can recover most of the oil products. It is difficult to deal with heavily emulsified oily sludge, which may cause secondary pollution. It is mainly suitable for landing oil sludge; the incineration method can reduce the amount to the greatest extent. Strong adaptability to raw materials, but high energy consumption, large equipment investment, high process technology requirements, generally low heat utilization rate, and there may be dust, SO 2 It is suitable for oily sludge with low water content and high oil content; the medium of thermal desorption method is completely inorganic, and hydrocarbons can be recycled, but the reaction conditions are relatively high and the operation is relatively complicated. Sludge with low water volume and high hydrocarbon content; solvent extraction method has high efficiency and thorough treatment, and most of the petroleum substances are extracted and recovered, but the extraction agent is expensive, there is some loss in the process, and the treatment cost is high. It is suitable for tank bottom sludge; The microbial treatment method has low energy consumption and low treatment cost, but the treatment cycle is long, the treatment effect on cycloalkanes, aromatics and heterocyclics is poor, it is difficult to adapt to high oily sludge, and resources cannot be reused. It is suitable for oil content less than 5% oily sludge
Due to the complex composition of oily sludge, no single treatment method can deal with all types of oily sludge

Method used

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  • Selective water blocking agent made from oil residue or oily sludge and preparation method thereof
  • Selective water blocking agent made from oil residue or oily sludge and preparation method thereof
  • Selective water blocking agent made from oil residue or oily sludge and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031] This embodiment provides a selective water shutoff agent made of oil residue. In terms of mass percentage, the raw materials for preparing the selective water shutoff agent are:

[0032] Oil residue: 20%, the oil residue has a sand content ratio of 10%, an oil content ratio of 20%, and a particle size of 10-100 μm;

[0033] Petroleum asphalt: 5%;

[0034] Cocamidopropyl Betaine: 0.2%;

[0035] Silok7007 (polyester hyperdispersant): 0.5%;

[0036] Rubber powder: 5%;

[0037] The balance is oilfield sewage.

[0038] The specific preparation process is:

[0039] (1) Heat the petroleum asphalt to 80-90°C to melt it;

[0040] (2) Cocamidopropyl betaine and hyperdispersant Silok7007 are added to the above-mentioned petroleum pitch, stirred evenly to obtain the first emulsion, and the stirring speed is 300r / min;

[0041] (3) adding oil residue and oilfield sewage into the above-mentioned first emulsion, stirring evenly to obtain the second emulsion;

[0042] (4) Add rub...

Embodiment 2

[0044] This embodiment provides a selective water shutoff agent that does not contain a hyperdispersant. In terms of mass percentage, the raw materials for preparing the selective water shutoff agent are:

[0045] Oil residue: 20%, the oil residue has a sand content ratio of 10%, an oil content ratio of 20%, and a particle size of 10-100 μm;

[0046] Petroleum asphalt: 5%;

[0047] Cocamidopropyl Betaine: 0.2%;

[0048] Rubber powder: 5%;

[0049] The balance is oilfield sewage.

[0050] The specific preparation process is:

[0051] (1) Heat the petroleum asphalt to 80-90°C to melt it;

[0052] (2) Cocamidopropyl betaine is added in the above-mentioned petroleum pitch, stir evenly, obtain the first emulsion, and stirring speed is 300r / min;

[0053] (3) adding oil residue and oilfield sewage into the above-mentioned first emulsion, stirring evenly to obtain the second emulsion;

[0054] (4) Add rubber powder to the above emulsion, and continue to stir for half an hour to ...

Embodiment 3

[0060] This embodiment provides a selective water shutoff agent made from oily sludge. In terms of mass percentage, the raw materials for preparing the selective water shutoff agent are:

[0061] Oily sludge: 30%, the oily sludge has a sand ratio of 20%, an oil ratio of 40%, and a particle size of 10-100 μm;

[0062] Coal tar pitch: 20%;

[0063] Lauramidopropyl Betaine: 1%;

[0064] Octylphenol polyoxyethylene ether OP-4 (polyether hyperdispersant): 2%;

[0065] Rubber powder: 10%;

[0066] The rest of the water.

[0067] The specific preparation process is:

[0068] (1) Heating the coal tar pitch to 80-90°C to melt it;

[0069] (2) Add lauryl amidopropyl betaine and hyperdispersant octylphenol polyoxyethylene ether OP-4 to the above-mentioned coal tar pitch, stir evenly to obtain the first emulsion, and the stirring speed is 300r / min;

[0070] (3) adding oily sludge and clear water to the above-mentioned first emulsion, stirring evenly to obtain a second emulsion;

[...

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Abstract

The invention provides a selective water blocking agent prepared from oil residues or sludge containing oil and a preparation method thereof. The selective water blocking agent is prepared from, by weight, 20-40% of the oil residues or the sludge containing oil, 5-20% of asphalt, 0.2-1% of an amphoteric surfactant, 0.5-2% of a super dispersing agent, 1-10% of solid-phase particles and the balance water. The selective water blocking agent prepared from the oil residues or the sludge containing oil has the advantages that the preparation technology is simple, raw material sources are wide, price is low, the selective water blocking agent is environmentally friendly, and the compatibility between the selective water blocking agent and a stratum is good. The selective water blocking agent is large in blocking strength, high in selective water blocking capacity, free of damage to an oil reservoir and a stratum and wide in application range of oil reservoir types.

Description

technical field [0001] The invention belongs to the field of oil-water well profile control and water shutoff, and in particular relates to a selective water shutoff agent made from oil residue or oily sludge and a preparation method thereof. Background technique [0002] Oil residue is the product of advanced treatment of oily sludge. Oily sludge refers to oil tanks, settling tanks, sewage tanks, bottom sludge of grease traps, oily water treatment facilities in refineries, light hydrocarbon processing plants, The oil sand and oil sludge removed by the natural gas purification device, the ground crude oil and oily sludge produced by drilling, operation, and pipeline perforation. When the oil storage tank is storing oil, a small amount of mechanical impurities, sand, soil, heavy metal salts, and heavy oily components such as paraffin and asphaltene in the oil deposit on the bottom of the oil tank to form sludge at the bottom of the tank. [0003] The oily sludge is huge, if ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/514
CPCC09K8/514
Inventor 陈小凯刘德铸王浩李瑞朱伟马昌明刘强吴赞美柳荣伟李俊萍阳小英石磊孙士馨陈同山刘海军
Owner PETROCHINA CO LTD
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