Method for synthesizing polycarboxylate superplasticizer through RAFT method
A technology of polycarboxylic acid and water reducing agent, applied in the field of polycarboxylic acid water reducing agent, can solve problems such as few research reports, and achieve the effects of high chain transfer efficiency, simple process and mild reaction conditions
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[0050] Example 1 Preparation of polycarboxylic acid water reducing agent
[0051] (1) Add 120g of TPEG macromonomer to the reaction kettle, add 117.5g of water, heat the reaction kettle to 80°C in a water bath, and continue to stir;
[0052] (2) 14.4g of acrylic acid and 40g of water are mixed uniformly, 2.256g of BDATT is added to the mixed solution to dissolve, and the mixture is dropped for 3h at a uniform speed;
[0053] (3) Dissolve 0.5424g of azobisisobutylamidine dihydrochloride in 20g of water, and start dropping the solution in step (2) at a uniform rate into the reaction kettle of step (1) at the same time, and the dropping time is 3h;
[0054] (4) After the dripping is finished, continue the constant temperature stirring reaction for 4h;
[0055] (5) After the reaction is over, add 30% NaOH aqueous solution and 10 g of water, and cool to room temperature to obtain the polycarboxylic acid water reducing agent.
Example Embodiment
[0056] Example 2 Preparation of polycarboxylic acid water reducing agent
[0057] (1) Add 120g of TPEG macromonomer to the reaction kettle, add 137.5g of water, heat the reaction kettle to 80°C in a water bath, and continue to stir;
[0058] (2) 14.4 g of acrylic acid and 30 g of water are mixed uniformly, 2.256 g of BDATT is added to the mixed solution to dissolve, and the mixture is added dropwise for 3 hours;
[0059] (3) Dissolve 0.2282g of ammonium persulfate in 20g of water, and start dropping the solution in step (2) at a uniform rate into the reaction kettle of step (1) at the same time, and the dropping time is 3h;
[0060] (4) After the dripping is finished, continue the constant temperature stirring reaction for 5 hours;
[0061] (5) After the reaction is completed, a 30% NaOH aqueous solution is added, and the mixture is cooled to room temperature to obtain a polycarboxylic acid water reducing agent.
Example Embodiment
[0062] Example 3 Preparation of polycarboxylic acid water reducing agent
[0063] (1) Add 120g of TPEG macromonomer to the reaction kettle, add 117.5g of water, heat the reaction kettle to 80°C in a water bath, and continue to stir;
[0064] (2) 14.4g of acrylic acid and 40g of water are mixed uniformly, 1.128g of BDATT is added to the mixed solution to dissolve, and the mixture is dropped for 3h at a uniform speed;
[0065] (3) 0.1356g of azobisisobutylamidine dihydrochloride was dissolved in 20g of water, and the solution in step (2) was simultaneously dropped into the reactor of step (1) at a uniform rate, and the dropping time was 3h;
[0066] (4) After the dripping is finished, continue the constant temperature stirring reaction for 5 hours;
[0067] (5) After the reaction, add 30% NaOH aqueous solution and 10 g of water, and cool to room temperature to obtain the polycarboxylic acid water reducing agent.
[0068] figure 1 The infrared spectra of PCE prepared in this example and PCE...
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