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A method for preparing soil conditioner with modified attapulgite as main raw material

A soil conditioner and main raw material technology, applied in soil conditioning materials, chemical instruments and methods, organic fertilizers, etc., can solve the problems of incomplete removal of harmful microorganisms, poor passivation effect of heavy metals, and increased investment costs, and achieve passivation. Long-term stable effect, abundant reserves, good effect

Active Publication Date: 2018-04-17
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the attapulgite in the natural mineral fertilizer has not been activated and has a poor passivation effect on heavy metals. In addition, the harmful microorganisms in the chicken manure may not be completely removed, and the collection of chicken manure is difficult, which will inevitably increase the investment cost.

Method used

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  • A method for preparing soil conditioner with modified attapulgite as main raw material
  • A method for preparing soil conditioner with modified attapulgite as main raw material
  • A method for preparing soil conditioner with modified attapulgite as main raw material

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preparation example Construction

[0036] Such as figure 2 A kind of preparation method of modified attapulgite of the present invention shown, it comprises the following steps:

[0037] (a) Place the attapulgite in a container, and then add 1 to 4 mol / l hydrochloric acid into the container, wherein the ratio of hydrochloric acid: attapulgite is 3:1 to 5:1 (ml:g);

[0038] (b) Place the above-mentioned attapulgite soaked in hydrochloric acid in a microwave field for microwave activation for 15-30 minutes, and the microwave power is 30-50w;

[0039] (c) Put the acidified and microwave-activated attapulgite into a rinsing device, and rinse with water until the pH of the washing water is 6-7;

[0040] (d) Suction filter the above-mentioned attapulgite that has been washed under the condition of vacuum degree of 0.05-0.08MPa;

[0041] (e) drying the attapulgite obtained by the above-mentioned suction filtration at 100-200° C., grinding and passing through a 100-300 mesh sieve to obtain a modified attapulgite.

...

Embodiment 1

[0057] Prepare the modified attapulgite, the specific steps are:

[0058] (a) Take 20g of attapulgite powder in a beaker, add 60mL-1mol / l hydrochloric acid;

[0059] (b) Place the attapulgite soaked in hydrochloric acid in a microwave field for microwave activation for 15 minutes, and the microwave power is 30w;

[0060] (c) Put the acidified and microwave-activated attapulgite into a rinsing device, and rinse with water until the washing water pH=7;

[0061] (d) Suction filter the above-mentioned attapulgite that has been washed under the condition of vacuum degree of 0.05MPa;

[0062] (e) The attapulgite obtained by the above suction filtration was dried at 100° C., ground and passed through a 100-mesh sieve to obtain a microwave acidified modified attapulgite.

[0063] Take the polluted soil and test the heavy metal content in the polluted soil: Cd-16.2mg / kg, Cu-191.3mg / kg, Hg-3.6mg / kg, Cr-340.7mg / kg, Zn-386.5mg / kg, As-56.9mg / kg, Pb-412.2mg / kg.

[0064] Mix the modifie...

Embodiment 2

[0074] Prepare the modified attapulgite, the specific steps are:

[0075] (a) Take 60g of attapulgite powder in a beaker, add 180mL-2mol / l hydrochloric acid;

[0076] (b) Place the attapulgite soaked in hydrochloric acid in a microwave field for microwave activation for 20 minutes, and the microwave power is 40w;

[0077] (c) Put the acidified and microwave-activated attapulgite into a rinsing device, and rinse with water until the washing water pH=6;

[0078] (d) Suction filter the above-mentioned attapulgite that has been washed under the condition of vacuum degree of 0.06MPa;

[0079] (e) The attapulgite obtained by the suction filtration was dried at 150°C, ground and passed through a 150-mesh sieve to obtain a modified attapulgite.

[0080] Take the polluted soil, after testing the heavy metal content in the soil: Cd-16.2mg / kg, Cu-191.3mg / kg, Hg-3.6mg / kg, Cr-340.7mg / kg, Zn-386.5mg / kg, As-56.9mg / kg, Pb-412.2mg / kg.

[0081] Mix the modified attapulgite prepared above w...

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Abstract

The invention discloses a method for preparing a modified attapulgite and a method for preparing a soil conditioner by using the modified attapulgite as a main raw material. The preparation method of the attapulgite comprises the following steps: (a) placing the attapulgite in a container, and then Add 1-4mol / l hydrochloric acid into the container; (b) place the above-mentioned attapulgite soaked in hydrochloric acid in a microwave field for microwave activation for 15-30min, and the microwave power is 30-50w; (c) put the above-mentioned acidified and microwaved The activated attapulgite is loaded into a rinsing device, and rinsed with water until the pH of the washing water is 6-7; (d) suction filtering the above-mentioned attapulgite that has been washed under the condition of a vacuum of 0.05-0.08MPa; (e) The attapulgite obtained by the suction filtration is dried at 100-200° C., ground and passed through a 100-300 mesh sieve to obtain a modified attapulgite. Can effectively improve the physical properties of soil.

Description

technical field [0001] The invention belongs to the field of environmental protection technology and agricultural fertilizer technology, more specifically, relates to a method for passivating heavy metals in soil by attapulgite modified by microwave acidification, and further relates to a preparation method of a novel agricultural fertilizer. Background technique [0002] With the rapid development of industry, the consequences of production and development activities on the soil environment are becoming more and more prominent. Soil heavy metal pollution has become a serious environmental problem. It will not only affect the development of agricultural production and food security, but also indirectly affect the safety of groundwater and other environmental elements closely related to human life. In addition, due to the long-term excessive application of chemical fertilizers and pesticides to the land, the natural ecosystem of the soil has been severely damaged, the soil la...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B33/40C09K17/00C09K101/00
Inventor 丁辉柯文静
Owner TIANJIN UNIV