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Polymer product and production method thereof, and polymer product producing apparatus

A manufacturing method and technology for manufacturing equipment, applied in chemical/physical/physical-chemical stationary reactors, etc., can solve the problems of polymer product durability and softening temperature deterioration, inability to obtain high molecular weight strong polymer products, etc. The effect of high melting point

Inactive Publication Date: 2015-12-23
RICOH KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, for the method of ring-opening polymerizing a ring-opening polymerizable monomer using a compressive fluid such as supercritical carbon dioxide, strong polymerization with a high molecular weight cannot be obtained if an organic catalyst that does not contain a metal atom is used as a catalyst. product, even by allowing the reaction to continue for a long time
There is also a problem that the durability and softening temperature of the polymer product can be deteriorated due to the influence of low molecular weight components

Method used

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  • Polymer product and production method thereof, and polymer product producing apparatus
  • Polymer product and production method thereof, and polymer product producing apparatus
  • Polymer product and production method thereof, and polymer product producing apparatus

Examples

Experimental program
Comparison scheme
Effect test

no. 1 approach

[0189] Figure 4 with Figure 5 is a system diagram showing an example of an aggregation step. exist Figure 4 In the system diagram of , the polymerization reaction apparatus 100 includes a supply unit 100a configured to supply a ring-opening polymerizable monomer and a compressive fluid, and a polymer product configured to polymerize the ring-opening polymerizable monomer supplied by the supply unit 100a A polymerization reaction apparatus main body 100b of an example of an apparatus is manufactured. The supply unit 100a comprises tanks (1, 3, 5, 7, 11), metering feeders (2, 4), and metering pumps (6, 8, 12). The polymerization reaction apparatus main body 100b includes: a contact area 9 provided at one end portion of the polymerization reaction apparatus main body 100b, a liquid delivery pump 10, a reaction area 13, a metering pump 14, and the other end portion of the polymerization reaction apparatus main body 100b Extruding cap (extrudingcap) 15 at.

[0190] The tank...

no. 2 approach

[0219] [Second Embodiment] (Application Example)

[0220] Next, a second embodiment that is an application example of the first embodiment will be explained. In the production method of the first embodiment, almost no ring-opening polymerizable monomer remains and the reaction proceeds quantitatively. Based on this, the first method of the second embodiment is to synthesize a polymer by using the polymer product produced by the production method of the first embodiment and by appropriately setting the timing of adding one or more ring-opening polymerizable monomers product. The second method of the second embodiment will be by using two or more polymers including the polymer product produced by the production method of the first embodiment and by combining the two or more polymer products Complexes are formed by continuous mixing in the presence of a compressive fluid. In this embodiment, "composite" means a copolymer comprising two or more polymer segments obtained by poly...

no. 3 approach

[0250] Next, the polymerization reaction apparatus 400 used in the batch type process will be explained. exist Figure 8 In the system pipeline diagram shown in , the polymerization reaction equipment 400 includes a tank 121 , a metering pump 122 , an adding pot (adding pot) 125 , a reaction vessel 127 , and valves ( 123 , 124 , 126 , 128 , 129 ). These devices are passed through the pressure pipe 130 such as Figure 8 Connect as shown in. The tube 130 is provided with joints (130a, 130b).

[0251] Tank 121 stores compressive fluid. The tank 121 can store a gaseous substance (gas) or a solid that becomes a compressive fluid through a path through which it is supplied to the reaction vessel 127 ; become a compressive fluid. In this case, the gaseous substance or solid stored in the tank 121 becomes image 3 (1), (2), or (3) states of the phase diagram.

[0252] The metering pump 122 supplies the compressive fluid stored in the tank 121 to the reaction vessel 127 at a con...

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Abstract

Provided is a polymer product that has a melting point difference (Tm1-Tm0) of 3 DEG C or more between a polymer melting point Tm0 before it is heated and a polymer melting point Tm1 after it is heated under a nitrogen atmosphere for 60 minutes at a temperature that is higher than the highest polymer melting point by from 10 DEG C to 50 DEG C.

Description

technical field [0001] The present invention relates to a polymer product, a method for producing the polymer product, and an apparatus for producing the polymer product. Background technique [0002] Conventionally, various polymers have been produced by ring-opening polymerizing a ring-opening polymerizable monomer. For example, polylactic acid is produced by ring-opening polymerization of lactide, which is an example of a ring-opening polymerizable monomer. The produced polylactic acid is used, for example, in fabrics for sutures, sheets for biocompatible materials, particles for cosmetics, and films for plastic bags. [0003] As a method of producing a polymer by ring-opening polymerization of such a ring-opening polymerizable monomer, there is a method of reacting the ring-opening polymerizable monomer in its molten state. For example, as a method of producing polylactic acid by ring-opening polymerization of lactide, a method of polymerizing lactide by polymerizing i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G63/08C08G63/78
CPCC08G63/785B01J19/24B01J2219/00051B01J2219/24C08G63/08C08G63/78C08G63/88
Inventor 新井阳子根本太一森田竜也镰田靖男和泉贤田中千秋今永之弘
Owner RICOH KK