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High-gloss spraying-free ABS (acrylonitrile butadiene styrene) composite material with special effect and preparation method thereof

A composite material and special effect technology, which is applied in the field of high-gloss spray-free ABS composite material and its preparation, can solve problems affecting production efficiency, affecting metal effects, and being easily damaged by shearing, achieving good lubrication and wetting effects, and improving Glossiness, the effect of reducing the number of cuts

Inactive Publication Date: 2015-12-30
SILVER AGE ENG PLASTICS DONGGUAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although this preparation method effectively solves the problem of flow marks that are easily produced when traditional aluminum powder pigments are introduced into the plastic matrix on the basis of maintaining a good metallic luster, the preparation of coated aluminum powder block pigments by double-roll mixing The method is complicated, new equipment needs to be added, and the investment is large. At the same time, the aluminum powder is easily broken and damaged by twin-screw shearing, which affects the metal effect.
[0005] Kingfa Science and Technology patent CN104629245A discloses a spray-free ABS composition with special aesthetic effects and its preparation method and application. In this patent, the special effect powder is coated with an aqueous polymer dispersion into microspheres and then dispersed into ABS resin , although the compatibility of special effect powder and ABS resin is obviously improved, the flow mark formed on the surface of the product during extrusion or injection molding is eliminated, and the weld line is lightened, but the special effect powder is coated with a water-based polymer dispersion into a micro The preparation process of the ball is complicated, which affects the production efficiency

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] A kind of high-gloss spray-free ABS composite material with special effects in this embodiment includes the following raw material components in parts by weight:

[0048] ABS resin 88.1 parts

[0049] 4.0 parts of compatibilizer

[0050] Toughener 5.0 parts

[0051] White oil 1.0 part

[0052] Composite antioxidant 0.4 parts

[0053] Lubricant 0.5 parts

[0054] 1.0 parts of pearl powder;

[0055] Among them, the ABS resin is a terpolymer MABS of methyl methacrylate (M), butadiene (B) and styrene (S), the brand is TR557, LG Chemical Co., Ltd.; the compatibilizer is a core-shell structure Silicone-acrylic acid copolymer, the grade is S2200, Mitsubishi Rayon (Shanghai) Management Co., Ltd.; the toughening agent is 60 μm in particle size, the glue content is 50% high rubber powder, the grade is MAG50, Styrolution Polymer Materials Co., Ltd.; white The oil has a kinematic viscosity of 10m 2 Industrial grade No. 15 white oil of / s, Shenzhen Kaipu Lubrication Technolog...

Embodiment 2

[0061] A kind of high-gloss spray-free ABS composite material with special effects in this embodiment includes the following raw material components in parts by weight:

[0062] ABS resin 83.5 parts

[0063] 6.0 parts of compatibilizer

[0064] Toughening agent 6.0 parts

[0065] 1.5 parts white oil

[0066] Composite antioxidant 0.4 parts

[0067] Lubricant 0.6 parts

[0068] 2.0 parts of pearl powder;

[0069] Wherein said toughening agent is particle diameter 60 μm, glue content 55% high rubber powder; The kinematic viscosity of white oil is 11m 2 / s; the particle size of pearlescent powder is 150μm, and the thickness is 4μm. The rest of the raw materials in this embodiment are the same as those in Embodiment 1, and will not be repeated here.

[0070] The preparation method of the high-gloss spray-free ABS composite material with special effects of the present embodiment comprises the following steps:

[0071] Step A, put the ABS resin, compatibilizer, composite ant...

Embodiment 3

[0075] A kind of high-gloss spray-free ABS composite material with special effects in this embodiment includes the following raw material components in parts by weight:

[0076] ABS resin 77.7 parts

[0077] 8.0 parts of compatibilizer

[0078] Toughener 7.0 parts

[0079] White oil 2.0 parts

[0080] Composite antioxidant 0.6 part

[0081] Lubricant 0.7 parts

[0082] 3.0 parts of pearl powder;

[0083] Wherein said toughening agent is particle diameter 60 μ m, glue content 60% high rubber powder; The kinematic viscosity of white oil is 12m 2 / s; the particle size of pearlescent powder is 200μm, and the thickness is 5μm. The rest of the raw materials in this embodiment are the same as those in Embodiment 1, and will not be repeated here.

[0084] The preparation method of the high-gloss spray-free ABS composite material with special effects of the present embodiment comprises the following steps:

[0085] Step A, put the ABS resin, compatibilizer, composite antioxidan...

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Abstract

The invention relates to the technical field of polymer materials, in particular to a high-gloss spraying-free ABS (acrylonitrile butadiene styrene) composite material with special effect and a preparation method thereof. The composite material comprises, by weight: 70-90 parts of ABS resin, 4.0-10 parts of a compatilizer, 5.0-10 parts of a toughener, 1.0-3.0 parts of white oil, 0.4-0.6 part of a composite antioxidant, 0.5-1.0 part of a lubricant, and 1.0-5 parts of pearl powder. The preparation method is simple, and the prepared ABS composite material has good mechanical properties, low aid emigration rate, significant pearl effect, smooth surface free of flow marks and scratch resistant, and long service life.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a high-gloss spray-free ABS composite material with special effects and a preparation method thereof. Background technique [0002] As people pay more and more attention to environmental issues, countries around the world have introduced strict environmental protection regulations for home appliances and other major environments, coupled with the embodiment of corporate social responsibility, spray-free material products are gradually showing their competitiveness, spray-free aesthetics Resin can reproduce the bright and colorful hues produced by spray paint and special effects such as pearlescent, glittering, metallic luster and texture, so as to meet the needs of customers whose product design trends are differentiation, personalization, diversification and differentiation, and in the production process It can really reduce the production process, improve the rate of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/04C08L33/20C08L91/06C08L21/00C08L23/08C08L35/06C08L25/14C08K13/02C08K5/134C08K5/526C08K5/098C08K5/103C08K5/09
Inventor 李小辉唐昌伟傅轶
Owner SILVER AGE ENG PLASTICS DONGGUAN
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