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Preparation method for core composite carbon electrode material of double-electric-layer capacitor

A technology of electric double layer capacitors and electrode materials, which is applied in the preparation of electrode materials and the preparation of sandwich composite carbon electrode materials, can solve the problems of large van der Waals force and loss of specific surface area, and achieve high rate performance, low internal resistance, abundant The effect of the pore structure

Active Publication Date: 2016-01-20
NINGBO CRRC NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the huge van der Waals force, the stacking of graphene sheets is easy to occur, resulting in a loss of specific surface area.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The particle diameter is 5μm, the specific surface area is 2500m 2 Activated carbon per gram was dispersed in an aqueous solution with a SDBS concentration of 1%, and dispersed by ultrasonic to obtain a uniform activated carbon suspension with a concentration of 10 g / mL. At the same time, the size is 10μm, the specific surface area is 1500m 2 / g of graphene oxide was dispersed in deionized water to obtain a graphene oxide suspension with a concentration of 10 g / mL. Then, the activated carbon suspension and the graphene oxide suspension are mixed to obtain a mixed suspension, and the mass ratio of the activated carbon to the graphene oxide in the mixed suspension is 1.5:1. The mixed suspension was stirred for 3 hours, so that the graphene oxide and activated carbon were fully mixed, and the two were interlaced to form a sandwich composite structure. Then filter, wash with deionized water for 5 times, and dry at 80° C. for 24 hours to obtain a composite of activated car...

Embodiment 2

[0038] The particle diameter is 4μm, the specific surface area is 2000m 2 Activated carbon per gram was dispersed in an aqueous solution with a SDBS concentration of 1%, and dispersed by ultrasonic to obtain a uniform activated carbon suspension with a concentration of 10 g / mL. At the same time, the size is 10μm, the specific surface area is 1500m 2 / g of graphene oxide was dispersed in deionized water to obtain a graphene oxide suspension with a concentration of 10 g / mL. Then, the activated carbon suspension and the graphene oxide suspension are mixed to obtain a mixed suspension, and the mass ratio of the activated carbon to the graphene oxide in the mixed suspension is 3:1. The mixed suspension was stirred for 3 hours, so that the graphene oxide and activated carbon were fully mixed, and the two were interlaced to form a sandwich composite structure. Then filter, wash with deionized water for 5 times, and dry at 80° C. for 24 hours to obtain a composite of activated carbon...

Embodiment 3

[0040] The particle diameter is 3μm, the specific surface area is 1800m 2 Activated carbon per gram was dispersed in an aqueous solution with a SDBS concentration of 1%, and dispersed by ultrasonic to obtain a uniform activated carbon suspension with a concentration of 10 g / mL. At the same time, the size is 10μm, the specific surface area is 1500m 2 / g of graphene oxide was dispersed in deionized water to obtain a graphene oxide suspension with a concentration of 10 g / mL. Then, the activated carbon suspension and the graphene oxide suspension are mixed to obtain a mixed suspension, and the mass ratio of the activated carbon to the graphene oxide in the mixed suspension is 5:1. The mixed suspension was stirred for 3 hours, so that the graphene oxide and activated carbon were fully mixed, and the two were interlaced to form a sandwich composite structure. Then filter, wash with deionized water for 5 times, and dry at 80° C. for 24 hours to obtain a composite of activated carbo...

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Abstract

The invention relates to a preparation method for a core composite carbon electrode material of a double-electric-layer capacitor, and belongs to the technical field of electrode material preparation. The method comprises the steps: dispersing activated carbon in an aqueous solution and obtaining activated carbon suspension liquid, wherein the surface active agent concentration is 0.1%-3%; enabling oxidized graphene to be dispersed in deionized water, and obtaining oxidized graphene suspension liquid; mixing the activated carbon suspension liquid and the oxidized graphene suspension liquid, obtaining a mixed suspension liquid, stirring and drying the mixed suspension liquid, obtaining a composite of activated carbon and oxidized graphene; mixing the composite with alkali for pore forming, reducing the oxidized graphene, carrying out neutral reaction through acid, carrying out filtering and drying, and obtaining the core composite carbon electrode material. The method is high in universality. When the prepared core composite carbon electrode material is used as the electrode material of the double-electric-layer capacitor, the material has high mass specific capacity and volume specific capacity, is low in internal resistance, and is high in rate capability.

Description

technical field [0001] The invention relates to a preparation method of an electrode material, in particular to a preparation method of a sandwich composite carbon electrode material used for an electric double layer capacitor, and belongs to the technical field of electrode material preparation. Background technique [0002] An electric double layer capacitor is a device that stores energy through physical adsorption. It has the advantages of high power density and long service life. It can be used in transportation, energy storage equipment, and heavy machinery start-up. However, compared with lithium-ion batteries, there is still a certain gap in the energy density of supercapacitors. [0003] Activated carbon is currently the most important commercial electrode material, which has the structural advantages of large specific surface area and rich pore structure, and exhibits high specific capacity when used as an electrode material. But at the same time, activated carbon...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/24H01G11/38H01G11/86
CPCY02E60/13
Inventor 阮殿波崔超婕乔志军
Owner NINGBO CRRC NEW ENERGY TECH CO LTD