Heavy oil aquathermolysis catalytic viscosity reducer and preparation method thereof

A catalytic viscosity reduction and thermal cracking technology, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of poor thermal stability, low effective rate, and inability to achieve ideal viscosity reduction effects of viscosity reducers, and achieve a solution Poor viscosity reduction effect, viscosity reduction, good viscosity reduction effect

Active Publication Date: 2016-03-02
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When organic ferric sulfonate or organic copper sulfonate of transition metal ions reacts with heavy oil under hydrothermal catalysis, due to the high temperature of thermal recovery of heavy oil, the viscosity reducer has poor thermal stability and low efficiency. Most of the current catalytic viscosity reducers cannot Achieve ideal viscosity reduction effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] This embodiment provides a heavy oil aquathermolysis catalytic viscosity reducer, which is prepared by the following steps:

[0030] Weigh 6.52g of dodecylbenzenesulfonic acid and place it in a container, add 40mL of distilled water, and stir at 30°C for 10min to obtain a milky white viscous liquid dodecylbenzenesulfonic acid solution;

[0031] Weigh 2.16g of o-phenylenediamine and place it in a container, and continue stirring at 70°C for 1-3h to obtain a brown thick intermediate product;

[0032] Weigh 2.50 g of copper sulfate pentahydrate and place it in a beaker, add 20 mL of distilled water to dissolve;

[0033] Add the dissolved copper sulfate solution into the container and continue to react for 2h-4h to obtain a dark brown thick precipitate. Stop the reaction and wait for cooling to room temperature for filtration. The precipitate is placed in a vacuum drying oven and dried at 30°C-50°C for 3h-5h to obtain Copper-centered dual-ligand catalytic viscosity reducer...

Embodiment 2

[0039] This embodiment provides a heavy oil aquathermolysis catalytic viscosity reducer, which is prepared by the following steps:

[0040] Weigh 7.82g of dodecylbenzenesulfonic acid and place it in a container, add 40mL of distilled water, and stir at 30°C for 10min to obtain a milky white viscous liquid dodecylbenzenesulfonic acid solution;

[0041] Weigh 2.16g of o-phenylenediamine and place it in a container, and continue to stir at 90°C for 1-3h to obtain a brown thick intermediate product;

[0042] Weigh 2.50 g of copper sulfate pentahydrate and place it in a beaker, add 20 mL of distilled water to dissolve;

[0043] Add the dissolved copper sulfate solution into the container and continue the reaction for 2-4 hours to obtain a dark brown thick precipitate. Stop the reaction and wait for cooling to room temperature to filter. The precipitate is placed in a vacuum drying oven and dried at 30°C-50°C for 3-5h to obtain Catalytic viscosity reducer for aquathermolysis of hea...

Embodiment 3

[0048] This embodiment provides a heavy oil aquathermolysis catalytic viscosity reducer, which is prepared by the following steps:

[0049] Weigh 9.78g of dodecylbenzenesulfonic acid into a container, add 40mL of distilled water, and stir at 30°C for 10min to obtain a milky white viscous liquid dodecylbenzenesulfonic acid solution;

[0050] Weigh 2.16g of o-phenylenediamine and place it in a container, and continue stirring at 110°C for 1-3h to obtain a brown thick intermediate product;

[0051] Weigh 5.0 g of copper sulfate pentahydrate and place it in a beaker, add 20 mL of distilled water to dissolve;

[0052] Add the dissolved copper sulfate solution into the container and continue the reaction for 2-4 hours to obtain a dark brown thick precipitate. Stop the reaction and wait for cooling to room temperature to filter. The precipitate is placed in a vacuum drying oven and dried at 30°C-50°C for 3-5h to obtain Catalytic viscosity reducer for aquathermolysis of heavy oil with ...

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Abstract

The invention provides a heavy oil aquathermolysis catalytic viscosity reducer and a preparation method thereof. The heavy oil aquathermolysis catalytic viscosity reducer comprises o-phenylenediamine, dodecylbenzene sulfonic acid and a transition metal sulfate in a mass mole ratio of 1:0.5-1.5:0.5-1.5. The heavy oil aquathermolysis catalytic viscosity reducer is prepared by the steps of: dissolving dodecylbenzene sulfonic acid in water to obtain a dodecylbenzene sulfonic acid solution with a concentration of 0.5mol / L-1.2mol / L; at 70-110DEG C, adding o-phenylenediamine into the dodecylbenzene sulfonic acid solution to obtain an intermediate product; dissolving the transition metal sulfate in water to obtain a transition metal sulfate solution with a concentration of 0.5mol / L-0.9mol / L; and adding the transition metal sulfate solution into the intermediate product, carrying out reaction at 70DEG C-110DEG C for 2h-4h, and performing vacuum drying to obtain the heavy oil aquathermolysis catalytic viscosity reducer. The heavy oil aquathermolysis catalytic viscosity reducer provided by the invention has better temperature resistance, and can reach more excellent cracking viscosity reducing effect.

Description

technical field [0001] The present invention relates to a heavy oil hydrothermal cracking catalytic viscosity reducer and its preparation method, in particular to a heavy oil hydrothermal cracking catalytic viscosity reducer with double ligands centered on a transition metal and its preparation method, which belongs to the catalytic viscosity reducer technology field. Background technique [0002] With the continuous development of the global economy, conventional oil resources are becoming less and less, and heavy oil, as a potential unconventional energy source, has attracted more and more attention. Considering the current situation of conventional oil exploitation and heavy oil reserves, it can be predicted that heavy oil will occupy an extremely important position in the future national energy strategy. [0003] The hydrothermal cracking catalytic viscosity reduction technology for heavy oil recovery is to inject high-temperature steam into the oil layer and add hydrot...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/592
CPCC09K8/592
Inventor 龚姚进户昶昊宫宇宁韩冰孙念焦春宇尚策庄丽吴迪楠
Owner PETROCHINA CO LTD
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