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Preparation method for lithium cobalt oxide silver-doped composite positive electrode material

A composite cathode material, lithium cobalt oxide technology, applied in the field of lithium ion batteries, can solve the problems of low rate discharge performance and electrical conductivity, and achieve the effects of low cost, improved service life, and improved discharge rate

Inactive Publication Date: 2016-04-13
CHANGZHOU CHANGYU PRACTICAL GAS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention: Aiming at the current problem of low rate discharge performance and low electrical conductivity, lithium manganate and other materials are used to externally coat it, but this problem cannot be fundamentally solved, and a silver mirror reaction is provided. The metal silver is doped into cobalt salt and lithium salt and other substances, and the molten mixture formed under high temperature conditions can change the internal structure of its lithium cobalt oxide composite positive electrode material and improve its rate discharge performance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0018] First, put 15 mL of silver nitrate with a mass fraction of 2% in a test tube, shake the test tube, and slowly add ammonia water with a mass fraction of 3% to it while shaking until the silver nitrate is completely dissolved in the ammonia water, then stop the dripping After the dropwise addition of ammonia water is completed, formaldehyde with 15% silver nitrate mass is slowly passed into it, and the test tube is placed in a water bath for heating at a temperature of 70°C. After reacting for 2 hours, filter it to obtain the filtrate metallic silver , and carry out drying and dehydration to it to obtain dry metal silver for subsequent use; then take 40g of lithium hydroxide and 80g of cobalt nitrate and mix it in deionized water with 1 times the total mass of the mixture, and stir it until it dissolves completely In deionized water, add aqua regia with 40% mass fraction of the mixture to it, stir and heat up to 50°C, and react for 45min. The aqua regia is composed of 95% ...

example 2

[0020] First, put 10 mL of silver nitrate with a mass fraction of 2% in a test tube, shake the test tube, and slowly add ammonia water with a mass fraction of 3% to it while shaking until the silver nitrate is completely dissolved in the ammonia water, and then stop the dripping Ammonia water, after the dropwise addition is completed, then slowly pass into it formaldehyde with 10% silver nitrate mass, and place the test tube in a water bath for heating at a temperature of 60°C. After reacting for 1 hour, filter it to obtain the filtrate metallic silver , and carry out drying and dehydration to it to obtain dry metallic silver for subsequent use; then take 30g of lithium hydroxide and 70g of cobalt nitrate and mix them in deionized water with 1 times the total mass of the mixture, and stir it until it dissolves completely In deionized water, add aqua regia with 30% mass fraction of the mixture to it, stir and heat up to 40°C, and react for 45min. The aqua regia is composed of 95...

example 3

[0022]First, put 12 mL of silver nitrate with a mass fraction of 2% in a test tube, shake the test tube, and slowly add ammonia water with a mass fraction of 3% to it while shaking until the silver nitrate is completely dissolved in the ammonia water, and then stop the dripping After the dropwise addition of ammonia water is completed, formaldehyde with 12% silver nitrate mass is slowly passed into it, and the test tube is placed in a water bath for heating at a temperature of 65°C. After reacting for 1 hour, filter it to obtain the filtrate metallic silver , and carry out drying and dehydration to it to obtain dry metallic silver for subsequent use; then take 35g of lithium hydroxide and 75g of cobalt nitrate, mix them in deionized water with 1 times the total mass of the mixture, and stir it until it dissolves completely In deionized water, add aqua regia with 30% mass fraction of the mixture to it, stir and heat up to 45°C, and react for 42min. The aqua regia is composed of ...

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Abstract

The invention relates to a preparation method for a lithium cobalt oxide silver-doped composite positive electrode material, and belongs to the technical field of a lithium ion battery. The preparation method comprises the steps of preparing metal silver through a silver mirror reaction for use; adding a water solution of cobalt salt and lithium salt into nitrohydrochloric acid, and then adding urea, warming and stirring, and filtering; performing high-temperature calcining on the filtered product in a muffle furnace until the filtered product is in a molten state, and uniformly paving the prepared metal silver on the surface of the product; continuing to heat for warming, and cooling; smashing the obtained product into powder, and then soaking the powder in perchloric acid; and washing the soaked powder by deionized water, and drying to obtain the lithium cobalt oxide silver-doped composite positive electrode material. The preparation method has the beneficial effects that the rate discharge speed of the prepared lithium cobalt oxide silver-doped composite positive electrode material is improved by 15-20%, the specific discharge capacity can reach 150-170mAh / g, and the service life can be improved by more than one time.

Description

technical field [0001] The invention relates to a preparation method of a lithium cobalt oxide doped silver composite cathode material, belonging to the technical field of lithium ion batteries. Background technique [0002] Lithium cobaltate, with the chemical formula LiCoO2, is an inorganic compound generally used as a positive electrode material for lithium-ion batteries. Generally used for lithium-ion secondary battery cathode materials, liquid phase synthesis process, it uses polyvinyl alcohol (PVA) or polyethylene glycol (PEG) aqueous solution as solvent, lithium salt, cobalt salt are dissolved in PVA or PEG aqueous solution respectively, The mixed solution is heated and concentrated to form a gel, and the resulting gel is heated and decomposed, then calcined at a high temperature, and the calcined powder is ground and sieved to obtain lithium cobaltate powder. [0003] For the commonly used lithium cobalt oxide materials, the larger the particles, the greater the com...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/525H01M10/0525H01M4/62
CPCH01M4/362H01M4/525H01M4/626H01M10/0525Y02E60/10
Inventor 陈蓉蓉雷国庆
Owner CHANGZHOU CHANGYU PRACTICAL GAS