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Application of sulfide electrolyte in preparing all-solid-state battery

A sulfide electrolyte, all-solid-state battery technology, applied in non-aqueous electrolyte battery electrodes, secondary batteries, circuits, etc., can solve problems such as difficult to apply all-solid-state battery production processes

Inactive Publication Date: 2016-04-13
CHINA AUTOMOTIVE BATTERY RES INST CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, there are very few solvent-binder systems suitable for sulfur-based electrolytes, and the traditional wet coating process for preparing lithium batteries is difficult to apply to the production process of all-solid-state batteries based on sulfur-based electrolytes.
In addition, problems such as toxicity, removal and recovery brought about by the use of organic solvents also put forward higher requirements on production conditions

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Prepare the positive electrode layer according to the following steps:

[0057] (1) LiCoO 2 、70Li 2 S-30P 2 S 5 Glass-ceramic electrolyte, multi-walled carbon nanotubes and polytetrafluoroethylene powder (PTFE) are fully mixed in a ball mill at a mass ratio of 65:25:5:5 to obtain a positive electrode mixed dry powder;

[0058] (2) Fully grind the positive electrode mixed dry powder to cause fibrosis and vibration of PTFE, so that the mixed dry powder particles are bonded together to act as a binder to obtain a black sticky powder;

[0059] (3) Pressing the viscous powder at 150° C. to obtain a foil-shaped positive electrode layer.

Embodiment 2

[0061] Prepare the positive electrode layer according to the following steps:

[0062] (1) The ternary 532, the electrolyte 5Li 2 S-GeS 2 -P 2 S 5 (i.e. Li 10 GeP 2 S 12 ), carbon nanotubes and polytetrafluoroethylene powder (PTFE) are fully mixed in a pulverizer with a mass ratio of 55:35:5:5 to obtain anode mixed dry powder;

[0063] (2) Fully grind the mixed dry powder of the positive electrode to obtain a black viscous powder;

[0064] (3) Pressing the viscous powder at 150° C. to obtain a foil-shaped positive electrode layer.

Embodiment 3

[0066] Prepare the electrolyte layer as follows:

[0067] (1) Will 75Li 2 S-25P 2 S 5 The glass-ceramic state electrolyte and ethylene-tetrafluoroethylene copolymer (ETFE) are fully mixed in a vibrating mill at a mass ratio of 98:2 to obtain a mixed dry powder of the electrolyte layer;

[0068] (2) Fully grind the dry powder mixed with the electrolyte layer to obtain a white viscous powder;

[0069] (3) Pressing the viscous powder at 150° C. to obtain a foil-shaped electrolyte layer.

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Abstract

The invention relates to an application of a sulfide electrolyte in preparing an all-solid-state battery. The application specifically comprise the steps of mixing a raw material comprising the sulfide electrolyte and a binder to obtain mixed dry powder; fully grinding the mixed dry powder into viscous powder, and compressing and shaping. According to the invention, the all-solid-state battery prepared from the sulfide electrolyte is further protected, wherein the all-solid-state battery comprises a positive electrode layer, an electrolyte layer, a negative electrode layer or / and a cell consisting of the positive electrode layer, the electrolyte layer and the negative electrode layer. According to the application method and the sulfide electrolyte based all-solid-state battery, the all-solid-state battery is free of any solvent, so that the condition that performance of the solid electrolyte is damaged due to a reaction between the solvent and the sulfide electrolyte is avoided; meanwhile, influences from toxic organic solvents, and troublesome processes for removing and recycling the toxic organic solvents are avoided; and in addition, the application is simple in operation method and easy to implement.

Description

technical field [0001] The invention relates to the technical field of lithium batteries, in particular to a construction method of an all-solid positive electrode layer, an electrolyte layer and a negative electrode layer, and an all-solid-state battery. Background technique [0002] In recent years, with the popularization of portable electronic devices (such as smart phones, personal computers, and cameras, etc.), especially low-pollution, non-polluting electric vehicles and hybrid vehicles have been included in the national strategic plan, lithium-ion batteries as their core components Batteries have become the top priority in research and development. However, most of the currently commercially available secondary lithium batteries use organic electrolytes as electrolytes, which have the disadvantages of being toxic, flammable, low in decomposition potential, and poor in safety. To prevent battery short circuit and improve the structural design. Although various prote...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0562H01M4/13H01M10/0525
CPCH01M4/13H01M10/0525H01M10/0562Y02E60/10
Inventor 李久铭杨容赵尚骞弓胜民张立孙浩博王耀卢世刚
Owner CHINA AUTOMOTIVE BATTERY RES INST CO LTD
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