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A kind of composite nanofiltration membrane and its preparation method and application

A composite nanofiltration membrane, a combined technology, applied in chemical instruments and methods, membrane technology, semi-permeable membrane separation, etc., can solve the problems of poor acid resistance of nanofiltration membranes

Active Publication Date: 2018-12-28
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is in order to overcome the defect that existing nanofiltration membrane is poor in acid resistance, and provide a kind of composite nanofiltration membrane and preparation method thereof, and this composite nanofiltration membrane and the composite nanofiltration membrane prepared by this method are in water applications in the field of processing

Method used

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  • A kind of composite nanofiltration membrane and its preparation method and application
  • A kind of composite nanofiltration membrane and its preparation method and application
  • A kind of composite nanofiltration membrane and its preparation method and application

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preparation example Construction

[0028] The present invention also provides a kind of preparation method of composite nanofiltration membrane, and this method comprises the following steps:

[0029] (1) dissolving polymers containing hydroxyl groups and silane coupling agents containing sulfonic acid groups in solvents to prepare coating solutions;

[0030] (2) coating the coating solution on the support layer to form an initial film;

[0031] (3) immerse the support layer formed with the initial film in step (2) into a solution containing a cross-linking agent and a cross-linking catalyst to carry out a cross-linking reaction to obtain a cross-linked network structure comprising the support layer and the surface of the support layer Composite nanofiltration membrane.

[0032] According to the present invention, the present invention is not particularly limited to the amount of polymers containing hydroxyl groups, silane coupling agents containing sulfonic acid groups, and solvents in the coating solution, a...

preparation example 1

[0058] This preparation example is used to illustrate the preparation method of the silane coupling agent (SKH550) containing sulfonic acid groups.

[0059] Add 5g of KH550 to a conical flask equipped with magnetic stirring, then drop 3g of 1,4-butyl sultone under stirring, and react at room temperature for 24 hours to obtain a silane coupling agent containing a sulfonic acid group; The reaction process is as figure 1 The formation process of the silane coupling agent containing sulfonic acid groups prepared by the present invention is shown in a schematic diagram.

preparation example 2

[0061] This preparation example is used to illustrate the preparation method of the silane coupling agent (SKH540) containing sulfonic acid groups.

[0062] Add 5 g of KH540 into a conical flask equipped with magnetic stirring, then drop 2 g of 1,3-propyl sultone under stirring, and react at room temperature for 24 hours to obtain a silane coupling agent containing sulfonic acid groups.

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Abstract

The invention discloses a composite nanofiltration membrane which comprises a support layer and a separate layer which are superposed together, wherein the separate layer is a composite nanofiltration membrane body adopting a cross-linked network structure formed on the surface of the support layer by dissolving one or more polymers containing hydroxyl groups and a silane coupling agent containing sulfonic groups in a solvent and carrying out a sol-gel reaction and a thermo-crosslinking reaction. The composite nanofiltration membrane is not only relatively high in desalinization ratio, water permeability (water flux), and acid resistance, but also simple in preparation method, thereby having a wide prospect in industrial application.

Description

technical field [0001] The invention relates to a composite nanofiltration membrane, a preparation method thereof, and an application of the composite nanofiltration membrane in the field of water treatment. Background technique [0002] Nanofiltration is a pressure-driven membrane separation process between reverse osmosis and ultrafiltration. The pore size of the nanofiltration membrane is in the range of several nanometers. Or multivalent ions and organic matter with a molecular weight between 200 and 500 have a higher removal rate. It can be widely used in fresh water softening, seawater softening, drinking water purification, water quality improvement, oil-water separation, waste water treatment and recycling, as well as the classification, purification and concentration of chemical products such as dyes, antibiotics, polypeptides and polysaccharides. [0003] At present, most commercial nanofiltration membranes are polyamide structures, which have the advantages of hi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D69/12B01D67/00B01D69/10C02F1/44
Inventor 张杨刘轶群潘国元严昊郭敏
Owner CHINA PETROLEUM & CHEM CORP
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