A kind of composite nanofiltration membrane and its preparation method and application
A composite nanofiltration membrane, a combined technology, applied in chemical instruments and methods, membrane technology, semi-permeable membrane separation, etc., can solve the problems of poor acid resistance of nanofiltration membranes
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[0028] The present invention also provides a kind of preparation method of composite nanofiltration membrane, and this method comprises the following steps:
[0029] (1) dissolving polymers containing hydroxyl groups and silane coupling agents containing sulfonic acid groups in solvents to prepare coating solutions;
[0030] (2) coating the coating solution on the support layer to form an initial film;
[0031] (3) immerse the support layer formed with the initial film in step (2) into a solution containing a cross-linking agent and a cross-linking catalyst to carry out a cross-linking reaction to obtain a cross-linked network structure comprising the support layer and the surface of the support layer Composite nanofiltration membrane.
[0032] According to the present invention, the present invention is not particularly limited to the amount of polymers containing hydroxyl groups, silane coupling agents containing sulfonic acid groups, and solvents in the coating solution, a...
preparation example 1
[0058] This preparation example is used to illustrate the preparation method of the silane coupling agent (SKH550) containing sulfonic acid groups.
[0059] Add 5g of KH550 to a conical flask equipped with magnetic stirring, then drop 3g of 1,4-butyl sultone under stirring, and react at room temperature for 24 hours to obtain a silane coupling agent containing a sulfonic acid group; The reaction process is as figure 1 The formation process of the silane coupling agent containing sulfonic acid groups prepared by the present invention is shown in a schematic diagram.
preparation example 2
[0061] This preparation example is used to illustrate the preparation method of the silane coupling agent (SKH540) containing sulfonic acid groups.
[0062] Add 5 g of KH540 into a conical flask equipped with magnetic stirring, then drop 2 g of 1,3-propyl sultone under stirring, and react at room temperature for 24 hours to obtain a silane coupling agent containing sulfonic acid groups.
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Abstract
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