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170results about How to "High retention performance" patented technology

Preparation method of nano tio2 modified pvdf ultrafiltration membrane

The invention relates to a preparation method of a nano TiO2-modified PVDF (Polyvinylidene Fluoride) ultrafiltration membrane. The preparation method comprises the following steps of: preparing a membrane making liquid from 15-20 percent by mass of PVDF, 1-3 percent of pore-foaming agent, 1-4 percent of nano TiO2, 3-5 percent of surfactant and 70-80 percent of solvent, ultrasonically oscillating the membrane making liquid for 5-10 minutes, leaching and defoaming; scraping with a membrane scraping machine to form a liquid membrane, standing in the air for 20-60 seconds, soaking into a coagulation bath and coagulating the liquid membrane into an ultrafiltration membrane; and after the ultrafiltration membrane falls off, taking the ultrafiltration membrane out, soaking into distilled water and cutting according to required size for later use. A nano TiO2 hydrophilic monomer is arranged on the surface of the PVDF ultrafiltration membrane, sodium dodecyl sulfate serving as a surfactant is used simultaneously, and dispersion is performed by ultrasonically oscillating, so that agglomeration of nano TiO2 is reduced, nano TiO2 is quickly and uniformly distributed into the membrane making liquid, the hydrophilicity of the PVDF ultrafiltration membrane is enhanced effectively, the energy consumption is enhanced greatly, the anti-pollution capacity and pollutant intercepting performance of the membrane are enhanced, and the service life of the membrane is prolonged.
Owner:ZHEJIANG OCEAN UNIV

Method for preparing loose nanofiltration membrane based on interfacial polymerization

The invention discloses a method for preparing a loose nanofiltration membrane based on interfacial polymerization. The method comprises the following steps: preparing a polymer casting solution, dispersing nanoparticles in an aqueous phase monomer and an oil phase monomer, and preparing a flat plate support membrane; immersing the flat plate support membrane in the water phase monomer, then pouring the oil phase monomer into the aqueous phase monomer, and loading a nano membrane onto the surface of the flat plate support membrane after the two phase monomers are subjected to an interfacial polymerization reaction. The composite nanofiltration membrane prepared by the method has a loose structure on the surface; nano materials are embedded into a polyamide nano thin layer during the interfacial polymerization reaction; on the one hand, the hydrophilicity of the surface of the membrane can be improved; on the other hand, in the process of polycondensation, polyamide is simultaneously grown around the materials in the direction perpendicular to the nano materials to form such a sandwich structure; upper and lower polyamide layers can protect the nano materials from being damaged under high operating pressure; the structure of the polyamide nano membrane is regulated; meanwhile, the structural stability, permeability and retention property of the nanofiltration membrane are improved.
Owner:TSINGHUA UNIV

Intermediate-high temperature acid-corrosion-resisting glass fiber treating compound and preparation method thereof

InactiveCN103964708AImprove temperature and weather resistanceGood adhesive properties and thermal stabilityPrepolymerEmulsion
The invention relates to an intermediate-high temperature acid-corrosion-resisting glass fiber treating compound and a preparation method thereof. The method comprises the following steps: putting bisphenol-A epoxy resin and benzoyl peroxide into a flask, and carrying out stirring and rising temperature; then dropwise adding methacrylic acid, and preserving heat; cooling the obtained product, adding paraxylene and dibutyltin dilaurate to continue to stir, dropwise adding vinyltriethoxysilane, and preserving heat to obtain a pale yellow modified epoxy resin prepolymer; adding deionized water and emulsifier into the flask, and then carrying out full stirring and heating for dissolving; adding the modified epoxy resin prepolymer slowly, and continuing to stir after dropwise adding; rapidly cooling the obtained film former emulsion to room temperature, then mixing the film former emulsion, a coupling agent, nanosilicon dioxide, a lubricating agent and an antistatic agent so as to obtain the glass fiber treating compound. The method has the benefit that the temperature resistance of a film former is improved. The treating compound can improve the performance retention rate of glass fiber reinforced plastics materials under the intermediate-high temperature acidic condition.
Owner:WUHAN UNIV OF TECH

Preparation method of dispersion fuel pellet with high uranium loading capacity

The invention discloses a preparation method of a dispersion fuel pellet with high uranium loading capacity, which comprises the steps of firstly adopting means such as pelleting, self-grinding balling and rolling coating to realize the balling of a uranium-based fuel and the coating with a reinforcing phase, then performing high temperature plasma sintering on a coated ball to obtain the uranium-based fuel pellet; forming a large amount of pores in a core pellet of the fuel by utilizing the volatilization of a pore-forming agent under high temperature, then promoting the low-temperature rapiddensification sintering of the reinforcing phase by combining the high temperature plasma sintering technology and a sintering aid, thus obtaining the dispersion fuel pellet with high uranium loadingcapacity, wherein the dispersion fuel pellet has a special core-shell structure in which the compact reinforcing phase coats the porous fuel core pellet, and the special core-shell structure is loosein the interior and compact in the exterior. The method has the advantages that the preparation is simple and the preparation cost is low, can be used for the scale production of the uranium-based fuel pellet; the uranium-based fuel pellet prepared by the method has the advantages of high thermal conductivity, high safety, high uranium loading capacity and high economy.
Owner:MATERIAL INST OF CHINA ACADEMY OF ENG PHYSICS

Preparation method of super-hydrophilic organic membrane based on surface covered with micro-nano structure

ActiveCN108043246AAchieve superhydrophilicityLong-term stable superhydrophilic propertiesSemi-permeable membranesMembranesMicro nanoSilicon dioxide
The invention provides a preparation method of a super-hydrophilic organic membrane. The method comprises the following steps: (1) providing a sheet with a micro-nano structure on the surface; (2) providing a membrane casting solution, and forming a membrane casting solution film on a glass plate; (3) arranging a cushion layer with adjustable height on the periphery of the membrane casting solution film; (4) covering the surface of the membrane casting solution film with the sheet with the micro-nano structure and supporting the sheet with the cushion layer; (5) placing the glass plate in a coagulation bath to form an organic membrane with a complementary micro-nano structure on the surface; (6) grafting a polymethylacrylic acid polymer to the micro-nano structured surface of the organic membrane through plasma induced graft polymerization to obtain a modified organic membrane; (7) soaking the modified organic membrane in a silica nanoparticle suspension with surface modified with a silane coupling agent. The organic membrane prepared with the method has a multi-level micro-nano structure, has the characteristics of being super-hydrophilic, high in flux, persistently anti-pollutionand the like and has good application prospect in the field of membrane-process water treatment.
Owner:BEIJING FORESTRY UNIVERSITY

Hydrolysis-resistant aliphatic-aromatic copolyester and preparation method thereof

The invention discloses hydrolysis-resistant aliphatic-aromatic copolyester and a preparation method thereof. The preparation method comprises the following steps of: (1) carrying out ester exchange reaction on aromatic binary acid ester or aromatic binary acid and excessive dihydric alcohol to obtain ester P1; (2) reacting aliphatic binary acid, cyclized aliphatic binary acid, an esterification derivative of aliphatic binary acid or an esterification derivative of cyclized aliphatic binary acid with aliphatic dihydric alcohol to obtain ester P2; and (3) mixing P1 with P2, adding an antioxidant to carry out condensation polymerization, then adding a carbonate mineral and a silane compound, and evenly mixing, thus the hydrolysis-resistant aliphatic-aromatic copolyester is obtained. The aliphatic-aromatic copolyester disclosed by the invention has better hydrolysis stability, properties of a polymer in storing and processing processes can be ensured to be stable, and the property retention rate of the polyester product can be improved; and meanwhile, the polyester product also has degradation performance after the application task of the product is completed, and a hydrolysis-resistant component is added in a synthetic process, thus addition during modification is avoided and process is simplified.
Owner:KINGFA SCI & TECH CO LTD +1

Preparation method of foamed nickel-loaded amorphous phosphorus-doped nickel molybdate bifunctional electrocatalytic electrode and application thereof

The invention provides a preparation method of a foamed nickel-loaded amorphous phosphorus doped nickel molybdate bifunctional electrocatalytic electrode and an application thereof, and belongs to thetechnical field of hydrogen energy and fuel cells. The preparation method comprises the following steps: soaking foamed nickel into an HCl solution, removing metal oxide on the surface, soaking the pickled foamed nickel into a phosphomolybdic acid aqueous solution, carrying out a spontaneous oxidation-reduction reaction, taking out, washing with deionized water, and drying for later use, therebyobtaining the foamed nickel-loaded amorphous phosphorus-doped nickel molybdate nanostructure. The foamed nickel is etched by using the phosphomolybdic acid aqueous solution, and can be directly used after drying, the material can be used as a bifunctional electrode material for urea electrooxidation and water and electricity reduction; a urea electrooxidation reaction with low oxidation potentialis used for replacing an electrocatalytic oxygen evolution reaction, a two-electrode urea auxiliary electrolysis hydrogen production system based on a bifunctional electrocatalyst is constructed in analkaline solution, low-cost, low-energy-consumption and stable electrochemical hydrogen production is achieved, and the method is suitable for large-scale industrial electrochemical hydrogen production application.
Owner:HARBIN INST OF TECH

Composite nanofiltration membrane and preparation method thereof

The invention discloses a composite nanofiltration membrane, a preparation method thereof, and application of the composite nanofiltration membrane prepared by adopting the preparation method to the field of water treatment. The composite nanofiltration membrane comprises a supporting layer and a separating layer which are overlapped together, wherein the separating layer is a cross-linked net structure which is positioned on the surface of the supporting layer and formed through thermal crosslinking reaction of polymer containing hydroxyl and a silane coupling agent with a structure as shown in the formula (I) (shown in the description) through sol-gel; in the formula (I), Y is alkenyl or carbon functional group, the carbon functional group is alkyl carried with Cl, NH2, epoxy, SH, N3, (methyl) acrylyl or isocyanate group; X is one or more of Cl, OMe, OEt, OC2H4OCH3, OSiMe3 and OAc. According to the composite nanofiltration membrane and the preparation method thereof, provided by the invention, stable operation of the composite nanofiltration membrane in an aqueous solution with the PH of 0-14 is achieved, a higher salt removing rate and water permeability are achieved, higher acid and alkali resistance is further achieved; besides, the method is simple, and an industrial application prospect is further realized.
Owner:CHINA PETROLEUM & CHEM CORP +1

Preparation method of flexible graphene oxide/metal organic framework composite filter membrane

The invention relates to a preparation method of a flexible graphene oxide/metal organic framework composite filter membrane. 2-methylimidazole zinc salt (ZIF-8) is used as a typical metal organic framework (MOFs), a hydrothermal method and a solvothermal method are used for preparing 2-methylimidazole zinc salt and graphene oxide composite particles (ZIF-8-coated GO composite particles) with chemical bonding, the composite particles and GO are subjected to cross-linking compounding, and the ZIF-8-coated GO/GO composite film with graphene oxide as a matrix and the composite particles as reinforcements is obtained. The obtained composite membrane can realize self-supporting, and can still keep complete under the bending action of a certain limit. Mesopores formed by the graphene oxide sheetlayer, micropores of the metal organic framework and macropores formed by adding the composite particles jointly endow the composite membrane with a hierarchical pore structure so that the compositemembrane has a richer pore channel structure, and the pollutant filtering performance is improved. Experimental data show that the membrane has excellent interception performance on pollutants such asPb < 2 + > and methylene blue.
Owner:TIANJIN UNIV

Polymer-surfactant solution ground injection system applicable to mine field and its injection method

ActiveCN107638715AMeet the requirements of diverse maturation timeReduce viscosity lossLiquid degasificationMixersEngineeringCheck valve
The invention provides a polymer-surfactant solution ground injection system applicable to mine field and its injection method. The polymer-surfactant solution ground injection system comprises at least two mixing tanks, a curing tank, and a fluid storage tank; the inner cavities of the mixing tanks are divided into a mixing room and a junction room by a middle board, and the top parts of the mixing tanks are equipped with vacuumizing devices connected to the mixing rooms; a check valve is arranged at the through hole of the bottom part of the middle plate, and the top part of the mixing roomis provided with a first fluid inlet; the bottom part of the junction room is provided with a first fluid outlet and a first sampling opening; the inner cavity of the curing tank is separated into atleast two curing rooms along the circumference, a second fluid inlet is arranged on the side wall of the curing tank corresponding to every curing room, and the bottom part corresponding to every curing room is provided with a second sampling opening and a second fluid outlet; the inner cavity of the fluid storage tank is separated to be at least two fluid storage rooms along the circumferential direction, and a third fluid inlet is arranged on the side wall corresponding to every fluid storage room; the bottom part corresponding to every fluid storage room is provided with a third sampling opening and a third fluid outlet.
Owner:PETROCHINA CO LTD

Method for manufacturing steel wire hydraulic knitted rubber hose containing formaldehyde modified lignin

The invention relates to a method for manufacturing a steel wire hydraulic knitted rubber hose containing formaldehyde modified lignin, belonging to the technical field of the methods for manufacturing rubber products. Mixing rubber produced by utilizing a mixing process serves as a rubber hose and used for producing the high-performance steel wire knitted hydraulic rubber hose for an inner liner. The technical scheme of the method comprises the following steps of: a sizing material mixing process: adopting a two-stage mixing method, that is, mixing and producing one-stage rubber by utilizingan internal mixer, placing the rubber for 8-24 hours and then carrying out second-stage sulfur adding in an open mill, wherein a reverse-order mixing method and variable-speed mixing are utilized in the one-stage mixing in the internal mixer and the heat treatment is carried out on the sizing material during the two-stage mixing in the open mill; extruding the inner liner of the steel wire hydraulic knitted rubber hose by utilizing the mixing rubber; and manufacturing the steel wire hydraulic knitted rubber hose via a knitted steel wire enhancing layer and an extrusion external coating and through cladding, setting and vulcanizing. By utilizing the mixing process, the dispersity of the lignin is greatly improved; the physical and mechanical properties of the steel wire hydraulic knitted rubber hose are good; and compared with nitrile rubber separately using carbon black as a reinforcing agent, the steel wire hydraulic knitted rubber hose containing the formaldehyde modified lignin hasobvious advantages of rigidity, aging resistance and oil resistance at a normal temperature.
Owner:GUANGZHOU TIANHE HOSE PRODS
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