The invention relates to a preparation method of a nano TiO2-modified PVDF (
Polyvinylidene Fluoride) 
ultrafiltration membrane. The preparation method comprises the following steps of: preparing a membrane making liquid from 15-20 percent by 
mass of PVDF, 1-3 percent of pore-
foaming agent, 1-4 percent of nano TiO2, 3-5 percent of surfactant and 70-80 percent of 
solvent, ultrasonically oscillating the membrane making liquid for 5-10 minutes, leaching and defoaming; scraping with a membrane scraping 
machine to form a liquid membrane, standing in the air for 20-60 seconds, soaking into a coagulation bath and coagulating the liquid membrane into an 
ultrafiltration membrane; and after the 
ultrafiltration membrane falls off, taking the ultrafiltration membrane out, soaking into 
distilled water and 
cutting according to required size for later use. A nano TiO2 
hydrophilic monomer is arranged on the surface of the PVDF ultrafiltration membrane, 
sodium dodecyl sulfate serving as a surfactant is used simultaneously, and dispersion is performed by ultrasonically oscillating, so that agglomeration of nano TiO2 is reduced, nano TiO2 is quickly and uniformly distributed into the membrane making liquid, the hydrophilicity of the PVDF ultrafiltration membrane is enhanced effectively, the 
energy consumption is enhanced greatly, the anti-
pollution capacity and 
pollutant intercepting performance of the membrane are enhanced, and the service life of the membrane is prolonged.