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Improved luminous 3D printing photosensitive adhesive and preparation method thereof

A 3D printing and photosensitive adhesive technology, which is applied in the direction of luminescent paint, coating, additive processing, etc., can solve the problems of single color, inconvenient use, lack of night visibility and functionality of 3D products, and achieve easy control, The effect of mature technology and fast curing speed

Inactive Publication Date: 2016-05-11
SHANGHAI INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the above-mentioned technical problems in the prior art, the present invention provides an improved luminous 3D printing photosensitive adhesive and its preparation method. The improved luminous 3D printing photosensitive adhesive and its preparation method should solve the problems in the prior art The 3D printing glue needs to be heated during the molding process, which makes it inconvenient to use; and the formed 3D products have a single color, and do not have the technical problems of poor night visibility and functionality

Method used

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  • Improved luminous 3D printing photosensitive adhesive and preparation method thereof
  • Improved luminous 3D printing photosensitive adhesive and preparation method thereof
  • Improved luminous 3D printing photosensitive adhesive and preparation method thereof

Examples

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Embodiment 1

[0057] An improved luminous 3D printing photosensitive adhesive, calculated in parts by weight, its raw material composition and content are as follows:

[0058]

[0059] Wherein, described UV curing resin A is prepared according to the following method:

[0060] Add 10g of methyl hydrogen-containing silicone oil and 10g of ethoxylated trimethylolpropane triacrylate into a 500ml three-necked flask, then add 0.01g of hydroquinone, pass in protective gas, stir and heat, and raise the temperature to 60 ℃, add 0.01g of chloroplatinic acid complex, keep the temperature under stirring for 3 hours, stop heating, wait until the temperature of the flask drops to room temperature, and obtain UV curable resin A.

[0061] Described UV curing resin B is a toughening resin, such as a mixture of epoxy acrylate and polyurethane acrylate in a mass ratio of 1:1;

[0062] The leveling agent is TegoGlide410;

[0063] Described UV wetting agent is NP-100 of U.S. Dow Company;

[0064] The sai...

Embodiment 2

[0075] An improved luminous 3D printing photosensitive adhesive, calculated in parts by weight, its raw material composition and content are as follows:

[0076]

[0077]

[0078] Wherein said UV curable resin A is prepared according to the following method:

[0079] Add 10g of methyl hydrogen-containing silicone oil and 10g of ethoxylated trimethylolpropane triacrylate into a 500ml three-necked flask, then add 0.01g of hydroquinone, pass in protective gas, stir and heat, and raise the temperature to 60 ℃, add 0.01g of chloroplatinic acid complex, keep the temperature under stirring for 3 hours, stop heating, wait until the temperature of the flask drops to room temperature, and obtain UV curable resin A.

[0080] Described UV curing resin B is a toughening resin, such as a mixture of epoxy acrylate and polyurethane acrylate in a mass ratio of 2:1;

[0081] The leveling agent is a mixture of German BYK-345 and BYK-346 in a mass ratio of 1:1;

[0082] The UV wetting age...

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Abstract

The invention discloses an improved luminous 3D printing photosensitive adhesive. The adhesive is prepared from, by weight, 50-80 parts of UV curing resin A, 50-80 parts of UV curing resin B, 0.05-0.1 part of flatting agent, 1-10 parts of wetting agent, 0.2-1 part of defoaming agent, 1-10 parts of luminous powder and 3-5 parts of photoinitiator A and photoinitiator B. The invention further provides a preparation method of the improved luminous 3D printing photosensitive adhesive. Wetting agent, flatting agent, defoaming agent and luminous powder are added into a high-speed disperser, UV curing resin A, UV curing resin B, photoinitiator A and photoinitiator B are added after dispersion at a rotation speed of 600-800 r / min, dispersion continues to be conducted, and materials are evenly mixed to obtain the improved luminous 3D printing photosensitive adhesive. The improved luminous 3D printing photosensitive adhesive has rapid curing capacity after being used for coating and irradiated by a 395-nm UV-LED lamp.

Description

technical field [0001] The invention belongs to the field of polymer materials and relates to a photosensitive adhesive, in particular to an improved luminous 3D printing photosensitive adhesive and a preparation method thereof. Background technique [0002] High-speed light-curing molding technology has been widely used in the world in recent years, especially 3D printing technology, which is a so-called additive molding technology that mainly manufactures three-dimensional products by adding materials layer by layer. It has low energy consumption, low cost, With the characteristics of high forming precision, it can print any complex parts that cannot be processed by traditional processing methods. There are still some problems in the development of the 3D printing photosensitive adhesive provided at present: the current 3D printing adhesive is mainly made of thermoplastic materials, such as PLA and ABS and other polymer materials, which need to be heated during the molding...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/06C08L63/10C08L75/14C09D183/06C09D163/10C09D175/14C09D5/22C08G77/38B33Y70/00
CPCC08G77/38C08L83/06C08L2205/03C09D5/22C09D183/06C08L63/10C08L75/14
Inventor 张英强常文秀李烨
Owner SHANGHAI INST OF TECH
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