A preparing method of a ternary copolymerized water reducer

A technology of water reducer and copolymerization, which is applied in the field of preparation of ternary copolymerization water reducer, which can solve the problems of high price of MPEGMAA, long production cycle of naphthalene-based water reducer, serious environmental pollution, etc., and improve the early strength and final strength , good market competitiveness, good cost-effective effect

Inactive Publication Date: 2016-05-18
SHAANXI JINHAOYUAN ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Naphthalene-based water-reducers have a long production cycle and serious environmental pollution. Melamines also have environmental pollution problems, which limit their further application. Polycarboxylate-based water-reducers have become a research hotspot due to their series of advantages.
The polycarboxylate water reducer MPEGMAA widely used in China is relatively expensive, and the preparation process is complicated

Method used

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  • A preparing method of a ternary copolymerized water reducer

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preparation example Construction

[0019] The preparation method of the ternary copolymerization water reducer of the present invention comprises the following steps:

[0020] Step 1: Add a certain amount of water, modified polyether allyl polyoxyethylene ether or methallyl polyoxyethylene ether, molecular weight regulator dodecyl mercaptan to the reactor, modify polyether and The mass ratio of water is 1:200-300, the dosage of the molecular weight regulator is 1%-3% of the modified polyether, and the modified polyether solution is obtained by stirring and dissolving;

[0021] Step 2: Heat the modified polyether solution obtained in step 1 to 70°C to 85°C, then add the mixed monomer acrylic acid and acrylamide and the aqueous initiator solution, and the moles of acrylic acid and modified polyether The ratio is 1~1.6:1, the molar ratio of acrylamide to modified polyether is 0.5~1.3:1, the initiator is ammonium persulfate or potassium persulfate, and the amount of initiator is 1%~ of the total mass of acrylic aci...

Embodiment 1

[0025] Step 1: Add a certain amount of water, allyl polyoxyethylene ether (APEG-2400), molecular weight regulator dodecyl mercaptan to the reactor, and the mass ratio of allyl polyoxyethylene ether to water is 1 : 200, the consumption of molecular weight regulator is 1% of allyl polyoxyethylene ether, stirring and dissolving obtains allyl polyoxyethylene ether solution;

[0026] Step 2: Heat the allyl polyoxyethylene ether solution obtained in step 1 to 70°C, then add the mixed monomers of acrylic acid, acrylamide and ammonium persulfate aqueous solution, acrylic acid and allyl polyoxyethylene ether dropwise within 1 hour The molar ratio of acrylamide to allyl polyoxyethylene ether is 1:1, the molar ratio of acrylamide to allyl polyoxyethylene ether is 0.5:1, the amount of ammonium persulfate is 1% of the total mass of acrylic acid and acrylamide, and the ammonium persulfate and The mass ratio of water is 1:5, after the mixed monomer and the ammonium persulfate aqueous solutio...

Embodiment 2

[0029] Step 1: Add a certain amount of water, methallyl polyoxyethylene ether (TPEG-2400), molecular weight regulator dodecyl mercaptan, and the mixture of methallyl polyoxyethylene ether and water into the reactor The mass ratio is 1:300, the amount of the molecular weight regulator is 2% of the allyl polyoxyethylene ether, stirring and dissolving to obtain the methallyl polyoxyethylene ether solution;

[0030] Step 2: Heat the methallyl polyoxyethylene ether solution obtained in step 1 to 75°C, and then add the mixed monomers acrylic acid and acrylamide and ammonium persulfate aqueous solution, acrylic acid and methacrylic acid simultaneously within 1.5 hours The molar ratio of polyoxyethylene ether is 1.3:1, the molar ratio of acrylamide to methallyl polyoxyethylene ether is 0.9:1, and the amount of ammonium persulfate is 4% of the mass sum of acrylic acid and acrylamide. The mass ratio of ammonium persulfate to water in the ammonium aqueous solution is 1:7. After the mixed...

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Abstract

A preparing method of a ternary copolymerized water reducer is disclosed. The method includes adding a proper amount of water, modified polyether and a molecular weight regulator into a reactor, stirring, dissolving to obtain a modified polyether solution, heating to 70-85 DEG C, adding dropwise a monomer mixture of acrylic acid and acrylamide and an aqueous initiator solution at the same time, after addition of the monomer mixture and the aqueous initiator solution is finished, continuously reacting at maintained temperature for 2-4 h, cooling after the reaction is finished, adding an alkali for neutralizing, and adjusting pH of the solution to 7-8 to obtain the modified polyether-polyacrylic acid-polyacrylamide ternary copolymerized water reducer. The method reduces raw material costs, is mild in preparation process conditions, low in cost and capable of meeting environment protection requirements. The water reducer can improve early-stage strength and final-strength of concrete perforated brick setting structures. Properties of the water reducer are superior to those of polycarboxylate water reducers of the same series in the market. The water reducer has a high cost performance ratio and high market competiveness.

Description

technical field [0001] The invention belongs to the technical field of water reducers, and in particular relates to a preparation method of a ternary copolymerization water reducer. Background technique [0002] With the rapid development of concrete technology, various indicators of concrete have also been continuously improved. Studies have shown that although there are many reasons for the cracking of concrete porous brick walls, there are cracks caused by temperature changes, cracks caused by masonry settlement deformation, and poor structure. Reasonable cracks, holes in the wall, cracks caused by grooves, etc., but the drying shrinkage of concrete porous brick masonry is often considered to be an important cause of wall cracking, so the demand and performance requirements for concrete admixtures are also important. Higher and higher. Water reducer is the most commonly used and most important concrete admixture. Adding an appropriate amount of water reducer can effectiv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/06C08F220/06C08F220/56C08F2/38C04B24/26C04B103/30
Inventor 李超
Owner SHAANXI JINHAOYUAN ENVIRONMENTAL PROTECTION TECH CO LTD
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