A kind of composite refrigeration natural gas liquefaction method

A composite refrigeration and natural gas technology, applied in the field of natural gas liquefaction, can solve the problem of high process energy consumption, achieve the effects of high operational safety, stable operation and space saving

Active Publication Date: 2018-06-05
中石化石油工程技术服务有限公司 +1
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Problems solved by technology

The disadvantage is that if all LNG production uses nitrogen expansion refrigeration, the energy consumption of the process will be high

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  • A kind of composite refrigeration natural gas liquefaction method

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Embodiment Construction

[0015] A compound refrigeration natural gas liquefaction method, which is used to exchange heat between pretreated natural gas and the compound refrigerant in a cold box heat exchanger, and liquefy the natural gas into liquefied natural gas, comprising the following steps:

[0016] First, the pretreated natural gas enters the first-stage cold box, and is cooled with the propane refrigeration cycle to -30°C ~ -60°C. In the propane refrigeration cycle, after the propane is pressurized and cooled by the compressor, a part of the propane is throttled and cooled to enter The first-stage cold box exchanges heat with natural gas and heavy hydrocarbons. After the other part of propane is throttled and cooled, the gas phase returns to the inlet of the propane compressor, and the liquid phase and the propane at the outlet of the first-stage cold box enter the second-stage cold box after throttling and cooling. Natural gas and ethylene are vaporized after heat exchange, and return to the ...

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Abstract

The invention relates to a method for natural gas liquefaction, in particular to a method for composite refrigeration natural gas liquefaction by adopting propane and ethylene refrigerant stepwise refrigeration and nitrogen expansion cycle. The method for composite refrigeration natural gas liquefaction is used for heat exchange of pretreated natural gas and a composite refrigerant in a cold box heat exchanger, so as to liquefy the natural gas into liquefied natural gas. The method comprises the steps of first making the pretreated natural gas enter a primary cold box to be subject to refrigeration cycle heat exchange with propane to -30 DEG C to -60 DEG C; making the natural gas enter a secondary cold box to be subject to refrigeration cycle heat exchange with ethylene to -90 DEG C; and finally making the natural gas enter a third-stage cold box to be subject to expansion refrigeration cycle heat exchange with nitrogen to -150 DEG C to -160 DEG C to form finished liquefied natural gas. According to the method for liquefying the natural gas, the refrigerant is a pure substance, no ratio problem occurs, and the refrigerant is stable to operate. Low temperature level refrigerant nitrogen is non-combustible fluid, space is saved better in plane arrangement, and the operational safety is higher.

Description

technical field [0001] The invention relates to a natural gas liquefaction method, in particular to a compound refrigeration natural gas liquefaction method using propane, ethylene refrigerant cascade refrigeration and nitrogen expansion cycle. Background technique [0002] Refrigerated natural gas liquefaction processes typically include three methods: cascade refrigeration, mixed refrigerant refrigeration, and expansion refrigeration. Chapter 3 of the book "LNG Technology" written by Machinery Industry Press, Gu Anzhong, etc. introduces the principles and methods of the three processes. Different refrigeration processes can be used alone and applied to natural gas liquefaction devices. . [0003] Cascade refrigeration usually uses three refrigerants: propane, ethylene, and methane. It consists of three independent refrigeration cycle systems. Each refrigeration cycle contains three heat exchangers. In the cascade liquefaction process, the refrigerant with a higher boiling...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): F25J1/02
CPCF25J1/0022F25J1/005F25J1/0052F25J1/0072F25J1/0085F25J1/0087F25J1/0207
Inventor 杜丽民银永明宋世昌龚金海陈清涛耿红明
Owner 中石化石油工程技术服务有限公司
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