Ultrasoft high-transparency flame-retardant heat-resistant polyvinyl chloride material and preparation method thereof

A technology of polyvinyl chloride and polyvinyl chloride resin, applied in the field of new polymer materials, can solve problems such as softness, transparency, and poor heat resistance, and achieve the goal of improving low-temperature softness, suppressing color changes, and high transparency Effect

Active Publication Date: 2016-12-07
HUBEI YANGTIAN PLASTIC PROD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to overcome the problems of poor softness, transparency and heat resistance in the prior art, and to provide an ultra-soft, high-transparency, flame-retardant and heat-resistant polymer with excellent softness, transparency and heat resistance. Vinyl chloride material and its preparation method

Method used

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Examples

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Effect test

preparation example Construction

[0032] A method for preparing the ultra-soft, highly transparent, flame-retardant and heat-resistant polyvinyl chloride material comprises the following steps in sequence:

[0033] Raw material blending: first polyvinyl chloride resin WS-1300, polyvinyl chloride resin SH-200, ethylene-vinyl acetate carbonyl copolymer E / VA / CO, trioctyl trimellitate, diisodecyl phthalate Add ester, epoxy soybean oil, flame retardant, stabilizer, lubricant and antioxidant into the high-speed mixer according to the required proportion, then stir at low speed for 3-5 minutes, then stir at high speed, and wait until the temperature rises to 105-115°C Continue high-speed stirring for 2-4 minutes to obtain the mixed material, and finally discharge the mixed material into the cooling mixer and stir for 3-5 minutes;

[0034] Plasticizing and granulating: discharge the cooled mixture into a two-stage extrusion granulating unit for extrusion and granulation.

[0035] In the plasticizing and granulating s...

Embodiment 1

[0058] An extra-soft, high-transparency, flame-retardant and heat-resistant polyvinyl chloride material, the raw material composition and weight ratio are: polyvinyl chloride resin WS-1300 50, polyvinyl chloride resin SH-200 30, ethylene-vinyl acetate carbonyl copolymer E / VA / CO 5, Trioctyl trimellitate 30, Diisodecyl phthalate 10, Epoxidized soybean oil 5, Tris (β-chloroethyl) phosphate 8, Phosphite monophenyl diisooctyl Esters 0.8, Stabilizer CA1362 0.4, Stabilizer ZN1500 0.1, Methylphenyl Silicone Oil 0.3, Dialkyl Thiodipropionate 0.8, Trimethylolpropane Trimethacrylate 3.

[0059] A method for preparing the ultra-soft, highly transparent, flame-retardant and heat-resistant polyvinyl chloride material comprises the following steps in sequence:

[0060] Blending of raw materials: First, add each raw material into the high-speed mixer according to the required ratio, then stir at low speed for 4 minutes, then stir at high speed, and continue stirring at high speed for 3 minut...

Embodiment 2

[0066] Step is with embodiment 1, and difference is:

[0067] The raw material composition and weight ratio of the material are: polyvinyl chloride resin WS-1300 80, polyvinyl chloride resin SH-20040, ethylene-vinyl acetate carbonyl copolymer E / VA / CO 10, trioctyl trimellitate 40. Diisodecyl phthalate 15, epoxidized soybean oil 8, tris(β-chloroethyl) phosphate 10, monophenylene diisooctyl phosphite 1, stabilizer CA1362 0.6, stabilizer ZN1500 0.3, Methyl phenyl silicone oil 0.5, dialkyl thiodipropionate 1, trimethylolpropane trimethacrylate 5.

[0068] In the raw material blending step, the low-speed stirring time is 5 minutes, the continuous high-speed stirring time is 4 minutes, and the stirring and cooling time is 5 minutes;

[0069] In the irradiation crosslinking step, the irradiation dose is 18 Mrads.

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PUM

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Abstract

The invention relates to an ultrasoft high-transparency flame-retardant heat-resistant polyvinyl chloride material which is composed of the following raw materials in parts by weight: 50-80 parts of polyvinyl chloride resin WS-1300, 30-40 parts of polyvinyl chloride resin SH-200, 5-10 parts of ethylene-vinyl acetate carbonyl copolymer E / VA / CO, 30-40 parts of trioctyl trimellitate, 10-15 parts of diisodecyl phthalate, 5-8 parts of epoxy soybean oil, 8-10 parts of flame retardant, 1.3-1.9 parts of stabilizer, 0.3-0.5 part of lubricant and 0.8-1 part of antioxidant. The preparation method comprises the following steps: blending the raw materials, and carrying out extrusion granulation in a double-screw extrusion granulator set. The polyvinyl chloride material has the advantages of favorable transparency, favorable flexibility, favorable flame retardancy and favorable heat resistance.

Description

technical field [0001] The invention belongs to the field of new polymer materials, and in particular relates to an extra-soft, highly transparent, flame-retardant and heat-resistant polyvinyl chloride material and a preparation method thereof. Background technique [0002] Some special components, such as automotive thin-walled wire harness materials, heat-resistant electrical wires, speaker wires, and cables that require high transparency, etc., in order to meet the requirements of use, the materials need to have super softness, high transparency, and high flame resistance at the same time resistance and heat resistance. However, it is difficult for ordinary materials to have the above properties at the same time, especially high transparency and high flame retardancy, because the addition of flame retardants will affect the high transparency and softness of the material. [0003] Chinese patent: The invention patent with application publication number CN101768313A and ap...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L23/08C08L91/00C08L83/04C08K13/02C08K5/12C08K5/521C08K5/526C08K5/372B29C47/92B29C48/92
CPCB29C48/92B29C2948/92542B29C2948/9258B29C2948/92704C08K2201/014C08L27/06C08L2201/02C08L2201/08C08L2201/10C08L2205/025C08L2205/035C08L2312/06C08L23/0853C08L91/00C08L83/04C08K13/02C08K5/12C08K5/521C08K5/526C08K5/372
Inventor 胡晓红
Owner HUBEI YANGTIAN PLASTIC PROD CO LTD
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