Photosensitive resin composition containing oxime ester photoinitiator and application of photosensitive resin composition

A photosensitive resin and photoinitiator technology, which is applied in the field of photosensitive resin compositions, can solve the problems of reduced developability, obstacles to the photosensitive properties of the composition, and reduced linearity of patterns, etc., to achieve complete and clear patterns, excellent curing effects, The effect of high optical clarity

Inactive Publication Date: 2017-02-22
CHANGZHOU TRONLY ADVANCED ELECTRONICS MATERIALS CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In general, it is necessary to improve the light-shielding properties of BM by increasing the film thickness or increasing the content of light-shielding pigments or dyes, but in the case where light-shielding properties are required in the entire light wavelength region, these measures tend to cause significant obstacles to the photosensitive properties of the composition The main manifestations are: there is a difference in crosslinking density between the exposed part and the unexposed part and the exposed bottom; the insoluble pigment in the developer reduces the developability, which leads to a decrease in the linearity of the pattern, or the pattern peels off, resulting in residue; etc.

Method used

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  • Photosensitive resin composition containing oxime ester photoinitiator and application of photosensitive resin composition
  • Photosensitive resin composition containing oxime ester photoinitiator and application of photosensitive resin composition
  • Photosensitive resin composition containing oxime ester photoinitiator and application of photosensitive resin composition

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specific Embodiment approach

[0077] The present invention will be described in further detail below through examples, but it should not be interpreted as limiting the protection scope of the present invention.

[0078] Preparation Example

[0079] According to the formulations listed in Table 1, the photosensitive resin compositions of Examples 1-8 and Comparative Examples 1-4 were prepared. Wherein, the structure of photoinitiator A1-A4 in comparative example 1-4 is as follows:

[0080]

[0081] Table 1

[0082]

[0083]

[0084] The photosensitive resin composition prepared according to the formula shown in Table 1 was dissolved in 100 parts by mass of solvent propylene glycol monomethyl ether acetate (PGMEA), and mixed uniformly to form a liquid composition;

[0085] Use a spin coater to coat the liquid composition on a glass substrate, then dry at 100°C for 5 minutes to remove the solvent to form a coating film with a film thickness of 8 μm; in order to obtain a coating film with the above...

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Abstract

The invention discloses a photosensitive resin composition, which comprises ultraviolet photosensitive prepolymer resin, an active diluent monomer, a photoinitiator and an optional coloring agent, wherein the photoinitiator is selected from at least one of an oxime ester compound as shown in a formula (I) and a derivative compound by employing the compound as shown in the formula (I) as a main body structure. The composition has high photosensibility, good developing performance, high resolution ratio and excellent sealing property with a substrate, is very suitable for preparation of a black matrix with high shading performance, a high-precision and high-quality color filter and a liquid crystal display device, and can be used in the aspects of a light spacer, a ribbed bar, a photoresist, a dry film and the like. The formula is as shown in the specification.

Description

technical field [0001] The invention belongs to the field of organic chemistry, in particular to a photosensitive resin composition containing an oxime ester photoinitiator and its preparation of color filter film (RGB), black matrix (BM), photoresist, and photospacer (photo-spacer), rib (rib) and dry film applications. Background technique [0002] In display devices such as liquid crystal displays, the liquid crystal layer is usually arranged between two substrates, and electrodes facing each other are arranged on each substrate, and on the inside of one of the substrates, opposite to the liquid crystal layer, red (R), A color filter layer formed by each pixel of green (G), blue (B), and black. Among them, the color weights of R, G, and B colors are usually distinguished in the form of setting matrix. [0003] At present, the methods for producing color filters mainly include dyeing method, printing method, pigment dispersion method and anode method, among which the pigm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03F7/027G03F7/004
Inventor 钱晓春胡春青于培培孙克疆
Owner CHANGZHOU TRONLY ADVANCED ELECTRONICS MATERIALS CO LTD
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