Composite sheet for protective film formation
A technology of protective film and composite sheet, which is applied in the direction of film/sheet adhesive, semiconductor/solid-state device parts, semiconductor devices, etc., to achieve the effect of excellent laser transmittance and inhibition of adhesion
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Embodiment 1
[0181] In Example 1, manufactured as follows image 3 , 4 The composite sheet 3 for forming a protective film is shown.
[0182] (1) Preparation of the first laminate including the protective film forming film
[0183] The following components were mixed in the compounding ratio (in terms of solid content) shown below, and diluted with methyl ethyl ketone so that the solid content concentration became 61% by mass to prepare a coating agent for forming a protective film.
[0184] (A) Adhesive polymer: 10 mass parts of n-butyl acrylate, 70 mass parts of methyl acrylate, 5 mass parts of glycidyl methacrylate and 15 mass parts of 2-hydroxyethyl acrylate (methyl acrylate) ) acrylate copolymer (weight average molecular weight: 800,000, glass transition temperature: -1°C) 100 parts by mass
[0185] (B-1) 60 parts by mass of bisphenol A epoxy resin (manufactured by Mitsubishi Chemical Corporation, jER828, epoxy equivalent 184 to 194 g / eq)
[0186] (B-2) 10 parts by mass of bisphen...
Embodiment 2~5 and comparative example 1~3
[0206] The arithmetic mean roughness (Ra1) and the arithmetic mean roughness (Ra2) after heating, the melting point, and the storage modulus at 130°C of the back surface of the substrate were changed as shown in Table 1 below, except Except that, the composite sheet for protective film formation of Examples 2-5 and Comparative Examples 1-3 was manufactured similarly to Example 1.
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