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A method for bonding and repairing surfaces with epoxy resin

A technology of epoxy resin and surface repair, which is applied in the direction of surface pretreatment bonding methods, epoxy resin glue, adhesives, etc., and can solve the problems of reduced bonding strength, poor wettability and fluidity of epoxy resin, and complicated treatment processes, etc. problems, to achieve the effect of increasing fluidity and wettability, facilitating on-site construction, and improving shear strength

Inactive Publication Date: 2019-08-30
CHANGAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the current bonding process, due to the lack of fluidity of the epoxy resin, it cannot penetrate into the surface pits or gaps, so that the epoxy resin cannot completely contact the rough bonding or repairing surface. After the epoxy resin is cured, it will be in the Gap at contact interface
like figure 1 As shown, if during the repair process, the gap defect 2 (early crack) will be formed at the bonding interface because the epoxy resin cannot penetrate deep into the gap of the repaired surface, which will have a serious impact on the safety of the aircraft
In addition, due to the poor wettability and fluidity of the epoxy resin, the carbon nanotubes 4 cannot be completely wrapped, so that the carbon nanotubes 4 will generate air bubbles 5 during the mixing process with the epoxy resin, and the presence of air bubbles on the surface of the carbon nanotubes and gaps on the bonding surface will cause serious problems. Cause stress concentration at the bonding interface and reduce the bonding strength
Because the direct mixing of carbon nanotubes and epoxy resin is prone to defects such as bubbles, and the viscous resin is generally difficult to enter the carbon nanotube aggregates, the current method is to mix by mechanical extrusion, or use chemical treatment methods, such as Carbon nanotubes are functionalized to improve the uniform distribution of carbon nanotubes in epoxy resin and reduce aggregates. Therefore, the existing treatment process is relatively complicated and not conducive to on-site operations

Method used

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  • A method for bonding and repairing surfaces with epoxy resin
  • A method for bonding and repairing surfaces with epoxy resin
  • A method for bonding and repairing surfaces with epoxy resin

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0033] (1) Preparation of pretreatment solution. The carbon nanotubes, the epoxy resin and the acetone are uniformly mixed according to the mass ratio (1-2):(2-5):(90-110) to obtain a dilute epoxy resin solution.

[0034] (2) Pretreatment of the interface to be bonded or repaired. Spray the epoxy resin dilution solution on the surface of the substrate to be bonded or repaired in 2 to 3 times by spraying, and pretreat the surface to be bonded or repaired. It is advisable that the mixture of carbon nanotubes and carbon nanotubes can completely fill the surface gaps to be repaired, such as figure 2 shown. The diluted epoxy resin solution that penetrates deep into the gap, due to the volatility of acetone, the acetone in the diluted solution will quickly volatilize in a short period of time. With the volatilization of acetone in the diluted epoxy resin solution, the diluted epoxy resin solution will The epoxy resin and carbon nanotubes in the bonded or repaired surface remain ...

Embodiment 1

[0042] (1) carbon nanotubes, epoxy resin and acetone are uniformly mixed in a mass ratio of 1:3:100 to obtain a diluted solution of epoxy resin;

[0043] (2) The epoxy resin dilution solution is sprayed three times on the surface to be repaired to obtain a pretreatment layer;

[0044](3) Mix the epoxy resin and curing agent evenly at a volume ratio of 1:1, and apply it on the pretreatment layer by brushing until the epoxy resin is completely cured, completing the epoxy resin bonding and repairing the surface. And test its performance after bonding as shown in Table 1 below:

[0045] Table 1 Adhesion strength test after surface pretreatment (pretreatment solution containing carbon nanotubes)

[0046]

Embodiment 2

[0059] (1) carbon nanotubes, epoxy resin and acetone are uniformly mixed in a mass ratio of 1:5:110 to obtain a diluted solution of epoxy resin;

[0060] (2) The epoxy resin dilution solution is sprayed three times on the surface to be repaired to obtain a pretreatment layer;

[0061] (3) Mix the epoxy resin and curing agent evenly at a volume ratio of 1:1.1, and coat it on the pretreatment layer until the epoxy resin is completely cured, completing the epoxy resin bonding and repairing the surface.

[0062] (1) Carbon nanotubes, epoxy resin and acetone are uniformly mixed in a mass ratio of 2:2:90 to obtain a diluted solution of epoxy resin;

[0063] (2) The epoxy resin dilution solution is sprayed three times on the surface to be repaired to obtain a pretreatment layer;

[0064] (3) Mix the epoxy resin and curing agent evenly at a volume ratio of 1:0.9, and coat it on the pretreatment layer until the epoxy resin is completely cured to complete the epoxy resin bonding and su...

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Abstract

The invention relates to an epoxy-resin surface bonding and repairing method. The method includes the steps that a carbon nanometer tube, epoxy resin and acetone are mixed to be even in the mass ratio of (1-2):(2-5):(90-110), and an epoxy-resin dilute solution is obtained; the epoxy-resin dilute solution is sprayed to a to-be-repaired surface multiple times, and a pretreatment layer is obtained; the epoxy and a curing agent are mixed to be even, the pretreatment layer is coated with the product till the epoxy is completely cured, and the epoxy-resin surface bonding and repairing is completed. According to the epoxy-resin surface bonding and repairing method, the epoxy resin with the added carbon nanometer tube is diluted with acetone, the mobility and the wettability of the epoxy resin are improved, and the carbon nanometer tube is completely coated by the epoxy resin and permeates into minimum gaps of a bonded or repaired surface, and the epoxy resin is cured through the diffusion effect of the curing agent; meanwhile, due to extruding, the small part of carbon nanometer tube in the gaps can enter post-covered epoxy resin, a gap-free and bubble-free bonding layer is formed, and the strength of a bonding interface is improved.

Description

[0001] 【Technical field】 [0002] The invention relates to the field of surface repair, in particular to a method for bonding and repairing surfaces with epoxy resin. [0003] 【Background technique】 [0004] Epoxy resin has strong cohesion, dense molecules, and good mechanical properties. And it contains polar groups such as epoxy group and hydroxyl group with great activity, which makes it have excellent adhesive performance. In addition, epoxy resin also has the advantages of strong chemical corrosion resistance and good electrical insulation, which determines that epoxy resin occupies an important position in national production. Composite materials made of epoxy resin have a series of advantages such as good mechanical properties, light weight, high specific strength and specific stiffness, making them widely used in automobiles, aviation and other fields. Especially in the field of aviation, the weight of the airframe determines the fuel consumption rate and thus determi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J5/02C09J163/00C09J11/04
Inventor 王斌华梁佳丁广志芦强王刚
Owner CHANGAN UNIV