Application of manganese oxide-fullerene hybrid material in near-infrared light denitrification
A near-infrared light and fullerene technology, applied in physical/chemical process catalysts, organic compound/hydride/coordination complex catalysts, chemical instruments and methods, etc.
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Embodiment 1
[0038] (1)C 60 -α-MnO 2 Preparation: Weigh manganese chloride and potassium permanganate (molar ratio of 3:2), and dissolve them in 20 mL of deionized water respectively, and add 5% fullerenes of the theoretical yield of manganese dioxide to the manganese chloride solution. , transferred to a three-necked flask by ultrasonic for 1 hour, heated to 85°C in a water bath, and added dropwise with potassium permanganate, refluxed into a condenser for 12h, filtered and washed, and vacuum-dried at 70°C for 12 hours to obtain the fullerene. -α-Manganese dioxide nanocomposite photocatalyst.
[0039] (2) Photocatalysis experiment: wrap the wall of a 100ml beaker with tin foil to prevent ultraviolet light and visible light from entering the reaction system, and cover the beaker mouth with a λ>780nm cut-off filter to ensure that only near-infrared light The radiation entered the photoreactor, and a 300W UV-Vis lamp was placed above the reactor. Add a certain concentration of ammonia nit...
Embodiment 2
[0045] C 60 -β-MnO 2 Preparation: Weigh manganese chloride and potassium permanganate (molar ratio of 3:2), dissolve them in 20 mL of deionized water respectively, then add 5% fullerenes of the theoretical yield of manganese dioxide to the manganese chloride solution, ultrasonically For 1 hour, add potassium permanganate solution, stir for 30min, transfer to a 100ml reaction kettle, heat at 160°C for 12h, cool to room temperature, filter and wash, and dry under vacuum at 70°C for 12h to obtain the fuller En-β-manganese dioxide nanohybrid photocatalysts.
[0046] (2) Photocatalysis experiment: wrap the wall of a 100ml beaker with tin foil to prevent ultraviolet light and visible light from entering the reaction system, and cover the beaker mouth with a λ>780nm cut-off filter to ensure that only near-infrared light The radiation entered the photoreactor and a 300W UV-Vis lamp was placed above the reactor. Add a certain concentration of ammonia nitrogen solution to the beaker,...
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