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Infrared barrier and heat insulation transparent inorganic coating, preparation method thereof and application

An inorganic coating and transparent technology, applied in the direction of reflection/signal coatings, coatings, etc., can solve the problems of the stability of transparent heat insulation film, lack of UV aging resistance and wear resistance, and achieve the effect of improving stability

Active Publication Date: 2017-04-26
傲川科技(河源)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, most of the film-forming agents of transparent heat-insulating coatings currently use organic substances, such as organic resins, which limit their service life, and the prepared transparent heat-insulating films are still lacking in stability, UV aging resistance, and abrasion resistance.

Method used

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  • Infrared barrier and heat insulation transparent inorganic coating, preparation method thereof and application
  • Infrared barrier and heat insulation transparent inorganic coating, preparation method thereof and application
  • Infrared barrier and heat insulation transparent inorganic coating, preparation method thereof and application

Examples

Experimental program
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Effect test

Embodiment 1

[0038] Example 1 (preparation of infrared-blocking nanopowders——zinc-doped ATO nanopowders)

[0039] 1. Zn in stoichiometric ratio in three beakers x Sb 0.1 sn 0.9-x (x=0.06) add SnCl respectively 4 ·5H 2 O, SbCl 3 and Zn(Ac) 2 2H 2 O, then add absolute ethanol to each beaker to fully dissolve (evenly distribute) the three raw materials in absolute ethanol, and obtain SnCl 4 ethanol solution, SbCl 3 Ethanol solution and Zn(Ac) 2 weak.

[0040] 2. Add SbCl 3 Ethanol solution and Zn(Ac) 2 The ethanol solution was added dropwise to the SnCl 4 In ethanol solution, reflux at 70°C for 4 hours to obtain a sol;

[0041] 3. Add ammonia water dropwise to the sol to adjust the pH of the sol obtained in step 2 to 7, transfer the obtained sol to a microwave hydrothermal reaction kettle, and set the microwave hydrothermal temperature to 160°C under microwave conditions. Reaction time 1 hour.

[0042] 4. The reacted sol obtained in step 3 was washed, centrifuged and dried severa...

Embodiment 2

[0045] A method for preparing an infrared-blocking and heat-insulating transparent inorganic coating, comprising the following steps: stirring an inorganic transparent film-forming medium, infrared-blocking nano-powder, sodium polyphosphate, nonionic polyacrylate, and methyl cellulose until uniform Mixing, adjusting the pH of the system to 9, stirring for 6 hours, ball milling for 48 hours; wherein,

[0046] The ratio of zinc-doped ATO nanopowder, inorganic transparent film-forming medium, sodium polyphosphate, nonionic polyacrylate and methyl cellulose is 20:75:2:2:1;

[0047] The inorganic transparent film-forming medium is made of silica sol, nano-titanium dioxide sol, and nano-zirconium sol, among which SiO 2 、TiO 2 and ZrO 2 The ratio of parts by mass is 75:15:10;

[0048] The infrared-blocking nano-powder is the zinc-doped ATO nano-powder prepared in Example 1.

[0049] The infrared-blocking and heat-insulating transparent inorganic coating obtained in Example 2 was ...

Embodiment 3

[0051] A method for preparing an infrared-blocking and heat-insulating transparent inorganic coating, comprising the following steps: mixing inorganic transparent film-forming medium, infrared-blocking nano-powder, silane coupling agent KH-560, nonionic polyacrylate and hydroxypropyl methyl Base cellulose was stirred until evenly mixed, the pH of the system was adjusted to 9, after stirring for 6 hours, ball milled for 48 hours; wherein,

[0052] The mass ratio of zinc-doped ATO nanopowder, inorganic transparent film-forming medium, silane coupling agent KH-560, nonionic polyacrylate and hydroxypropyl methylcellulose is 25:70:1:3:1;

[0053] The inorganic transparent film-forming medium is made of silica sol, nano-titanium dioxide sol, and nano-zirconium sol, among which SiO 2 、TiO 2 and ZrO 2 The ratio of parts by mass is 80:10:10;

[0054] The infrared-blocking nano-powder is the zinc-doped ATO nano-powder prepared in Example 1.

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Abstract

The invention discloses an infrared barrier and heat insulation transparent inorganic coating, a preparation method thereof and an application. The preparation method of the transparent inorganic coating includes the steps: uniformly mixing inorganic transparent filming media, infrared barrier nano-powder, dispersing agents, leveling agents and thickening agents; adjusting pH (potential of hydrogen) of a system to range from 8 to 10; stirring materials for 4-10 hours and performing ball milling for 12-72 hours. The inorganic transparent filming media replace traditional organic resin, an infrared barrier and heat insulation transparent inorganic film prepared from the inorganic transparent filming media can remarkably improve stability, ultraviolet aging resistance and wear resistance of film materials.

Description

technical field [0001] The invention belongs to the technical field of material preparation, and in particular relates to an infrared-blocking and heat-insulating transparent inorganic coating and a preparation method and application thereof. Background technique [0002] Today's world economy is developing rapidly, but the environment on which human beings depend is deteriorating day by day, and the problem of energy consumption is becoming more and more prominent, especially the problem of energy consumption in buildings. Therefore, in recent years, in order to save energy, people have tried various measures to solve the heat insulation problem of glass. There are mainly three methods used in traditional insulating glass. One is to use magnetron sputtering and other processes to prepare filmed glass. The process is more complicated and the equipment is expensive. Most of the glass film is imported, resulting in a higher price of glass film. ; The second is to use heat ref...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D1/00C09D5/33C09D7/12C03C17/00
CPCC03C17/009C09D1/00C09D5/004C09D7/61C09D7/63C09D7/65
Inventor 毛智勇李万忠王达健蔡名一高文宇刘耀文陈静静
Owner 傲川科技(河源)有限公司
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