Infrared barrier and heat insulation transparent inorganic coating, preparation method thereof and application
An inorganic coating and transparent technology, applied in the direction of reflection/signal coatings, coatings, etc., can solve the problems of the stability of transparent heat insulation film, lack of UV aging resistance and wear resistance, and achieve the effect of improving stability
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Embodiment 1
[0038] Example 1 (preparation of infrared-blocking nanopowders——zinc-doped ATO nanopowders)
[0039] 1. Zn in stoichiometric ratio in three beakers x Sb 0.1 sn 0.9-x (x=0.06) add SnCl respectively 4 ·5H 2 O, SbCl 3 and Zn(Ac) 2 2H 2 O, then add absolute ethanol to each beaker to fully dissolve (evenly distribute) the three raw materials in absolute ethanol, and obtain SnCl 4 ethanol solution, SbCl 3 Ethanol solution and Zn(Ac) 2 weak.
[0040] 2. Add SbCl 3 Ethanol solution and Zn(Ac) 2 The ethanol solution was added dropwise to the SnCl 4 In ethanol solution, reflux at 70°C for 4 hours to obtain a sol;
[0041] 3. Add ammonia water dropwise to the sol to adjust the pH of the sol obtained in step 2 to 7, transfer the obtained sol to a microwave hydrothermal reaction kettle, and set the microwave hydrothermal temperature to 160°C under microwave conditions. Reaction time 1 hour.
[0042] 4. The reacted sol obtained in step 3 was washed, centrifuged and dried severa...
Embodiment 2
[0045] A method for preparing an infrared-blocking and heat-insulating transparent inorganic coating, comprising the following steps: stirring an inorganic transparent film-forming medium, infrared-blocking nano-powder, sodium polyphosphate, nonionic polyacrylate, and methyl cellulose until uniform Mixing, adjusting the pH of the system to 9, stirring for 6 hours, ball milling for 48 hours; wherein,
[0046] The ratio of zinc-doped ATO nanopowder, inorganic transparent film-forming medium, sodium polyphosphate, nonionic polyacrylate and methyl cellulose is 20:75:2:2:1;
[0047] The inorganic transparent film-forming medium is made of silica sol, nano-titanium dioxide sol, and nano-zirconium sol, among which SiO 2 、TiO 2 and ZrO 2 The ratio of parts by mass is 75:15:10;
[0048] The infrared-blocking nano-powder is the zinc-doped ATO nano-powder prepared in Example 1.
[0049] The infrared-blocking and heat-insulating transparent inorganic coating obtained in Example 2 was ...
Embodiment 3
[0051] A method for preparing an infrared-blocking and heat-insulating transparent inorganic coating, comprising the following steps: mixing inorganic transparent film-forming medium, infrared-blocking nano-powder, silane coupling agent KH-560, nonionic polyacrylate and hydroxypropyl methyl Base cellulose was stirred until evenly mixed, the pH of the system was adjusted to 9, after stirring for 6 hours, ball milled for 48 hours; wherein,
[0052] The mass ratio of zinc-doped ATO nanopowder, inorganic transparent film-forming medium, silane coupling agent KH-560, nonionic polyacrylate and hydroxypropyl methylcellulose is 25:70:1:3:1;
[0053] The inorganic transparent film-forming medium is made of silica sol, nano-titanium dioxide sol, and nano-zirconium sol, among which SiO 2 、TiO 2 and ZrO 2 The ratio of parts by mass is 80:10:10;
[0054] The infrared-blocking nano-powder is the zinc-doped ATO nano-powder prepared in Example 1.
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Abstract
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