Preparation method of high-abundance rare earth sintered neodymium-iron-boron magnet capable of regulating and controlling grain boundary multi-layer structure and product prepared by preparation method

A rare earth neodymium iron boron, multi-layer structure technology, applied in magnetic objects, inductor/transformer/magnet manufacturing, magnetic materials, etc., can solve the problem of single grain boundary strengthening effect, waste of heavy rare earth resources, and inability to fine-tune grain boundary structure question

Active Publication Date: 2017-04-26
MATERIAL INST OF CHINA ACADEMY OF ENG PHYSICS
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The purpose of the present invention is to aim at the inability to finely regulate the grain boundary structure in the existing methods, resulting in a single grain boundary strengthening effect and serious waste of heavy rare earth resources, and with the sharp increase in the amount of magnets, it will lead to a large amount of limited rare earth resources Consumption problem, provide a preparation method of high-abundance rare earth sintered NdFeB magnets controlled by grain boundary multilayer structure and its products

Method used

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  • Preparation method of high-abundance rare earth sintered neodymium-iron-boron magnet capable of regulating and controlling grain boundary multi-layer structure and product prepared by preparation method
  • Preparation method of high-abundance rare earth sintered neodymium-iron-boron magnet capable of regulating and controlling grain boundary multi-layer structure and product prepared by preparation method

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Embodiment 1

[0049] This embodiment includes the following steps.

[0050] (1) Preparation of Nd-Fe-B main phase powder with low rare earth content and NdFeB main phase powder containing high abundance rare earth

[0051] When preparing Nd-Fe-B main phase powder with low rare earth content, Nd-Fe-B quick-setting flakes were obtained by smelting and flake rapid cooling. Subsequently, the Nd-Fe-B main phase powder with low rare earth content and an average particle size of about 3.8 μm was obtained through hydrogen explosion and jet milling processes.

[0052] Preparation of NdFeB main phase powder containing high-abundance rare earth, the composition is Nd 12.3 Fe bal B 6.1 and (Nd 10.3 La 2.0 )Fe bal B 3.1 . NdFeB quick-setting flakes are prepared by smelting and flake rapid cooling. Subsequently, through the hydrogen explosion and jet milling process, the NdFeB main phase powder containing high-abundance rare earths with an average particle size of about 3.8 μm was obtained.

[00...

Embodiment 2

[0060] This embodiment includes the following steps.

[0061] (1) Preparation of Nd-Fe-B main phase powder with low rare earth content and NdFeB main phase powder containing high abundance rare earth

[0062] First prepare the Nd-Fe-B main phase powder with low rare earth content, and the NdFeB main phase powder containing high-abundance rare earth (the composition is Nd 12.3 Fe bal B 6.1 and (Nd 10.3 Ce 2.0 )Fe bal B 3.1 ). NdFeB quick-setting flakes are prepared by smelting and flake rapid cooling. Subsequently, two main phase powders with an average particle size of about 3.8 μm were obtained through hydrogen explosion and jet milling processes.

[0063] (2) Preparation of low melting point heavy rare earth grain boundary reconstruction alloy

[0064] According to the phase diagram of the alloy and the mixing enthalpy between elements, the alloy composition is designed to reconstruct the grain boundary of heavy rare earth elements with low melting point. around th...

Embodiment 3

[0070] This embodiment includes the following steps.

[0071] (1) Preparation of Nd-Fe-B main phase powder with low rare earth content and NdFeB main phase powder containing high abundance rare earth

[0072] First prepare the Nd-Fe-B main phase powder with low rare earth content, and the NdFeB main phase powder containing high-abundance rare earth (the composition is Nd 12.3 Fe bal B 6.1 and (Nd 9.3 La 3.0 )Fe bal B 3.1 ). NdFeB quick-setting flakes are prepared by smelting and flake rapid cooling. Subsequently, two main phase powders with an average particle size of about 3.8 μm were obtained by hydrogen explosion and jet milling processes.

[0073] (2) Preparation of low melting point heavy rare earth grain boundary reconstruction alloy

[0074] According to the alloy phase diagram and inter-element mixing enthalpy, design the low-melting point heavy rare earth grain boundary to reconstruct the alloy composition. It is required that the alloy contains more heavy ra...

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Abstract

The invention discloses a preparation method of a high-abundance rare earth sintered neodymium-iron-boron magnet capable of regulating and controlling a grain boundary multi-layer structure and a product prepared by the preparation method, and aims at solving the problems that the grain boundary strengthening effect is single and waste of heavy rare earth resources is serious due to the fact that fine regulation and control on the grain crystal structure cannot be achieved by an existing method, and limited rare earth resources are greatly consumed along with a dramatic increase in the dosage of the magnet. According to the preparation method, preparation of the high-abundance rare earth sintered neodymium-iron-boron magnet capable of regulating and controlling the grain boundary multi-layer structure is achieved by adopting a double-alloy process and a second sintering technology. The prepared magnet has a double main phase structure and has an Nd2Fe14B main phase and an (La, Nd)2Fe14B/(Ce, Nd)2Fe14B main phase at the same time; and the grain boundary phase has a multi-layer grain boundary structure of a heavy rare earth thin shell layer/a high-potential grain boundary center layer containing high-abundance rare-earth/another heavy rare earth thin shell layer. According to the preparation method, overall improvement of the magnetic property and the corrosion resistance of the magnet is achieved through fine regulation and control on the grain crystal structure on the basis of achieving full utilization of the high-abundance rare earth; and the preparation method has relatively high application value and economic value.

Description

technical field [0001] The invention relates to the field of permanent magnet materials, in particular to a preparation method of a high-abundance rare earth sintered NdFeB magnet and its product, which can realize the regulation and control of the multi-layer structure of the grain boundary. A preparation method and product of a rare earth sintered NdFeB magnet. Background technique [0002] NdFeB permanent magnet materials have excellent magnetic properties and are ideal materials for manufacturing high-efficiency, small-volume, and light-weight magnetic functional devices. They have been widely used in electric bicycles, automobile motors, computer hard drives, electronic toys, and electric tools. And other products, as well as audio equipment, communication products, consumer electronics, medical equipment, home appliances, magnetic separation equipment and other fields, its products have high grade, high added value and wide application range. Especially in the applica...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F1/057H01F41/02
CPCH01F1/0577H01F41/0253
Inventor 张培胡梅娟
Owner MATERIAL INST OF CHINA ACADEMY OF ENG PHYSICS
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