A modified Y-type molecular sieve and its preparation method

Abstract

The invention discloses a modified Y-type molecular sieve and a preparation method thereof. The preparation method comprises: (1) carrying out ammonium salt ion exchange in an ammonium salt solution by using NaY zeolite as raw powder to achieve a Na2O weight content of less than 3.0%; (2) carrying out hydrothermal treatment on the Y molecular sieve obtained in the step (1); (3) carrying out sodium ion exchange on the Y molecular sieve obtained in the step (2) in a sodium salt solution; and (4) carrying out ammonium hexafluorosilicate dealuminzation silicon supplementing treatment on the Y molecular sieve obtained in the step (3), filtering, drying, and calcining to obtain the final modified Y-type molecular sieve. According to the present invention, with the method, the high-silicon and high-crystallinity modified Y molecular sieve being rich in mesoporous structure can be obtained.

Description

technical field

[0001] The invention relates to a modified Y-type molecular sieve and a preparation method thereof, in particular to a modified Y-type molecular sieve rich in mesoporous structure with high silicon and high crystallinity and a preparation method thereof. Background technique

[0002] Hydrocracking technology has many advantages such as strong feedstock adaptability, flexible production scheme, high selectivity of target products and good product quality, and plays an important role in the process of crude oil lightening and clean fuel production. For the hydrocracking process, its core is a hydrocracking catalyst, which is a typical dual-function catalyst, and its active center is composed of a hydrogenation center and a cracking center. The hydrogenation active center of the hydrocracking catalyst usually exists in the form of active metal sulfides of Group VI and Group VIII in the periodic table of elements, and the cracking active center of the hydrocracki...

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