Cultural relic fumigation method

A technology of cultural relics and fumigants, applied in the field of cultural relics fumigation, can solve the problems of cumbersome operation, danger, fluoride human bone poisoning, etc., and achieve the effect of simple operation, low cost and low pollution

Inactive Publication Date: 2017-05-24
SHANGHAI INST OF ORGANIC CHEMISTRY - CHINESE ACAD OF SCI +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although these existing methods can achieve insecticidal and sterilizing effects to a certain extent, each has its own shortcomings, for example: nitrogen kills insects for a long time, and the tolerance of different insects to high-purity nitrogen varies significantly ;Because carbon dioxide is weakly acidic, it will affect the material being processed under high humidity conditions, especially the material containing lead oxide, which will generate carbonate in a short time; ethylene oxide is an explosive substance and has Denaturation; methyl bromide has poor bactericidal ability, and since the ninth "Montreal Protocol Conference of the Parties" in 1997, developed countries have agreed to phase out the use of methyl bromide from 2005, and according to the Montreal Protocol, by 2015, my country will also The use of methyl bromide will be banned; sulfuryl fluoride is difficult to penetrate into water-containing eggs due to its hydrophobicity, so the egg killing ability is poor, and the deposition of fluoride has the risk of poisoning human bones
In addition, the greenhouse effect of sulfuryl fluoride is significant, and the greenhouse effect caused by the emission of sulfuryl fluoride is about 5000 times that of the equivalent amount of carbon dioxide! Therefore, research and development of a safe and environmentally friendly preservation method for cultural relics that can effectively prevent insects and mildew, do not affect the material of cultural relics and human health, and do not pollute the environment is a major problem that needs to be solved urgently in front of cultural relics protection workers all over the world. problem
[0006] Although the fumigation and disinfection method for cultural relics disclosed in Chinese patent CN201310403788.6 uses active ingredients in plants to replace fumigants such as cyclochloroethane and methyl bromide, and solves the problem of explosiveness, destructiveness to the environment and safety and harmlessness of the human body, but This method needs to put the plant fumigant and cultural relics into the fumigation box, and the amount of plant essential oil used for fumigation is also relatively large. In addition, high-purity nitrogen gas needs to be introduced, and a specific humidity needs to be selected for different mold disease types and cultural relic materials. Conditions and fumigation time, for example: for cultural relics made of paper, bone, and ivory, the humidity needs to be adjusted at 50-55%; for cultural relics made of textiles, wood, and leather products, the humidity needs to be adjusted at 50-60%; generally for black Molds such as Aspergillus and Aspergillus flavus need to be fumigated for 20-24 hours; therefore, this patented technology is not only cumbersome to operate, but also cannot realize one-time fumigation treatment of cultural relics of various materials and various bacterial molds in the same environment. The key is, The patented technology does not inform that the cultural relics are treated by the fumigation and disinfection method, and then placed in the cultural relics collection environment to regenerate mold

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Embodiment 1: the preparation of fumigant

[0023] 1. The compound of methyl methyl thiosulfinate and ethyl ethyl thiosulfinate:

[0024] Stir and mix methyl methyl thiosulfinate and ethyl ethyl thiosulfinate at room temperature according to the volume ratio of 1:3; abbreviated as fumigant A; determine the oral LD ​​of mice 50 >500mg / Kg, belongs to low toxicity.

[0025] 2. Compound of ethyl ethyl thiosulfinate and methyl methyl thiosulfinate:

[0026] Stir and mix ethyl ethyl thiosulfinate and methyl methyl thiosulfinate evenly at room temperature according to the volume ratio of 1:2; abbreviated as fumigant B; determine the oral LD ​​of mice 50 >500mg / Kg, belongs to low toxicity.

[0027] 3. Compound of ethyl ethyl thiosulfinate and ethyl ethyl thiosulfinate:

[0028] Stir and mix ethyl ethyl thiosulfinate and ethyl ethyl thiosulfinate at room temperature according to the volume ratio of 1:1; abbreviated as fumigant C; determine the oral LD ​​of mice 50 >500mg / Kg...

Embodiment 2

[0041] Embodiment 2: cultural relics fumigation experiment

[0042] Cultural relic material: paper

[0043] Diseases: Aspergillus and Penicillium, etc.

[0044] Fumigant: Fumigant A

[0045] Fumigation method:

[0046] Put the fumigant and cultural relic samples into the fumigation box, close the fumigation box, control the temperature in the fumigation box to 25°C, and after 36 hours of fumigation, depressurize and pump for 2 hours, open the fumigation box, and remove the cultural relic samples;

[0047] It is known from the microscope inspection that no mold has grown on the cultural relic samples after the above-mentioned fumigation treatment;

[0048] And it is known from the detection and analysis of gas chromatography and mass spectrometry (GC-Ms): there is no fumigant residue on the cultural relic samples after the above-mentioned fumigation treatment.

[0049] Place the samples of cultural relics after the fumigation treatment in this embodiment in the collection r...

Embodiment 3-1

[0052] Example 3-1: Cultural relics fumigation experiment

[0053] Cultural relic material: silk material

[0054] Diseases: Aspergillus and Penicillium, etc.

[0055] Fumigant: Fumigant C

[0056] Put the fumigant and cultural relic samples into the fumigation box, close the fumigation box, control the temperature in the fumigation box to 25°C, and after 24 hours of fumigation, depressurize and pump for 2 hours, open the fumigation box, and remove the cultural relic samples;

[0057] It is known from the microscope inspection that no mold has grown on the cultural relic samples after the above-mentioned fumigation treatment;

[0058] And by the detection and analysis of gas chromatography and mass spectrometry (GC-Ms), it is known that there is no fumigant residue on the cultural relic samples after the above-mentioned fumigation treatment;

[0059] Place the samples of cultural relics after the fumigation treatment in this embodiment in the collection room of the cultural...

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Abstract

The invention discloses a cultural relic fumigation method comprising the following operations: putting a fumigant and cultural relics into a fumigation box, fumigating for 1 to 36 hours at the temperature of 25 to 45 DEG C, then carrying out reduced pressure air exhausting for 1 to 3 hours, opening the fumigation box, and taking out the cultural relics, wherein the fumigant is a complex of a thiosulfinate compound and a thiosulfonate compound. The method not only realizes safe and effective sterilization and disinfection of the cultural relics, but also has the advantages of green environmental protection; especially, the method can realize one-time treatment of the cultural relics with a variety of materials and various bacteria and moulds in the same fumigation environment; the cultural relics after fumigation treatment can be placed for at least more than or equal to half a year in a cultural relic collection environment without regeneration of bacteria and moulds; and in addition, the method also has the advantages of simple operation, low cost, wide range of applicable materials and bacteria and moulds and the like.

Description

technical field [0001] The invention relates to a fumigation method for cultural relics, which belongs to the technical field of cultural relics preservation. Background technique [0002] As a class of items with special social value, cultural relics can reflect the culture, scientific and technological level and production conditions at that time from all aspects of society, as well as the living preferences, habits and conditions of people at all levels of society at that time. irreplaceable important role. Therefore, the protection of cultural relics is of great significance. [0003] Since a considerable part of the cultural relics in the collection are organic cultural relics of various materials, such as silk, bamboo, cotton, paper, fur, lacquered wood, etc., the organic components in the cultural relics can provide a large amount of enrichment for the growth and physiological metabolism of microorganisms and pests. Therefore, the degree of damage caused by microorg...

Claims

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Application Information

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IPC IPC(8): A61L2/20A01N41/08A01P1/00A01P3/00A61L101/40
CPCA01M13/00
Inventor 姜标张琛陶黎明周新光吴来明
Owner SHANGHAI INST OF ORGANIC CHEMISTRY - CHINESE ACAD OF SCI
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