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Preparation method of graphene oxide modified polymer cement waterproofing coating

A graphene-modified, waterproof coating technology, applied in the direction of carbon compounds, chemical instruments and methods, inorganic chemistry, etc., can solve the problems of limited effect, low coating durability and mechanical strength, and achieve impermeability and improvement. The effect of overall performance, good mechanical properties and durability

Inactive Publication Date: 2017-05-31
冠宏化工(扬州)有限公司
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AI Technical Summary

Problems solved by technology

However, because acrylate polymers are organic substances, they have limited effect on the problems of low durability and mechanical strength that have plagued the development of polymer cement waterproof coatings for a long time.

Method used

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Experimental program
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Embodiment Construction

[0020] Below in conjunction with specific embodiment, content of the present invention is described in further detail:

[0021] A preparation method of graphene oxide modified polymer cement waterproof coating, realized by the following steps:

[0022] (1) Preparation of graphene oxide:

[0023] According to the number of parts by mass, slowly add 50 parts of concentrated sulfuric acid to the mixture of 5 parts of graphite powder and 5 parts of sodium nitrate under stirring, control the temperature of the system to be less than 10°C, and slowly add 16-20 parts of potassium permanganate after adding and stirring evenly , then react at 35°C for 9 hours, heat up to 80°C and react for 1 hour, then slowly add 600 parts of deionized water, then add hydrogen peroxide with a concentration of 30%, react until no bubbles are generated, filter, wash, Adjust the pH to 7 with 25-35% NaOH, and obtain a graphene oxide solution by ultrasonication for 2 hours;

[0024] (2) Preparation of gra...

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Abstract

The invention relates to a preparation method of a graphene oxide modified polymer cement waterproofing coating. The polymer cement waterproofing coating is a dual-component aqueous building waterproofing coating prepared by adopting an acrylate polymer emulsion and cement as raw materials and adding other additives; and the polymer cement waterproofing coating has the problems of unsatisfactory mechanical performances, poor impermeability and poor durability, so the promotion and the application of the coatings are severely restricted. The excellent mechanical performances of graphene oxide substantially increase the tensile strength of a film formed by the acrylate polymer emulsion and improve the waterproof property to a certain degree; and additionally, the abundant oxygen-containing function groups of the graphene oxide adjust the growth of a cement hydration product and improve the tensile strength and the toughness of the cement hydration product, so the graphene oxide modified polymer cement waterproofing coating has the advantages of good durability, good impermeability, good physical and mechanical performances, and wide application prospect.

Description

technical field [0001] The invention relates to the technical field of waterproof coatings, in particular to a preparation method of graphene oxide modified polymer cement waterproof coatings. Background technique [0002] Polymer cement waterproof coating is a two-component water-based architectural waterproof coating made of acrylic polymer emulsion and cement as the main raw materials and other admixtures. The products are divided into Type I and Type II. Type I is mainly polymer, which is mainly used for building waterproofing projects in non-long-term flooding environments; Type II is mainly cement, and is mainly used for building waterproofing projects in long-term flooding environments. . This kind of coating not only has the extensibility and water resistance of polymer coating film, but also has the advantages of high strength of water-based gelling material and easy bonding with wet base. However, there are still problems such as unsatisfactory mechanical propert...

Claims

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Application Information

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IPC IPC(8): C04B28/00C04B14/02C01B32/198C04B111/27
CPCC04B28/00C04B14/024C04B2111/00482C04B2111/27C04B2103/50C04B2103/302C04B24/2641C04B2103/61C04B14/06C04B14/28C04B14/042
Inventor 章松吴汉勋
Owner 冠宏化工(扬州)有限公司
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