Waste-material-recycled multi-phase permanent magnet material and preparation method therefor
A technology for permanent magnet materials and waste materials, which is applied in the field of waste recycling multiphase permanent magnet materials and its preparation, can solve the problem of low maximum magnetic energy product value, and achieve the effects of improving magnetic properties, reducing costs, and high social value
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Embodiment 1
[0035] The preparation method of the multi-phase permanent magnet material reused by the waste material of the present invention comprises the following steps:
[0036] 1) Waste disposal:
[0037] First, first place the phosphor waste material in a roasting furnace for pretreatment, the treatment temperature is 600 ° C, the holding time is 2 hours, and after cooling, the ball mill is 20-80 microns to obtain the pretreatment waste material; the pretreatment waste material is added to a concentration of Mix in 5mol / L sulfuric acid. The mixture is first kept at 55°C for 7 hours, and then kept at 98°C for 1.5 hours. The mass ratio of pretreatment waste to sulfuric acid is 1:40. After cooling, soak it with water for 5 times and collect the precipitate. , and dried at a temperature of 120° C. for 1.5 hours, and then placed at a temperature of 1100° C. for 1.5 hours. After cooling, the precipitated rare earth oxide A containing Y, Ce, Tb, and Eu was obtained for subsequent use;
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Embodiment 2
[0048] The preparation method of the multi-phase permanent magnet material reused by the waste material of the present invention comprises the following steps:
[0049] 1) Waste disposal:
[0050] First, first place the phosphor waste material in a roasting furnace for pretreatment, the treatment temperature is 500 ° C, the holding time is 1 hour, and after cooling, the ball mill is 20-80 microns to obtain the pretreatment waste material; the pretreatment waste material is added to a concentration of Mix in 3 mol / L sulfuric acid, heat the mixture at 45°C for 5 hours, then heat it at 90°C for 1 hour, the mass ratio of pretreatment waste to sulfuric acid is 1:30, soak it with water for 3 times after cooling, and collect the precipitate , and dried at a temperature of 120°C for 1 hour, and then kept at a temperature of 1050°C for 1 hour, and after cooling, precipitated rare earth oxide A was obtained, which was set aside;
Embodiment 3
[0061] In this example, the rare earth permanent magnet material alloy ingot prepared by waste recycling is batched according to the following mass percentages:
[0062] Nd 27%, Y 2.7%, Ce 2.7%, Tb 0.27%, Eu 0.27%, La 0.27%, Pr 0.27%, B 3%, V 0.27%, W2.3%, and the rest is Fe. All the other preparation conditions and processes are the same as in Example 2. The mass percent content of N in the material is 1.08%.
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