Coal briquette adhesive employing defatted soybean protein as raw material and preparation method of coal briquette adhesive

A defatted soybean protein and adhesive technology, which is applied in the preparation of protein adhesives, animal glue or gelatin, adhesives, etc., can solve the problems of greatly reduced cold strength of briquettes, affecting the use of briquettes, and poor waterproof performance , to achieve the effect of low processing cost, convenient processing and good water resistance

Inactive Publication Date: 2017-06-23
瑞安市智造科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The so-called clean coal technology refers to coal gasification, liquefaction, high-efficiency coal combustion, or making anthracite coal into briquettes. As a type of clean coal, briquettes are environmentally friendly coal resources approved by the government. Among them, briquettes are sticky Mixture is the key to the preparation of briquettes, and it is also the bottleneck restricting the development of briquettes. Although the briquettes prepared by using the briquette binders on the market can meet the requirements of industrial briquettes in terms of coldness, heat strength and thermal stability, the cost Higher, especially poor waterproof performance, only absorbing a small amount of water in the air can greatly reduce the cold strength of the briquette, which will cause a lot of damage during transportation, loading and unloading, and affect the use of the briquette

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A briquette adhesive using defatted soybean protein as a raw material, the briquette adhesive is processed from the following raw materials in parts by weight:

[0029] 20 parts of cement, 80 parts of modified defatted soybean powder, 8 parts of organic bentonite, 8 parts of propolis powder, 400 parts of water;

[0030] The preparation method of the modified defatted soybean powder is as follows: add defatted soybean powder, an appropriate amount of complex enzyme and an appropriate amount of deionized water into the reaction vessel, adjust the pH to 5.5, enzymatically hydrolyze at 45°C for 2 hours, then heat to 85°C to inactivate 3min, cooled to 35°C, added 1% coupling agent and 0.5% oxidizing agent by mass of defatted soybean powder, stirred for 0.5h, filtered to remove impurities, concentrated in vacuum, and dried to obtain modified defatted soybean powder;

[0031] The compound enzyme is a mixture of cellulase, α-amylase and protease at an enzyme activity ratio of 5...

Embodiment 2

[0039] A briquette adhesive using defatted soybean protein as a raw material, the briquette adhesive is processed from the following raw materials in parts by weight:

[0040] 30 parts of cement, 120 parts of modified defatted soybean powder, 12 parts of organic bentonite, 12 parts of propolis powder, 600 parts of water;

[0041] The preparation method of the modified defatted soybean powder is as follows: add defatted soybean powder, an appropriate amount of complex enzyme and an appropriate amount of deionized water into the reaction vessel, adjust the pH to 6.0, enzymatically hydrolyze at 55°C for 2 hours, and then heat to 95°C to inactivate 2min, cooled to 35°C, added 2% coupling agent and 0.3% oxidizing agent by mass of defatted soybean powder, stirred for 1 hour, filtered to remove impurities, concentrated in vacuum, and dried to obtain modified defatted soybean powder;

[0042] The compound enzyme is a mixture of cellulase, α-amylase and protease at an enzyme activity r...

Embodiment 3

[0050] A briquette adhesive using defatted soybean protein as a raw material, the briquette adhesive is processed from the following raw materials in parts by weight:

[0051] 25 parts of cement, 100 parts of modified defatted soybean powder, 10 parts of organic bentonite, 10 parts of propolis powder, and 500 parts of water;

[0052]The preparation method of the modified defatted soybean powder is as follows: add defatted soybean powder, an appropriate amount of complex enzyme and an appropriate amount of deionized water into the reaction vessel, adjust the pH to 5.8, enzymatically hydrolyze at 50°C for 1.5h, then heat to 90°C to extinguish Live for 3 minutes, cool to 32°C, add 1.5% coupling agent and 0.4% oxidant by mass of defatted soybean powder, stir for 0.5h, filter to remove impurities, vacuum concentrate, and dry to obtain modified defatted soybean powder;

[0053] The compound enzyme is a mixture of cellulase, α-amylase and protease at an enzyme activity ratio of 5:1:1...

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Abstract

The invention relates to a coal briquette adhesive employing defatted soybean protein as a raw material and a preparation method of the coal briquette adhesive. The coal briquette adhesive is prepared by processing the following raw materials in parts by weight: 20-30 parts of cement, 80-120 parts of modified defatted soy flour, 8-12 parts of organobentonite, 8-12 parts of propolis powder and 400-600 parts of water; the preparation method of the modified defatted soy flour comprises the steps of adding the defatted soy flour, a proper amount of compound enzyme and a proper amount of deionized water to a reaction container, adjusting the pH to 5.5-6.0, carrying out enzymolysis at 45-55 DEG C for 1-2h, heating a product to 85-95 DEG C, inactivating for 2-3min, cooling to 30-35 DEG C, adding 1-2% of a coupling agent and 0.3-0.5% of an oxidizing agent on the basis of the mass of the defatted soy flour and carrying out stirring treatment for 0.5-1h; filtering out impurities, and carrying out vacuum concentration and drying to obtain the modified defatted soy flour, wherein the compound enzyme is a mixture of cellulose, alpha-amylase and protease. The adhesive has good water resistance and bonding property; main raw materials all are natural raw materials; the coal briquette adhesive is wide in source, convenient to process and low in processing cost; the adhesive is long in expiration date; and the coal briquette processed by the coal briquette adhesive is high in quality and not easy to mildew and deliquescence caused by moisture absorption is not easily caused.

Description

technical field [0001] The invention relates to a briquette adhesive using defatted soybean protein as a raw material and a preparation method thereof. Background technique [0002] As China's main energy resource, coal will always occupy a dominant position in the short term, but environmental problems such as greenhouse effect and smog caused by its combustion products have gradually attracted people's attention, and it is necessary to vigorously develop clean coal technology. [0003] The so-called clean coal technology refers to coal gasification, liquefaction, high-efficiency coal combustion, or making anthracite coal into briquettes. As a type of clean coal, briquettes are environmentally friendly coal resources approved by the government. Among them, briquettes are sticky Mixture is the key to the preparation of briquettes, and it is also the bottleneck restricting the development of briquettes. Although the briquettes prepared by using the briquette binders on the ma...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J189/00C09J11/04C09J11/08C08H1/00
CPCC08H1/00C09J11/04C09J11/08C09J189/00C08L5/00C08K3/346
Inventor 金羽彤
Owner 瑞安市智造科技有限公司
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