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Winding-used resin with high NOL ring tensile strength

A tensile strength, epoxy resin technology, applied in the field of resin in winding process, can solve the problems of low test value, unable to form a good interface, and the fiber cannot be stressed as a whole at the same time, so as to achieve the effect of improving performance

Inactive Publication Date: 2017-06-30
HENGSHEN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] ①Under high tension winding, the resin volume content of the NOL ring produced by the winding process is lower than that of other molding processes, generally below 35%. With such a small resin content, the resin cannot protect the fiber well during the test process. The fiber cannot be stressed as a whole at the same time, so the test value is low;
[0005] ② Carbon fiber is an inorganic material, and epoxy resin is an organic material. When the two are combined, they cannot form a good interface, resulting in low test results

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] The dosage of each component in the resin system:

[0018] type name Dosage resin Bisphenol A epoxy (epoxy value 0.51) 100 parts by weight Hardener Methyl Nadic Anhydride 90 parts by weight Accelerator DMP-30 2 parts by weight coupling agent KH-560 1 part by weight

[0019] Weigh the various resin components according to the above proportions, mix them evenly at 30°C until there are no filaments, and put the resin upside down in the glue tank, and the temperature of the glue tank is set at 30°C.

[0020] The viscosity of the entire resin system is between 200-400cps (30°C). The pot life of this resin system at 30°C is >8h. After 8h at 30°C, the viscosity of the resin system is 650cps, which is still satisfactory for the winding process.

[0021] Using T700SC-12K fiber, prepare the NOL ring sample according to the requirements of the single ring method in the GB / T 1458 standard. After the preparation is completed, it ...

Embodiment 2

[0024] The dosage of each component in the resin system:

[0025] type name Dosage resin Bisphenol A epoxy (epoxy value 0.54) 100 parts by weight Hardener Methylhexahydrophthalic anhydride 85 parts by weight Accelerator 2E4-MZ-CN 2 parts by weight coupling agent KH-550 1 part by weight

[0026] Weigh the various resin components according to the above proportions, mix them evenly at 30°C until there are no filaments, and put the resin upside down in the glue tank, and the temperature of the glue tank is set at 30°C.

[0027] The viscosity of the entire resin system is between 200-400cps (30°C). The pot life of this resin system at 30°C is >8h. After 8h at 30°C, the viscosity of the resin system is 750cps, which is still sufficient for the winding process.

[0028] Using T700SC-12K fiber, prepare the NOL ring sample according to the requirements of the single ring method in the GB / T 1458 standard. After the preparation is co...

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Abstract

The invention discloses winding-used resin with high NOL ring tensile strength. The resin system comprises the following raw materials in parts by weight: 100 parts of epoxy resin, 60-90 parts of a curing agent, 0-5 parts of an accelerator and 0-5 parts of a coupling agent. In the invention, a silane coupling agent is introduced into the resin system and is a type of organosilicon compounds with molecules containing inorganic and organic groups simultaneously, so that a 'molecular bridge' is erected between an interface of a carbon fiber which is an inorganic matter and an interface of epoxy resin which is an organic matter, and the two materials with intervallic properties are connected with each other, so that the property of a composite material is improved. The NOL ring tensile strength of the prepared resin can achieve the comparatively high level of the industry, is higher than that in documentary records by about 20% and can reach 3,000 MPa or higher.

Description

technical field [0001] The invention relates to a resin suitable for winding technology, in particular to a winding resin with high tensile strength of NOL rings. Background technique [0002] Among many composite material molding processes, fiber wet winding is a continuous fiber bundle impregnated with resin, which is precisely wound on a rotating mandrel according to a predetermined path under tension control, cured according to a certain specification, and demolded after curing. Filament winding has the advantages of maintaining fiber continuity and exerting fiber integrity for barrel-shaped parts, such as various pressure vessels. At the same time, filament winding molding technology can better realize the combination of low cost and high efficiency, and has become an important molding method for composite materials, and is widely used in the fields of aerospace and weapons. The test of the tensile strength of the NOL ring can well simulate the state of the barrel subj...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08K5/5435C08K7/06C08K5/544
CPCC08K5/5435C08K5/544C08K7/06C08L63/00
Inventor 焦自保单瑞俊钟元伟朱珊珊
Owner HENGSHEN