Partition wall and method for making same, repair method of partition wall, repaired partition wall, optical element
A repair method and a technology for dividing walls, applied in the field of optical components, can solve problems such as inability to evenly coat ink
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[0404] The present invention will be described in more detail below using examples, but the present invention is not limited to these examples. In addition, Examples 1-10, 14-23 are examples, and Examples 11-13, 24-26 are comparative examples. In addition, in the following description, unless otherwise specified, "part" and "%" mean "part by mass" and "% by mass", respectively.
[0405] Each measurement was performed by the following method.
[0406] (number average molecular weight (Mn) and weight average molecular weight (Mw))
[0407] Using a commercially available GPC measuring device (manufactured by Tosoh Corporation, device name: HLC-8320GPC), the coagulation of various monodisperse polystyrene polymers with different degrees of polymerization commercially available as a standard sample for molecular weight measurement was measured. Gel Permeation Chromatography (GPC). A calibration curve was prepared based on the relationship between molecular weight of polystyrene ...
manufacture example 1
[0443] (Production Example 1: Production of Lyophobic Compound (A1-1))
[0444] Compound (a11) (in compound (a1), R 1 and R 2 is methyl, R 41 , R 51 , R 71 , R 81 is a hydrogen atom, R 61 A compound having a structure shown in formula (a1-1), X being an oxygen atom, n being 1, and m being 1; manufactured by Ciba Specialty Chemicals Company, trade name: IRGACURE 2959) 2.5 g and triethylamine 2.3 g in dichloro 62 mL of methane was mixed and dissolved to obtain a solution. A solution obtained by dissolving 1.2 g of methacryloyl chloride (compound (b11)) in 8 mL of dichloromethane was added dropwise to this solution while stirring the solution at 0°C. After the dropwise addition, stirred at 0° C. for 1 hour to obtain compound (c11) (in compound (c1), R 1 and R 2 is methyl, R 42 , R 52 , R 72 , R 82 is a hydrogen atom, R 62 A solution of a compound having a structure represented by formula (c1-1), X being an oxygen atom, n being 1, m being 1, and Z being a methacryloy...
manufacture example 2
[0454] (Production Example 2: Production of Lyophobic Compound (A1-2))
[0455] In 2.4g of 2-butanone, compound (m1-1) 0.90g, 2-hydroxyethyl methacrylate 0.03g and styrene 0.08g in n-dodecyl mercaptan 0.035g and 2,2'- The reaction was carried out at 50° C. for 24 hours in the presence of 0.005 g of azobis(2,4-dimethylvaleronitrile). After cooling to room temperature (20-25°C), add 0.03g of 2-acryloyloxyethyl isocyanate, 0.0001g of dibutyltin dilaurate and 0.0017g of 2,6-di-tert-butyl-p-cresol. Down reaction 24 hours, obtain the 2-butane of the lyophobic property compound (A1-2) that has following formula unit (u1-1-1), unit (u1-2-1) and unit (u1-3-2) Ketone solution. The 2-butanone solution of the obtained lyophobic compound (A1-2) was dropped into hexane to precipitate, and the obtained solid was vacuum-dried to obtain a powdery lyophobic compound (A1-2 ) 0.44g.
[0456]
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