A kind of flexible substrate, preparation method and application thereof
A flexible substrate and flexible display technology, applied in the fields of semiconductor/solid-state device manufacturing, organic semiconductor devices, electric solid-state devices, etc. The effect of short interruption time
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[0025] Please refer to the attached figure 2 , which is a flow chart of a method for preparing a flexible substrate provided in an embodiment of the present application. Depend on figure 2 Visible, described method comprises the following steps:
[0026] S101: Mixing hydroxyazobenzene and the first chopped cellulose to prepare a hydroxyazobenzene composition.
[0027] The hydroxyazobenzene is uniformly mixed with the first chopped cellulose, so that the hydroxyazobenzene adheres to the surface of the first chopped cellulose, forming a form in which the hydroxyazobenzene wraps the first chopped cellulose, and the hydroxyazobenzene is obtained. Azobenzene composition. Wherein, hydroxyazobenzene can be p-hydroxyazobenzene (4-hydroxyazobenzene) or hydroxyazobenzene compounds, and the general structural formula is R group can be -H, -CH 3 , -NO 2 、-OCH 3 or -NH 2 etc., the hydroxyazobenzene in the application requires stronger polarity; the first chopped cellulose is bac...
Embodiment 1
[0058] A kind of preparation method of flexible substrate, get respectively 2g hydroxyazobenzene, 0.1g the first chopped cellulose (length mean value is in 10 3 nm), 2.5g poly 4-vinylpyridine, 0.15g second chopped cellulose (average length in 10 3 nm) and 10g of PDMS; mixed hydroxyazobenzene and the first chopped cellulose to make a hydroxyazobenzene composition; mixed poly-4-vinylpyridine and the second chopped cellulose to make poly-4-vinyl Pyridine composition; mix hydroxyazobenzene composition, poly-4-vinylpyridine composition and PDMS, and co-extrude to obtain a flexible substrate with a thickness of 1 mm. The test shows that the rigid tensile modulus of the flexible substrate can reach 6Gpa and the flexural modulus can reach 700Mpa, which meets the requirements for the use of flexible QLEDs.
Embodiment 2
[0060] A kind of preparation method of flexible substrate, get respectively 2g hydroxyazobenzene, 0.1g the first chopped cellulose (length mean value is in 10 3 nm), 2.5g poly 4-vinylpyridine, 0.15g second chopped cellulose (average length in 10 3 nm) and 10g of PDMS; mixed hydroxyazobenzene and the first chopped cellulose to make a hydroxyazobenzene composition; mixed poly-4-vinylpyridine and the second chopped cellulose to make poly-4-vinyl Pyridine composition; PDMS was dissolved in 25ml of n-hexane, hydroxyazobenzene composition and poly-4-vinylpyridine composition were added to the PDMS n-hexane solution, and mixed evenly; co-extruded to obtain a flexible film with a thickness of 0.8mm substrate. The test shows that the rigid tensile modulus of the flexible substrate can reach 6Gpa and the flexural modulus can reach 700Mpa, which meets the requirements for the use of flexible QLEDs.
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