Technology of purifying metallurgical industry wastewater
A technology for metallurgical industry and wastewater, applied in metallurgical wastewater treatment, water/sewage treatment, chemical instruments and methods, etc., can solve the problems of high cost, slow purification, large energy consumption, etc., achieve easy magnetization, short cycle, energy low consumption effect
Inactive Publication Date: 2017-12-15
江苏天诺环境工程技术开发有限公司
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Problems solved by technology
The disadvantage of using this method is that the purification of metallurgical industrial wastewater needs to be carried out at high temperature, which requires a lot of energy: adding divalent and ferric iron salts, the cost is high; the purification speed is slow and the purification cycle is long; the generated ferrite waste residue has no Use, only for stockpiling, the continuous increase of sediment takes up a lot of space, improper storage will cause secondary pollution
Method used
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Experimental program
Comparison scheme
Effect test
Embodiment 1
[0010] A process for purifying metallurgical industrial wastewater, comprising the following steps: a process for purifying metallurgical industrial wastewater, adding divalent iron salts at alkaline normal temperature, and aerating and stirring for 20 to 40 seconds to generate MeO·Fe 2 o 3 -Fe 3 o 4 Solid solution, because the metal ions in the wastewater enter the solid solution lattice, and the suspended matter is adsorbed and wrapped to form ferrite sediment, so that the wastewater can be purified. Add polar hydrocarbon acid and non-polar hydrocarbon oil or water to the ferrite sediment for surface treatment, so that the ferrite particles can be stably transferred into the oil phase or water phase to form a ferrofluid.
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The invention discloses a technology of purifying metallurgical industry wastewater. The technology comprises the following steps: adding bivalent iron salt at normal temperature; adjusting pH; stirring to generate a MeO.Fe2O3-Fe3O4 solid solution shown in the description. Since metal ions in the wastewater enter the crystal lattice of the solid solution, the suspended solids are adsorbed and coated to form ferrite sediment, and thus the wastewater is purified. A polar surfactant and hydrocarbon oil or water are added into the sediment for surface treatment so that the particles are transferred into an oil phase or water phase to form ferromagnetic fluid. The raw materials are cheap and easily available, the energy consumption is low, the period is short, and waste residue is avoided. The obtained magnetic fluid is easy to magnetize, hard to saturate and free of residual magnetism, and thus is suitable for treating magnetism wastewater.
Description
technical field [0001] The invention relates to a process for purifying metallurgical industrial wastewater. Background technique [0002] In the prior art, ferrite is used to purify metallurgical industrial wastewater by adding divalent and trivalent iron salts under alkaline high temperature to produce ferrite to purify metallurgical industrial wastewater. The disadvantage of using this method is that the purification of metallurgical industrial wastewater needs to be carried out at high temperature, which requires a lot of energy: adding divalent and ferric iron salts, the cost is high; the purification speed is slow and the purification cycle is long; the generated ferrite waste residue has no It is only used for stockpiling, and the continuous increase of sediment takes up a lot of space, and improper storage will cause secondary pollution. [0003] Therefore, it is of great practical significance to improve the shortcomings of the appeal and study a method that can pu...
Claims
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IPC IPC(8): C02F1/62H01F1/44H01F41/00C02F103/16
CPCC02F1/62C02F2103/16H01F1/445H01F41/00
Inventor 肖护兵张玉贞权栋
Owner 江苏天诺环境工程技术开发有限公司