A kind of whisker-filled polycarbonate and polyethylene terephthalate composite material with high thermal stability and preparation method thereof
A polyethylene terephthalate and high thermal stability technology, which is applied in the field of polycarbonate and polyethylene terephthalate composite materials, can solve the problems of uneven product performance and achieve excellent thermal stability properties, improved thermal stability, and simple composition
Active Publication Date: 2020-04-07
宁波甬强科技有限公司
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Problems solved by technology
This will make the performance of the product non-uniform, and each thermal history will make the performance of the product change
Method used
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Embodiment 1-1
[0034] The aqueous solution of 1g of calcium sulfate whiskers and 0.5g of sodium dihydrogen phosphate was ultrasonically oscillated at room temperature for 30 minutes, dried in an oven, fully dried and ground before use.
Embodiment 1-2
[0036] An aqueous solution of 20 g of calcium sulfate whiskers and 2 g of sodium dihydrogen phosphate was ultrasonically oscillated at room temperature for 30 minutes, dried in an oven, fully dried and ground before use.
Embodiment 1-3
[0038] The aqueous solution of 5 g of calcium sulfate whiskers and 1 g of sodium dihydrogen phosphate was ultrasonically oscillated at room temperature for 30 minutes, dried in an oven, fully dried and ground before use.
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The invention discloses a whisker-filled polycarbonate-polyethyleneterephthalate composite with high thermal stability and a preparation method thereof. The polycarbonate-polyethyleneterephthalate composite PC-PET-Ca is a blend of polycarbonate, polyethylene terephthalate and a pretreated calcium sulfate whisker in a mass ratio of (80-60): (20-40): (1-40), wherein the pretreated calcium sulfate whisker is a compound prepared by compounding a calcium sulfate whisker and sodium dihydrogen phosphate in an aqueous solution. The method comprises the following concrete steps: adding above raw materials into a melt-mixing device and carrying out melt-mixing at 240 to 280 DEG C to obtain a mixture; and discharging the mixture from the melt-mixing device, cooling the mixture to normal temperature and carrying out crystallization. The PC-PET compound of the invention greatly improves the thermal stability of PC-PET and ensures that the thermal stability of the filled composite is remarkably improved.
Description
technical field [0001] The invention belongs to the technical field of macromolecular materials, and relates to a polycarbonate and polyethylene terephthalate composite material with high thermal stability and a preparation method thereof, especially filling PC by adding pretreated calcium sulfate whiskers / PET to obtain polycarbonate and polyethylene terephthalate composite PC-PET-Ca with high thermal stability. Background technique [0002] Fiber reinforced composites are currently the most widely used composite materials. As a new type of reinforcing agent, inorganic whiskers can also be used in thermosetting resins, thermoplastic resins, rubber and other polymers, and can produce high-performance engineering plastics, special composite materials, etc. It plays a very important role in the manufacture of composite materials. Value, broad market and applied research. [0003] When PC is melt blended with PET, a transesterification reaction occurs to produce a block polye...
Claims
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IPC IPC(8): C08L69/00C08L67/02C08K9/02C08K7/08C08K3/30
CPCC08L69/00C08L2201/08C08L67/02C08K9/02C08K7/08C08K2003/3045
Inventor 李勇进吴涛
Owner 宁波甬强科技有限公司



