Method for preparing electrothermal film by graphene aqueous slurry

A water-based, electrothermal film technology, applied in the direction of electric heating devices, ohmic resistance heating, electrical components, etc., can solve the problems of high price, increased manufacturing cost, low size matching, etc., to achieve faster dissolution speed, small structural impact, Good film-forming effect

Active Publication Date: 2016-08-24
DEYANG CARBONENE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the actual application process of this patent, there are still the following defects: 1. Carbon black powder and graphite powder are used as heating materials. The mixture of the two is difficult to grind and disperse to the required fineness, and forms a good conductive network connection; 2. Carbon black and graphite do not conduct heat, and conduct heat in the form of contact, while the stainless steel strip electrode and copper strip electrode in the electrode group used , aluminum strip electrodes, etc. are all heat-conducting ma

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A kind of method utilizing graphene water-based slurry to prepare electrothermal film, comprises the following steps:

[0039] (1) Add deionized water and amine compounds to the acrylic resin in proportion. The mass ratio of acrylic resin to deionized water and amine compounds is 60:140:10-30. The amine compounds are ammonia water and fatty amine compounds. , alcohol amine compounds, amide compounds or alicyclic amine compounds, etc.; after the addition is completed, the acrylic resin is uniformly dissolved in a stirring manner at a temperature of 60-80 degrees, and the water-soluble acrylic resin is obtained after dissolution.

[0040] (2) Add graphene and additives to the water-soluble acrylic resin to obtain a mixed solution, and then perform high-speed dispersion and mixing on the mixed solution to obtain a homogeneous dispersion. Among them, the mass ratio of graphene to acrylic resin is 1:5-30, and graphene needs to be hydrophilized before use. The treatment metho...

Embodiment 2

[0047] A kind of method utilizing graphene water-based slurry to prepare electrothermal film, comprises the following steps:

[0048] (1) Add deionized water and ammonia water to the acrylic resin in proportion. The mass ratio of acrylic resin to deionized water and ammonia water is 60:140:10. After the addition is completed, dissolve it evenly at a temperature of 60 degrees by stirring Acrylic resin, after dissolving to obtain water-soluble acrylic resin.

[0049] (2) Add graphene and additives to water-soluble acrylic resin, the mass ratio of graphene to acrylic resin is 1:5, additives include wetting and dispersing agent, defoaming agent, substrate wetting agent, antifreeze and After the antifungal agent is added, a mixed solution is obtained, and then the mixed solution is dispersed and mixed by ball milling to obtain a homogeneous dispersion. Among them, graphene needs to be hydrophilized before use, and the treatment method is ultrasonic dispersion in sodium dodecylbenz...

Embodiment 3

[0054] A kind of method utilizing graphene water-based slurry to prepare electrothermal film, comprises the following steps:

[0055] (1) Add deionized water and fatty amine compounds to the acrylic resin in proportion. The mass ratio of acrylic resin to deionized water and fatty amines is 60:140:30. The acrylic resin is uniformly dissolved by stirring, and the water-soluble acrylic resin is obtained after dissolution.

[0056] (2) Add graphene and additives to the water-soluble acrylic resin. The mass ratio of graphene to acrylic resin is 1:30. The additives include film-forming additives, antifreeze agents and antifungal agents. After the addition is completed, a mixed liquid, and then the mixed liquid was subjected to high-speed shear emulsification, dispersion and mixing to obtain a homogeneous dispersion. Among them, graphene needs to be hydrophilized before use, and the treatment method is high-speed shear emulsification in polyvinyl alcohol solution.

[0057] (3) Add ...

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Abstract

The invention discloses a method for preparing an electrothermal film by graphene aqueous slurry. The method comprises the steps of: (1) adding deionized water and an amine compound to solid acrylic resin to obtain water-soluble acrylic resin; (2) adding graphene and an auxiliary agent to the water-soluble acrylic resin, and dispersing and mixing the water-soluble acrylic resin to obtain a homogeneous dispersion liquid; (3) adding a binder to the homogeneous dispersion liquid, and stirring and mixing the homogeneous dispersion liquid to obtain the graphene aqueous slurry; and (4) coating a film-forming carrier with the graphene aqueous slurry to form a graphene conducting layer and drying the graphene conducting layer to obtain the electrothermal film. The electrothermal film with excellent thermal conductivity and electrical conductivity can be prepared with the aqueous slurry; no organic solvent is added in the preparation process; the problem of VOC emission does not exist; and the method is safe and environment-friendly. Compared with other technologies that require special modification of filler, the preparation method is simple; coupling treatment is not carried out on an exothermic material by adoption of a coupling agent; the existing production technology can be simplified; and the production cost is reduced.

Description

technical field [0001] The invention relates to a novel electrothermal material, in particular to a method for preparing an electrothermal film by using graphene water-based slurry. Background technique [0002] The electrothermal film heating system is different from the point heating system represented by radiators, air conditioners, and radiators and the line heating system represented by heating cables. It is a low-carbon heating system developed by modern aerospace technology in the field of surface heating. Technology Products. [0003] The principle of electric heating film heating is that under the action of an electric field, the carbon molecular clusters in the heating element produce "Brownian motion", and severe friction and impact occur between carbon molecules, and the heat energy generated is transmitted to the outside in the form of far-infrared radiation and convection. , the conversion rate of electric energy and heat energy is as high as 98%. The action ...

Claims

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Application Information

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IPC IPC(8): H05B3/14H05B3/20
CPCH05B3/14H05B3/20
Inventor 简璐赵景浩尹天平姚林高华
Owner DEYANG CARBONENE TECH
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