Isomerization catalyst, method for producing linear olefin, and method for producing compound
A technology for straight-chain olefins and a production method, which is applied in the directions of isomerization to hydrocarbon production, carbon compound catalysts, physical/chemical process catalysts, etc., can solve the problems of insufficient yield, reduced product purity, catalyst deterioration, etc., and achieves good efficiency. , the effect of suppressing catalytic degradation
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Embodiment 1
[0105] 0.3 cc of an H-β zeolite catalyst (manufactured by Tosoh Corporation, Si / Al=250 (mol / mol)) was filled in a tubular reactor (manufactured by SUS tube). The tube reactor had an inner diameter of 14 mm and a total length of 60 cm. Fill the upper and lower parts of the catalyst with glass beads. The glass beads had an average particle diameter of 1 mm. After connecting this reactor to a circulation reactor, the temperature in the reactor was raised to 350° C. using an electric furnace. A raw material (raw material gas) containing olefin, an oxygen / nitrogen mixed gas (oxygen concentration 10%), and water (steam) were supplied to the heated reactor. The isomerization reaction of olefins is carried out in the above steps.
[0106] In addition, the inflow rates of the raw material gas, air and water (steam) into the reactor were as follows. In addition, the oxygen concentration in the gas supplied to a reactor was 8.5 volume%, and the water concentration was 7.1 volume%. T...
Embodiment 2
[0114] Isomerization of olefins was carried out in the same manner as in Example 1 except that a zeolite catalyst of H-ZSM-5 (manufactured by Tosoh Corporation, Si / Al=940 (mol / mol)) was used as the isomerization catalyst. reaction.
Embodiment 3
[0116] The isomerization reaction of olefins was carried out in the same manner as in Example 1 except that the SAPO-34 zeolite catalyst prepared in reference to Comparative Example 2 of JP-A-2012-91997 was used as the isomerization catalyst.
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