Sintering method for precious metal layer on surface of ceramic or glass

A technology of glass surface and sintering method, which is applied in the field of sintering of precious metal layers on ceramic or glass surfaces, which can solve the problems of harmful effects on the environment and people's health, large amount of organic solvents used, and thin thickness of fired silver film, so as to achieve the goal of not falling off easily , Avoid flocculation, thickness controllable effect

Active Publication Date: 2018-01-12
HANDAN COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There is another silver paste method. In this method, silver powder is dispersed into an organic solvent to make a silver paste, which is coated on the surface of the ceramic and then sintered to make the silver adhere. In this process, a large amount of organic solvent is used. There will be a large amount of VOC, which will cause harmful effects on the environment and people's health. At the same time, the thickness of the fired silver film is relatively thin

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment 1: The sintering method of the noble metal layer on the ceramic or glass surface is as follows.

[0026] The parts by weight of the primer components are: 60 parts of 0.5-2.0 micron silver powder, 5 parts of lead-free low-temperature glass powder with a softening point of 600°C, 3 parts of borax, 1 part of Tween 20, 15 parts of polyethylene glycol 400, 15 parts of water.

[0027] The parts by weight of the body paste components are: 80 parts of 0.5-2.0 micron silver powder, 2 parts of lead-free low-temperature glass powder with a softening point of 600 DEG C, 3 parts of Tween 20, 10 parts of polyethylene glycol 400, and 20 parts of water.

[0028] The parts by weight of the batter components are: 90 parts of 0.5-2.0 micron silver powder, 1.0 part of lead-free low-temperature glass powder with a softening point of 600°C, 5 parts of Tween 20, 5 parts of polyethylene glycol 400, and 10 parts of water.

[0029] The preparation methods are as follows: add water i...

Embodiment 2

[0032] Embodiment 2: The sintering method of the noble metal layer on the ceramic or glass surface is as follows.

[0033] The parts by weight of the primer components are: 70 parts of 4-6 micron silver powder, 4 parts of lead-free low-temperature glass powder with a softening point of 500°C, 1 part of borax, 3 parts of Tween 20, 10 parts of polyethylene glycol 1200, 18 parts of water.

[0034] The parts by weight of the body paste components are: 75 parts of 5-10 micron silver powder, 1 part of lead-free low-temperature glass powder with a softening point of 700 DEG C, 5 parts of Tween 20, 5 parts of polyethylene glycol 800, and 18 parts of water.

[0035] The parts by weight of the batter components are: 80 parts of 1-3 micron silver powder, 1.5 parts of lead-free low-temperature glass powder with a softening point of 600 DEG C, 3 parts of Tween 20, 8 parts of polyethylene glycol 600, and 2 parts of water.

[0036] The preparation methods are as follows: add water into a co...

Embodiment 3

[0039] Embodiment 3: The sintering method of the noble metal layer on the ceramic or glass surface is as follows.

[0040] The parts by weight of the primer components are: 55 parts of 6-10 micron silver powder, 3.5 parts of lead-free low-temperature glass powder with a softening point of 550° C., 2 parts of borax, 4 parts of Tween 20, 12 parts of polyethylene glycol 1000, 18 parts of water.

[0041]The parts by weight of the body paste components are: 77 parts of 1-5 micron silver powder, 2.5 parts of lead-free low-temperature glass powder with a softening point of 500° C., 4 parts of wetting agent Hydropalat 875, 7 parts of polyethylene glycol 1200, and 17 parts of water. share.

[0042] The parts by weight of the batter components are: 82 parts of 6-10 micron silver powder, 0.8 part of lead-free low-temperature glass powder with a softening point of 700 DEG C, 2 parts of Tween 20, 8 parts of polyethylene glycol 1000, and 12 parts of water.

[0043] The preparation methods...

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Abstract

The invention discloses a sintering method for a precious metal layer on the surface of ceramic or glass. The sintering method adopts three slurries, i.e., a bottom slurry, a body slurry and a surfaceslurry. The sintering method comprises the following steps: coating the bottom slurry onto the surface of the ceramic or the glass, carrying out drying in the air, and carrying out sintering; then coating the body slurry, carrying out drying in the air, and carrying out sintering; and coating the surface slurry, carrying out drying in the air, and carrying out sintering so as to form the preciousmetal layer on the surface of the ceramic or the glass, wherein the bottom slurry comprises the following components in parts by weight: 50 to 70 parts of precious metal powder, 3 to 5 parts of glasspowder, 1 to 5 parts of borax, 1 to 5 parts of a wetting agent, 10 to 20 parts of polyethylene glycol and 15 to 20 parts of water; the body slurry comprises the following components in parts by weight: 70 to 80 parts of precious metal powder, 1 to 3 parts of glass powder, 1 to 5 parts of a wetting agent, 5 to 10 parts of polyethylene glycol and 15 to 20 parts of water; and the surface slurry comprises the following components in parts by weight: 80 to 90 parts of precious metal powder, 0.5 to 1.5 parts of glass powder, 1 to 5 parts of a wetting agent, 5 to 10 parts of polyethylene glycol and2 to 20 parts of water. The method provided by the invention can firmly attach the precious metal layer onto porcelain, has controllable and uniform thickness, and is friendly to the environment.

Description

technical field [0001] The invention relates to the technical field of surface processing of ceramics or glassware, in particular to a method for sintering a precious metal layer on the surface of ceramics or glass. Background technique [0002] Ceramic or glassware is one of the most widely used utensils in people's daily life. With the improvement of living materials and cultural level, the requirements for the ornamental and functional requirements of this kind of utensils are getting higher and higher. Traditional ceramics, Glass products can no longer meet people's needs. [0003] Gold and silver are precious metals that people love. They are very decorative, such as making silver ornaments, etc.; at the same time, silver also has bactericidal properties, such as making silver bowls and other tableware, so as to play the role of disinfection, sterilization and preservation . However, sterling silver tableware uses a large amount of silver and the cost is relatively hi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/89C03C17/34
Inventor 任云王博谢鹏涛杨儒林葛宝仑
Owner HANDAN COLLEGE
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