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Method for treating methyl orange wastewater

A methyl orange, wastewater technology, applied in water/sewage treatment, chemical instruments and methods, oxidized water/sewage treatment, etc.

Inactive Publication Date: 2018-02-23
TAIYUAN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to solve the problems existing in the existing dye wastewater treatment method, the present invention provides a method for treating methyl orange wastewater

Method used

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  • Method for treating methyl orange wastewater

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Embodiment 1

[0022] Weigh 28.4gNa 2 SiO 3 9H 2 O in a 250mL beaker, add 100mL of water to dissolve. Weigh 24.9gCo(OAC) 2 4H 2 O in another 250mL beaker, add 100mL of water to dissolve, slowly add to the sodium silicate solution under stirring, age in a water bath at 80-90°C for 30 minutes, cool to room temperature, filter with suction, and wash Until the filtrate became neutral, it was dried in a drying oven at 105°C for 5 hours to obtain 15.0 g of gray-blue cobalt silicate.

[0023] Prepare methyl orange wastewater, take 100mL concentration to be 10mg·L -1 Add 0.0270g of cobalt silicate to a 250mL Erlenmeyer flask, place it in a water bath at 35°C, and add 30% (mass fraction) hydrogen peroxide under constant temperature magnetic stirring to make the hydrogen peroxide in the wastewater The concentration is 0.0360mol L -1 , reacted for 60 minutes, the color removal rate of methyl orange wastewater reached 95.29%.

Embodiment 2

[0025] In order to prove the influence of temperature on the chroma removal rate of methyl orange wastewater, the synthesis was carried out according to the parameters in Table 1.

[0026] Table 1

[0027]

[0028] It can be seen from Table 1 that as the temperature increases, the chromaticity removal first increases and then decreases slowly, reaching the highest at 35°C; when there is no cobalt silicate in the methyl orange wastewater, the chromaticity removal rate is 0.

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Abstract

The invention relates to the field of dye wastewater treatment and in particular to a method for treating methyl orange wastewater. The method comprises the following steps: putting cobaltous silicateand hydrogen peroxide into methyl orange wastewater, and performing an oxidation reaction, thereby removing chroma of the methyl orange wastewater. The inventor finds that hydrogen peroxide can be decomposed by cobaltous silicate to generate hydroxyl radicals, so that the cobaltous silicate is prepared by using a sedimentation method and is applied to catalyze the hydrogen peroxide to oxidize anddegrade methyl orange simulated wastewater, and results show that the cobaltous silicate has excellent catalysis activity. The cobaltous silicate is not dissolved in water, belongs to heterogeneous catalysts, can be recycled and repeatedly used without adjusting the pH value of wastewater, and is free of secondary pollution. In addition, hydrogen peroxide is an environmental-friendly cleaning oxidant, and excessive hydrogen peroxide can be decomposed into water and oxygen by the cobaltous silicate, therefore, a cobaltous silicate-hydrogen peroxide heterogeneous catalysis method has the potential of becoming an environmental-friendly wastewater treatment method.

Description

technical field [0001] The invention relates to the field of dye wastewater treatment, in particular to a method for treating methyl orange wastewater. Background technique [0002] The treatment methods of dye wastewater include physical method, chemical method and biological method; chemical method can be divided into chemical coagulation method, electrochemical method and advanced oxidation method. Fenton oxidation is the main and most commonly used advanced oxidation method, but it has disadvantages such as long reaction time, narrow pH range, difficult catalyst recovery, and easy to cause secondary pollution. [0003] The inventor found that cobalt silicate can decompose hydrogen peroxide to generate hydroxyl radicals, so cobalt silicate was prepared by precipitation method, and it was used to catalyze the oxidation degradation of methyl orange simulated wastewater by hydrogen peroxide. The results showed that cobalt silicate Has excellent catalytic activity. Cobalt s...

Claims

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Application Information

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IPC IPC(8): C02F1/72B01J23/75C02F101/30
CPCB01J23/75C02F1/722C02F1/725C02F2101/308
Inventor 陈志敏李敏景银兰韩靖茜
Owner TAIYUAN INST OF TECH