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Method for detecting concentration of corrosion inhibitor by spectrophotometer

A technology of spectrophotometer and corrosion inhibitor, which is applied in the direction of color/spectral characteristic measurement, measuring device, analysis material, etc., can solve the problems of poor repeatability, poor accuracy of corrosion inhibitor concentration test results, and affecting the normal operation of experiments, etc. problem, achieve reliable analysis and detection, shorten waiting time, and improve work efficiency

Inactive Publication Date: 2018-04-03
XI'AN PETROLEUM UNIVERSITY
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Problems solved by technology

[0004] For spectrophotometry, when the traditional phosphate buffer system is used to measure the concentration of corrosion inhibitors for highly hard sewage such as oil and gas well produced water, the phosphate ions in the buffer will interact with the calcium, calcium, and Magnesium plasma forms a large amount of calcium phosphate and magnesium phosphate precipitates, making the buffer solution into a non-uniform suspension, which seriously affects the normal progress of the experimental work, resulting in poor accuracy and repeatability of the corrosion inhibitor concentration test results. Difference

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  • Method for detecting concentration of corrosion inhibitor by spectrophotometer
  • Method for detecting concentration of corrosion inhibitor by spectrophotometer
  • Method for detecting concentration of corrosion inhibitor by spectrophotometer

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Embodiment Construction

[0025] The present invention will be described in detail below in conjunction with the accompanying drawings and specific embodiments.

[0026] A method for spectrophotometer detection of corrosion inhibitor concentration of the present invention comprises the following steps:

[0027] (1) Prepare color developer

[0028] Accurately weigh 0.1g of bromothymol blue in a beaker, add a small amount of ethanol to dissolve it and transfer it to a 250mL volumetric flask, clean the beaker and set the volume to the mark to obtain a 0.4g / L bromothymol blue-ethanol solution for color development agent use.

[0029] (2) Preparation of tris hydrochloride buffer solution

[0030] Dissolve 25g of Tris in water, add 8mL of concentrated hydrochloric acid, and dilute to 1L with distilled water.

[0031] (3) Preparation of imidazoline quaternary ammonium salt corrosion inhibitor standard solution

[0032] Weigh 0.1-0.5g of imidazoline quaternary ammonium salt corrosion inhibitor into a 250mL...

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Abstract

The invention discloses a method for detecting the concentration of a corrosion inhibitor by a spectrophotometer. A tri-hydroxymethyl aminomethane hydrochloride buffer solution is used for providing aweak alkaline environment for a system, so that a pH value (8.0) of a buffer system is prevented from being changed, and the problems that phosphate ions in a traditional phosphate buffer solution and ions such as calcium and magnesium in produced water form a large amount of calcium phosphate and magnesium phosphate precipitates, which leads to the results that the buffer solution becomes non-uniform suspension, the accuracy of a concentration detection result of the corrosion inhibitor is poor, and the repeatability is poorer are solved; the detection result of the concentration has relatively-high accuracy and feasibility.

Description

technical field [0001] The invention belongs to the field of detection of corrosion inhibitors in oil and gas fields, and in particular relates to a method for detecting the concentration of corrosion inhibitors with a spectrophotometer. Background technique [0002] As an environment-friendly corrosion inhibitor, imidazoline quaternary ammonium salt corrosion inhibitor not only has very good corrosion inhibition performance, but also is non-toxic, non-irritating odor, good thermal stability, and has no harm to the human body and the surrounding environment. At present, it is mostly used for oil and gas well shaft anticorrosion in the process of oil and natural gas exploitation. When the imidazoline quaternary ammonium salt corrosion inhibitor is added downhole, the anticorrosion effect of the wellbore is often analyzed and evaluated by the concentration of the corrosion inhibitor in the produced water of the oil and gas well. If the amount of corrosion inhibitor added is t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/31G01N21/78
CPCG01N21/31G01N21/78G01N2021/3185
Inventor 范峥牛梦龙井晓燕赵笑男
Owner XI'AN PETROLEUM UNIVERSITY
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