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Catalytic cracking aid capable of improving octane barrels of gasoline and preparation method thereof

A catalytic cracking aid, gasoline octane number technology, applied in catalytic cracking, molecular sieve catalysts, chemical instruments and methods, etc., can solve the problems of poor production cost, poor hydrothermal stability, popularization and application, achieve good catalytic cracking performance, improve gasoline Effect of octane number, increased content

Active Publication Date: 2018-05-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As mentioned above, the synthesis of molecular sieves with high silicon-aluminum ratio is difficult to be popularized and applied in catalytic cracking catalysts due to production costs, environmental pollution, and poor hydrothermal stability caused by fine grains.

Method used

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  • Catalytic cracking aid capable of improving octane barrels of gasoline and preparation method thereof
  • Catalytic cracking aid capable of improving octane barrels of gasoline and preparation method thereof
  • Catalytic cracking aid capable of improving octane barrels of gasoline and preparation method thereof

Examples

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Embodiment approach

[0051] A specific embodiment, based on the dry basis weight of the phosphorus-aluminum inorganic binder, the phosphorus-aluminum inorganic binder includes Al 2 o 3 15-40% by weight aluminum component, with P 2 o 5 45-80% by weight of the phosphorus component and 0-40% by weight of the first clay based on dry weight, and its P / Al weight ratio is 1.0-6.0, the pH value is 1-3.5, and the solid content is 15- 60% by weight; for example including Al 2 o 3 15-40% by weight aluminum component, with P 2 o 5 A phosphorus component of 45-80% by weight and a first clay of 1-40% by weight on a dry basis; preferably containing Al 2 o 3 15-35% by weight of the aluminum component, as P 2 o 5 50-75% by weight of the phosphorus component and 8-35% by weight of the first clay on a dry basis, the P / Al weight ratio is preferably 1.2-6.0, more preferably 2.0-5.0, and the pH is preferably 1.5 -3.0.

[0052] Another specific embodiment, based on the dry basis weight of the phosphorus-alumi...

Embodiment 1

[0100] Crystallized ZSM-5 molecular sieve (produced by Catalyst Qilu Branch Company, synthesized without amine method, n(SiO 2 ) / n(Al 2 o 3 )=27) filter out mother liquor, wash with water to Na 2O content is lower than 3.0% by weight, filter to obtain filter cake; Take above-mentioned molecular sieve 100g (dry basis) and add in 1000g 2.0% NaOH solution, heat up to 65 ℃, after reacting for 30min, after rapidly cooling to room temperature, filter, wash to filtrate neutral. Then, add 800g water to the filter cake to make a slurry, add 40g NH 4 Cl, heated to 75°C, exchanged for 1h, to Na 2 O content is lower than 0.2% by weight, filters, washes, and obtains molecular sieve filter cake; Get above-mentioned molecular sieve 50g (dry basis) and add water and be mixed with the molecular sieve slurry of solid content 10% by weight, add oxalic acid 11g in stirring, then 110g hydrochloric acid (mass fraction 10%) and 92g of fluosilicic acid (mass fraction 3%) were added in parallel, ...

Embodiment 2

[0126] Crystallized ZSM-5 molecular sieve (produced by Catalyst Qilu Branch Company, synthesized without amine method, n(SiO 2 ) / n(Al 2 o 3 )=27) filter out mother liquor, wash with water to Na 2 O content is lower than 3.0% by weight, filter to obtain filter cake; Get above-mentioned molecular sieve 100g (dry basis) and add in 1500g 2.4% NaOH solution, heat up to 60 ℃, after reacting for 45min, after rapidly cooling to room temperature, filter, wash to filtrate neutral. Then, add 800g water to the filter cake to make a slurry, add 40g NH 4 Cl, heated to 75°C, exchanged for 1h, to Na 2 O content is lower than 0.2% by weight, filters, washes, obtains molecular sieve filter cake; Get above-mentioned molecular sieve 50g (dry basis) and add water and be mixed with the molecular sieve slurry of solid content 10% by weight, add citric acid 22g in stirring, then 55g sulfuric acid (mass Fraction 10%) and 280g fluosilicic acid (mass fraction 3%) were added in parallel, and the add...

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Abstract

The invention discloses a catalytic cracking aid capable of improving the octane barrels of gasoline and a preparation method thereof. The catalytic cracking aid comprises, on the basis of dry base weight, 10 to 75 wt% of a MFI-structure molecular sieve containing phosphorus and loading metal in terms of the dry base weight, 3 to 40 wt% of a phosphorus-aluminum inorganic binder in terms of the drybase weight, 1 to 30 wt% of other inorganic binder in terms of oxide, 0 to 60 wt% of second clay in terms of the dry base weight and 0.5 to 15 wt% of a metallic additive in terms of oxide, wherein the metallic additive is at least one selected from a group consisting of group-VIII metal, manganese, zinc and gallium. When the catalytic cracking aid is applied to catalytic cracking process, the octane number of the gasoline is improved by increasing the content of isohydrocarbons in gasoline, and the yield of the gasoline is almost maintained unchanged, so the octane barrels of the gasoline areimproved.

Description

technical field [0001] The disclosure relates to a catalytic cracking additive for increasing gasoline octane barrels and a preparation method thereof. Background technique [0002] In recent years, the number of domestic motor vehicles has continued to rise, supporting the strong demand for domestic gasoline terminal consumption. During the "Twelfth Five-Year Plan" period, the average annual growth rate of automobile sales is 11%, driving the demand for gasoline to maintain an average annual growth rate of 5%. It is estimated that the apparent consumption of gasoline will reach 98Mt by 2015. With the commissioning of a new round of dedicated propylene production capacity, global propylene supply will greatly outpace demand growth in the next five years. It is predicted that global propylene capacity will increase by 30Mt in the next five years, while demand growth is expected to be only 22Mt. This gap between supply and demand may lead to lower propylene prices. Driven by...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/85C10G11/05
CPCB01J29/85C10G11/05C10G2300/1037C10G2300/305C10G2300/70C10G2400/02
Inventor 任飞刘倩倩朱玉霞田辉平欧阳颖罗一斌
Owner CHINA PETROLEUM & CHEM CORP
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