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Low-cost slag washing method

A low-cost, slag washing technology, applied in the field of iron and steel metallurgy, can solve the problems of difficult sampling, difficult production organization and operation, waste of resources, etc., and achieve the effects of reducing the consumption of slag-forming materials, good desulfurization capacity, and reducing slag-forming time.

Active Publication Date: 2018-05-11
SHANDONG IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the continuous casting process in steelmaking production, after the molten steel in the ladle is cast, a part of the refining slag will remain in the ladle. At present, most steel factories pour the refining slag into the slag basin, and then mix it with the ordinary converter Waste slag is mixed and stacked in the slag yard for treatment, occupying a large amount of land resources. Due to the high content of CaO in the slag, it is difficult to use the slag on a large scale in cement, ceramics and other industries. It is mainly used for road construction, and the selling price is about A few yuan / ton
This treatment method not only seriously pollutes the environment, but also has extremely low utilization value, which wastes a lot of resources in vain.
There are also some steel mills who have done research on the recycling of hot LF furnace refining slag. However, due to the large amount of refining slag in each furnace, the amount of slag is about 20-30kg / ton of steel. All these hot LF furnace refining slags Pouring into the ladle of the next heat will cause problems such as large amount of slag and difficulty in sampling, and because there is sometimes a deviation between the casting of the molten steel tank and the time node of the converter tapping, it is difficult to fix the recovery of the refining slag at a specific point. The process point of production organization is difficult, and the process of pouring the refining slag from the molten steel ladle into the next furnace ladle brings great inconvenience to the organization and operation of the traffic, and even requires additional traffic

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Use refining slag and deoxidizer to make synthetic slag material for slag washing in the ladle after molten steel casting, and then use the finished solid synthetic slag material with higher temperature for slag washing in the next furnace tapping process Operation, the nominal capacity of the converter is 120 tons, the smelting steel type is SPHC, and the dissolved oxygen in the molten steel at the end of the converter smelting is 600ppm. The specific operation steps of preparing synthetic slag and slag washing are as follows:

[0023] 1. After the continuous casting is finished, pour out part of the refining slag in the ladle into the slag basin. There is still 5kg / ton of steel refining slag in the ladle. The composition of the refining slag is: CaO%: 45%, Al 2 o 3 : 35%, SiO 2 : 5%, MgO: 10%, FeO+MnO≤2%, S≤0.8%, P 2 o 5 ≤0.5%.

[0024] 2. Add 3kg / ton steel deoxidizer to the ladle, the deoxidizer is aluminum iron with 55% aluminum content.

[0025] 3. Blow nitro...

Embodiment 2

[0029] The refining slag and deoxidizer are used to make synthetic slag material for slag washing in the ladle after molten steel casting, and then the solid synthetic slag material with relatively high temperature is used for slag washing operation in the tapping process of the next heat. The nominal capacity of the converter is 120 tons, the smelting steel is Q690, and the dissolved oxygen in the molten steel at the end of the converter smelting is 400ppm. The specific operation steps of preparing synthetic slag and slag washing are as follows:

[0030] 1. After the continuous casting is finished, pour out part of the refining slag in the ladle into the slag basin. There is still 10kg / ton of steel refining slag in the ladle. The composition of the refining slag is: CaO%: 60%, Al 2 o 3 : 15%, SiO 2 : 15%, MgO: 4%, FeO+MnO≤2%, S≤0.8%, P 2 o 5 ≤0.5%.

[0031] 2. Add 2kg / ton steel deoxidizer to the ladle, the deoxidizer is calcium carbide.

[0032] 3. Blow nitrogen or argo...

Embodiment 3

[0036] The refining slag and deoxidizer are used to make synthetic slag material for slag washing in the ladle after molten steel casting, and then the solid synthetic slag material with relatively high temperature is used for slag washing operation in the tapping process of the next heat. The nominal capacity of the converter is 120 tons, the smelting steel is Q690, and the dissolved oxygen in the molten steel at the end of the converter smelting is 400ppm. The specific operation steps of preparing synthetic slag and slag washing are as follows:

[0037] After the continuous casting is finished, part of the refining slag in the ladle is poured into the slag basin. There is still 7kg / ton of steel refining slag in the ladle. The composition of the refining slag is: CaO%: 52%, Al 2 o 3 : 22%, SiO 2 : 10%, MgO: 7%, FeO+MnO≤2%, S≤0.8%, P 2 o 5 ≤0.5%.

[0038] Add 2.5kg / ton of steel deoxidizer into the ladle, the deoxidizer can be silicon carbide.

[0039] Blow nitrogen or ar...

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PUM

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Abstract

The invention belongs to the technical field of iron and steel metallurgy and in particular relates to a low-cost slag washing method. The low-cost slag washing method comprises the following steps: producing synthetic slag for slag washing in a steel ladle, obtained by casting molten steel, by utilizing refining slag and a deoxidant; then utilizing the produced solid-state synthetic slag with relatively high temperature for slag washing operation of a steel tapping process of the next heat. The method provided by the invention has a simple technology and is low in cost; the consumption of slag production materials is less and the heat of the refining slag is recycled; smooth production is not influenced; compared with cyclic utilization of heat-state refining slag, the low-cost slag washing method has remarkable advantages. Sulfur is effectively removed.

Description

technical field [0001] The invention belongs to the technical field of iron and steel metallurgy, in particular, the invention relates to a low-cost slag washing method. Background technique [0002] The slag washing operation in the steelmaking process is to add synthetic slag with strong adsorption and inclusion capacity into the ladle during the tapping process of the converter or electric furnace. During the tapping process, the tapping steel flow impacts the synthetic slag in the ladle and fully stirs , The molten steel is in full contact with the synthetic slag, and the synthetic slag absorbs inclusions and removes [S] in the molten steel, so that the molten steel is purified by slag washing. The slag washing material is rich in CaO and Al 2 o 3 A mixture of calcium aluminate slag and deoxidizer. [0003] In the continuous casting process in steelmaking production, after the molten steel in the ladle is cast, a part of the refining slag will remain in the ladle. At ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C7/06C21C7/064
CPCC21C7/06C21C7/0645Y02P10/20
Inventor 刘洪银孙建卫刘曌娲路峰王孝科郝帅王利袁鹏举亓伟伟王奉县
Owner SHANDONG IRON & STEEL CO LTD
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