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A kind of preparation method of the black silicon cell of rie texture

A technology of black silicon and batteries, which is applied in the field of solar cells, can solve problems such as changes in diffusion concentration, uneven surface morphology of silicon wafers, and the influence of PN junction diffusion depth, etc., to achieve absolute value improvement of efficiency, increase conversion efficiency, and additional costs low effect

Inactive Publication Date: 2020-04-10
镇江大全太阳能有限公司
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  • Abstract
  • Description
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Problems solved by technology

In the case of this textured texture, it will affect the diffusion depth of the PN junction, and the acid textured process will also cause the surface of the silicon wafer to be uneven, which further aggravates the inhomogeneity of the PN junction. As a result, the local diffusion concentration changes with the ups and downs of the suede surface, which increases the surface recombination rate of photogenerated carriers, thereby affecting the performance of the cell
[0004] Although the processes in the prior art (such as patents CN201510003710.4 and CN201520004215.0) also mention the back polishing technology, which improves the flatness of the silicon wafer surface before diffusion, thereby improving the performance of black silicon cells, these processes still use It is an existing commonly used process, which still does not take into account the influence of the suede size on the uniformity of diffusion. Therefore, the improvement of battery efficiency is limited.

Method used

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  • A kind of preparation method of the black silicon cell of rie texture
  • A kind of preparation method of the black silicon cell of rie texture

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Embodiment 1

[0023] Such as figure 2 Shown, the preparation method of the black silicon cell of a kind of RIE texturing of the present invention comprises the following steps: Step S1, removes the positive surface damage layer of black silicon chip 5, and carries out polishing treatment to the back side of black silicon chip 5; Step S2, performing phosphorus source diffusion on the surface of the black silicon wafer 5 to prepare a PN junction 4; step S3, cleaning the black silicon wafer 5, RIE texturing, and forming a nano-textured surface on the front surface of the black silicon wafer 5 3; Step S4, repairing the nano textured surface 3 of the black silicon wafer 5, to remove the loss layer in the formation process of the nano textured surface 3; Step S5, depositing anti-reflection on the front surface of the black silicon wafer 5 Film 2; step S6, respectively printing back silver and aluminum paste on the back of the black silicon wafer 5 and drying, then printing front silver on the fr...

Embodiment 2

[0035] A method for preparing a black silicon battery made of RIE texture of the present invention, its steps are substantially the same as in Example 1, the only difference is that in the step S3, a dry cleaning method is used, and a mixed gas composed of CF4 and H2 is used. The plasma etches the side of the black silicon wafer 5 to realize the etching of the PN junction 4 on the side of the black silicon wafer 5 caused by the diffusion of the phosphorus source in step S2. Specifically, the reactive gas CF4 is ionized and forms plasma under the excitation of radio frequency power. The active reactive groups formed by the plasma and excitation reach the surface of the black silicon wafer 5 under the action of the electric field, undergo a chemical reaction and generate volatile reactant SiF4, which is drawn out of the cavity by the vacuum system, thereby completing dry etching. By adjusting the volume ratio of CF4 / H2 in the mixed gas composed of CF4 and H2, the etching rate of...

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Abstract

The invention relates to an RIE texturing-based preparation method of a black silicon battery. The method comprises the following steps that: step S1, a damage layer on the front surface of a black silicon wafer is removed, and the back surface of the black silicon wafer is polished; step S2, phosphorus source diffusion is performed on the surface of the black silicon wafer, so that a PN junctioncan be prepared; step S3, the black silicon wafer is cleaned, RIE texturing is performed on the cleaned black silicon wafer, and a nano texturized surface is formed on the front surface of the black silicon wafer; step S4, the nano texturized surface of the black silicon wafer is repaired, so that a loss layer during the formation of the nano texturized surface can be removed; step S5, an antireflection film is deposited on the front surface of the black silicon wafer; and step S6, the back surface of the black silicon wafer is printed with back silver and aluminum paste, drying is performed,then the front surface of the black silicon wafer is printed with front silver, sintering is performed, and the black silicon battery can be obtained.

Description

technical field [0001] The invention belongs to the technical field of solar cells, in particular to a method for preparing a black silicon cell made of RIE texture. Background technique [0002] The preparation process of the black silicon battery in the prior art is to carry out acid texturing, RIE texturing, PN junction diffusion after the texturing repair, and then post-cleaning to remove the phosphosilicate glass layer (PSG) and edge etching, PECVD deposition Anti-reflection film, screen printing and sintering process to complete the preparation of black silicon cells, such as figure 1 shown. [0003] Using the above-mentioned process flow, after RIE texturing, a small textured surface with a depth of about 200-500nm will be formed on the surface of the black silicon wafer, and this depth is equivalent to the current diffusion PN junction depth. In the case of this textured texture, it will affect the diffusion depth of the PN junction, and the acid textured process w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/18
CPCH01L31/182Y02P70/50
Inventor 李化阳张良李良王霞姚玉任海兵
Owner 镇江大全太阳能有限公司