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Processes and systems for purification of 1,3-butadiene

A technology of butadiene and butene, applied in the field of purifying 1,3-butadiene, which can solve problems such as poor performance

Active Publication Date: 2018-06-08
SABIC GLOBAL TECH BV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] A disadvantage of certain methods used to purify crude 1,3-butadiene may be poor performance when the crude 1,3-butadiene contains significant amounts of cis and / or trans-2-butene

Method used

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  • Processes and systems for purification of 1,3-butadiene
  • Processes and systems for purification of 1,3-butadiene
  • Processes and systems for purification of 1,3-butadiene

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0041] The following non-limiting examples are included purely by way of illustration of the presently disclosed subject matter. The following example is using ASPEN Results of steady-state computer simulations performed for versions 2006.5 and V8.2.

[0042] Example 1 - Parameters within an exemplary system

[0043] provided the basis figure 1 system 100 . The parameters of the system 100 are shown in Table 1.

[0044] Table 1

[0045]

[0046]

[0047] The reboiler duty and condenser duty values ​​in Table 1 measure the energy input to the second distillation column 102 (main distillation column). These values ​​demonstrate that systems and methods in accordance with the presently disclosed subject matter can be energy efficient.

Embodiment 2

[0048] Embodiment 2 - the method for purifying 1,3-butadiene

[0049] according to figure 1 A crude 1,3-butadiene stream of 15750 kg / h is fed into the system 100 . The crude 1,3-butadiene stream had the composition shown in Table 2.

[0050] Table 2

[0051]

[0052]

[0053] Crude 1,3-butadiene was supplied in liquid form to the twelfth theoretical plate of the first distillation column 101 having 30 theoretical plates via the 1,3-butadiene feed line 107 . The top vapor stream of the first distillation column 101 is fed into the seventeenth theoretical stage of the second distillation column 102 via the third interconnection 105 . The bottoms stream of the first distillation column 101 is fed into the forty-sixth theoretical plate of the second distillation column 102 via the fourth interconnection 106 . A part of the liquid reflux from the second distillation column 102 is taken from the seventeenth theoretical stage and fed to the first theoretical stage of the fi...

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Abstract

Systems for purifying 1,3-butadiene are provided. An exemplary system includes a first distillation column, a second distillation column, and interconnections between the first and second distillationcolumns. A first interconnection can feed a liquid stream from the second distillation column to the first, while a second interconnection can feed a gas stream from the second distillation column tothe first. Processes for purifying 1,3-butadiene are also provided.

Description

[0001] Cross References to Related Applications [0002] This application claims priority and benefit to US Provisional Application No. 62 / 245,333, filed October 23, 2015. The contents of the cited applications are incorporated by reference into this application. technical field [0003] The presently disclosed subject matter relates to methods and systems for purifying 1,3-butadiene. Background technique [0004] 1,3-Butadiene is a very valuable hydrocarbon. Also known as buta-1,3-diene, erythrene, and vinylethylene, it is the simplest 1,3-diene compound. 1,3-Butadiene can be used as a monomeric starting material for the preparation of various polymers, including synthetic rubber. 1,3-Butadiene can be used as a raw material in the production of adiponitrile. 1,3-Butadiene can also be used as a substrate in certain Diels-Alder reactions. [0005] 1,3-Butadiene can be obtained from different sources, including the dehydrogenation of n-butane and the reaction of ethanol. ...

Claims

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Application Information

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IPC IPC(8): C07C7/04C07C11/167B01D3/00
CPCB01D3/143C07C7/04C07C7/005C07C11/167B01D3/4211B01D2256/24B01D2257/7022
Inventor 拉杜·米哈伊·伊格纳特迈克尔·施勒格尔
Owner SABIC GLOBAL TECH BV
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