A new type of high-performance antibacterial and anti-fog film
An anti-fog film, high-performance technology, applied in the field of plastic packaging, can solve the problems of affecting the antibacterial effect of the film, fogging, fine bacteria reproduction, etc., and achieve excellent anti-fog performance and hydrophilicity, high tensile strength, good The effect of the antibacterial effect
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[0053] In a preferred embodiment, the preparation method of the antibacterial anti-fog film layer resin comprises the steps:
[0054] (1) Put the required amount of organosiloxane in the reaction kettle, add the required amount of solvent, stir and dissolve at 30-35°C, then add the required amount of isocyanate under the atmosphere of nitrogen gas, and react 1 to 3 hours;
[0055] (2) The reaction system in the step (1) is cooled to 25° C., and the required amount of amino nitrogen-containing heterocyclic compound and binary oxime is added, and the reaction is stirred for 1.5 to 2 hours, and then the chloride of the metal ion is added, Stir for 15 to 30 minutes to obtain an antibacterial and antifogging film layer resin.
Embodiment 1
[0060] Embodiment 1 provides a kind of high-performance antibacterial antifog film, described high performance antibacterial antifog film comprises polyolefin resin film layer, antibacterial antifog film layer and printing layer; Described polyolefin resin film layer is sandwiched between printing layer and In the middle of the antibacterial antifog film layer; the thickness of the high performance antibacterial antifog film is 12 microns. The resin selected for the polyolefin resin film layer is polypropylene resin; the thickness of the antibacterial and anti-fog film layer is 6 microns.
[0061] The antibacterial and antifog film layer is prepared from an antibacterial and antifog film layer resin; the raw materials for the preparation of the antibacterial and antifog film layer resin include, in parts by weight, organosiloxane 30, isocyanate 25, amino nitrogen-containing heterocycle Compound 3, binary oxime 3, solvent 150.
[0062] The organosiloxane is 1,3-di(aminopropyl)...
Embodiment 2
[0068] Embodiment 2 provides a kind of high-performance antibacterial antifog film, described high performance antibacterial antifog film comprises polyolefin resin film layer, antibacterial antifog film layer and printing layer; Described polyolefin resin film layer is sandwiched between printing layer and In the middle of the antibacterial antifog film layer; the thickness of the high performance antibacterial antifog film is 18 microns. The resin selected for the polyolefin resin film layer is polypropylene resin; the thickness of the antibacterial and anti-fog film layer is 6 microns.
[0069] The antibacterial and antifog film layer is prepared from an antibacterial and antifog film layer resin; the raw materials for the preparation of the antibacterial and antifog film layer resin include, in parts by weight, organosiloxane 50, isocyanate 35, amino nitrogen-containing heterocycle Compound 5, binary oxime 5, solvent 150.
[0070] The organosiloxane is hydroxyl-terminated...
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