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Retreatment technology for defective wet process black silicon chip

A technology for reprocessing and defective products, applied in the direction of post-processing, post-processing details, final product manufacturing, etc.

Inactive Publication Date: 2018-10-02
GCL POLY ENERGY HLDG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Based on this, it is necessary to address the problem of how to avoid affecting the subsequent use of black silicon wafers, and provide a reprocessing process for defective wet-process black silicon wafers that can avoid affecting the subsequent use of black silicon wafers

Method used

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  • Retreatment technology for defective wet process black silicon chip
  • Retreatment technology for defective wet process black silicon chip
  • Retreatment technology for defective wet process black silicon chip

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0083] The defective product of the wet-process black silicon wafer of Example 1 was characterized by scanning electron microscopy to obtain figure 1 . by figure 1 It can be seen that there are small black spots on the surface of the defective wet-process black silicon wafer of Example 1.

[0084] It is judged that the texture structure of the defective wet-process black silicon wafer of Example 1 is qualified, and step A is adopted. Step A includes the following steps:

[0085] The defective wet-process black silicon wafers are sequentially subjected to alkaline washing, pure water rinsing and acid washing to remove the dirt on the surface of the defective wet-process black silicon wafers to obtain reprocessed wet-process black silicon wafers.

[0086] Among them, the alkaline washing operation is: washing with a KOH solution with a mass concentration of 1.0%, the washing temperature is 25°C, and the washing time is 30s.

[0087] Among them, the pure water rinsing time is 20s.

[008...

Embodiment 2

[0092] The defective product of the wet-process black silicon wafer of Example 2 was characterized by scanning electron microscopy to obtain image 3 . by image 3 It can be seen that there is a watermark on the surface of the defective wet-process black silicon wafer of Example 2.

[0093] It is judged that the texture structure of the defective wet black silicon wafer of Example 2 is qualified, and step A is adopted. Step A includes the following steps:

[0094] The defective wet-process black silicon wafers are sequentially subjected to alkaline washing, pure water rinsing and acid washing to remove the dirt on the surface of the defective wet-process black silicon wafers to obtain reprocessed wet-process black silicon wafers.

[0095] Among them, the alkaline washing operation is: cleaning with a NaOH solution with a mass concentration of 0.5%, the cleaning temperature is 25°C, and the cleaning time is 15s.

[0096] Among them, the pure water rinsing time is 30s.

[0097] Among th...

Embodiment 3

[0101] The defective product of the wet-process black silicon wafer of Example 3 was characterized by scanning electron microscopy to obtain Figure 5 . by Figure 5 It can be seen that the surface pores of the defective wet-process black silicon wafer of Example 3 are smaller than those of the normal suede surface, and the surface of the defective wet-process black silicon wafer of Example 3 has more deep holes, indicating its The reflectivity is low.

[0102] To determine that the suede structure of the defective wet black silicon wafer is unqualified, step B is adopted. Step B includes the following steps:

[0103] The defective wet-process black silicon wafers are sequentially subjected to alkali polishing, metal deposition, metal-induced catalysis, metal removal, hole expansion, alkali washing, and pickling to obtain re-processed wet-process black silicon wafers.

[0104] Among them, the operation of alkali polishing is: cleaning with a KOH solution with a mass concentration o...

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Abstract

The invention relates to a retreatment technology for a defective wet process black silicon chip. The technology includes the steps of: judging whether the textured structure of a defective wet process black silicon chip is qualified, if the textured structure is qualified, adopting step A; if the textured structure is unqualified, adopting step B; wherein, the step A includes the: conducting alkali washing, pure water rinsing and acid pickling on the defective wet process black silicon chip in order to remove dirt on the surface of the defective wet process black silicon chip, thus obtainingthe retreated wet process black silicon chip; and the step B includes: carrying out alkali polishing, metal deposition, metal-induced catalysis, metal removal, pore enlargement, alkali washing and acid pickling on the defective wet process black silicon chip in order, thus obtaining the retreated wet process black silicon chip. The wet process black silicon chip treated by the retreatment technology for a defective wet process black silicon chip provided by the invention has little weight loss, and can avoid influence on the follow-up use of the black silicon chip.

Description

Technical field [0001] The invention relates to the technical field of silicon wafer manufacturing, in particular to a process for reprocessing defective wet black silicon wafers. Background technique [0002] Black silicon technology is widely favored by polycrystalline battery manufacturers due to its good light trapping effect, can greatly improve the conversion efficiency of polycrystalline silicon wafers, and can solve the suede problem of diamond wire-cut polycrystalline silicon wafers. The mainstream of black silicon technology is the ion reaction method of dry texturing and the metal-catalyzed chemical corrosion method of wet texturing. However, wet-process black silicon requires the use of trough equipment, and the reaction is a complex and chained multi-channel chemical reaction. It is difficult to control the process stability. In the actual production process, the primary yield is low. Therefore, it is necessary to reprocess the defective products obtained by the wet...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C30B29/06C30B33/10H01L31/0236H01L31/18
CPCC30B29/06C30B33/10H01L31/02366H01L31/1804Y02P70/50
Inventor 吉鑫阮文娟宫龙飞
Owner GCL POLY ENERGY HLDG