Fine adjustment combined splicing type building decorative sheet and preparation method thereof
A decorative board and composite thermal insulation technology, which is applied in the field of flame-retardant materials, can solve the problems of adding flame-retardant materials, adding auxiliary treatment, surface precipitation, etc., and achieve the effects of improving fire-proof and flame-retardant performance, increasing packing density, and low thermal seepage coefficient
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[0042] A method for preparing a fireproof and flame-retardant composite thermal insulation decorative board for an exterior wall comprises the following steps:
[0043] 1) Preparation of modified expandable graphite: use flake graphite, hydrogen peroxide, and fuming nitric acid, and stir rapidly in an ice-water bath until the reaction becomes gentle. ≥ 99.5% acetic acid solution with constant stirring, react for 60 minutes, wash with water, filter with suction, and dry to obtain sulfur-free and ash-free modified expandable graphite with an expansion volume of 300-350ml / g, of which flake graphite, fuming nitric acid, hydrogen peroxide , the ratio of acetic acid is 5(g): 12(ml): 1(ml): 5(ml);
[0044] 2) Preparation of modified expandable polystyrene: water, polystyrene masterbatch, sodium butylnaphthalene sulfonate, polyvinyl alcohol, butane, dicumyl peroxide, tetrabromobutane, antioxidant The agent BHT is mixed according to the mass ratio of 1.6:1:0.03:0.002:0.1:0.008:0.013:0...
Embodiment 2
[0053] 1) Preparation of modified expandable graphite: add KMnO4 to flake graphite according to the ratio of mass ratio flake graphite: KMnO4 = 1:0.3, stir evenly, add 70% HClO3 solution, and maintain the ratio of solid to liquid at 1:4 Keep stirring at 35°C for 90 minutes, wash with water, filter with suction, and dry to obtain modified expandable graphite with an expansion volume of 550ml / g2) Preparation of modified expandable polystyrene: mix water, polystyrene Masterbatch, sodium butylnaphthalene sulfonate, polyvinyl alcohol, butane, dicumyl peroxide, hexabromocyclododecane, and antioxidant BHT in a mass ratio of 1.6:1:0.03:0.002:0.1:0.008: 0.02: 0.003 mixing, impregnation reaction at 72±2°C, pressure 0.9±0.1MPa, 100r / min speed for 10h can be obtained;
[0054] 3) Preparation of flame-retardant insulation layer: feed the modified expandable polystyrene obtained in step 2) into a pre-expansion machine with a steam pressure of 0.2 MPa and preheated to 70°C for pre-foaming. ...
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