Labeling complex and its preparation method, kit, application and detection system
A complex and detection kit technology, applied in the field of detection systems, can solve the problems of increasing reagent components, affecting immunological activity, affecting the stability and sensitivity of markers, and achieving the effect of improving sensitivity
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preparation example Construction
[0062] According to another aspect of the present invention, a method for preparing the above-mentioned labeling complex is provided. The preparation method comprises the following steps: performing a coupling reaction on a labeled protein with a functional group on the surface and an antigen to obtain an intermediate product of the labeling complex; performing a coupling reaction on the signal generating substance and the intermediate product of the labeling complex, and separating, purifying and removing Unbound material yields labeled complexes.
[0063] Among them, the functional groups on the surface of the labeled protein include but are not limited to carboxyl (-COOH), amino (-NH 2 ), hydroxyl group (-OH), mercapto group (-SH), aldehyde group (-CHO), sugar group (-C=O) and imidazole group, functional group and free amino group, carboxyl group, mercapto group, aldehyde group or Glycosyl coupling (since the present invention has defined that the functional groups on the ...
Embodiment approach
[0064] According to a typical embodiment of the present invention, the specific steps of the preparation method are as follows: A. Select an appropriate method according to the coupling functional group to perform a coupling reaction between the labeled protein and the antigen; B. Remove unbound substances to obtain the intermediate product of the labeled complex ; C. Selecting an appropriate method according to the coupling functional group to perform a coupling reaction between the signal generating substance and the intermediate product of the labeling complex; D. Removing unbound substances to obtain the final labeling complex.
[0065] Select an appropriate method for the signal-generating substance according to the coupling functional group to perform a coupling reaction with the intermediate product of the labeling complex. The methods used for the coupling reaction include but are not limited to the mixed anhydride method, carbodiimide method, glutaraldehyde method, glut...
Embodiment 1
[0133] 1) Weigh 5 mg of HRP (M=44000) and dissolve it in 1 mL of distilled water (5 mg / mL).
[0134] 2) Add 0.5mL freshly prepared 0.06M NaIO to the above solution 4 (M=213.89) solution, mix well, and stand at 4°C in the dark for 30 minutes.
[0135] 3) Add 0.5mL 0.16M ethylene glycol (remove excess NaIO 4 ), mix well, and stand at room temperature for 30min.
[0136] 4) 1mg HIV-1 recombinant antigen (2mg / mL) was dialyzed with 0.05M pH 9.5 carbonate buffer at 4°C for 2h, then immediately added NaIO4 Oxidized HRP 1mg, stirred gently at room temperature for 2h in the dark.
[0137] 5) Add 50 μL of newly prepared 2mg / mL NaBH 4 (M=37.83) solution, after mixing, let stand at 4°C for 2h.
[0138] 6) Put the above solution into a dialysis bag, and dialyze against 0.01M pH7.4PBS at 4°C overnight.
[0139] 7) Choose a dialysis bag with a cut-off of 3500, measure the appropriate size, tie one end tightly after wetting, and test for leaks with purified water 3 times (it is better if...
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