Polarizing film, polarizing film with pressure-sensitive adhesive layer, process for producing polarizing film, and image display device
An adhesive layer and polarizing film technology, which is applied to the polarizing film with adhesive layer, image display device, and the manufacturing field of the above-mentioned polarizing film, can solve the problem of insufficient thinning of the polarizing film, etc., and achieve high optical reliability. , Suppressing the degradation of optical properties, suppressing the effect of nanoslits
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manufacture example 1
[0211] Production example 1 (production of polarizer A0)
[0212] For substrates of amorphous isophthalic acid-copolyethylene terephthalate (IPA-co-PET) film (thickness: 100 μm) with a water absorption rate of 0.75% and a glass transition temperature (Tg) of 75°C Corona treatment was performed on one side, and the corona treatment surface was coated with polyvinyl alcohol (polymerization degree: 4200, saponification degree: 99.2 mol%) and acetoacetyl modified PVA ( Degree of polymerization: 1200, degree of acetoacetyl group modification: 4.6%, degree of saponification: 99.0 mol% or more, trade name: Gohsefimer Z200, manufactured by Nippon Synthetic Chemical Industry Co., Ltd.) and dried to form a PVA with a thickness of 11 μm Resin layer, a laminated body was produced.
[0213] The obtained laminate was stretched 2.0 times in the longitudinal direction (longitudinal direction) in an oven at 120° C. between rollers having different circumferential speeds, and free-end uniaxial...
manufacture example 2~8
[0220] Production Examples 2-8 (Production of Polarizers A1-A7)
[0221] Except having changed the manufacturing conditions as shown in Table 1, it carried out similarly to the manufacture example 1, and produced the polarizers A1-A7. Table 1 shows the thicknesses, optical properties (single transmittance, degree of polarization), and boric acid content of polarizers A1 to A7.
[0222]
manufacture example 9
[0224] (Preparation of Monomer Emulsion)
[0225] The monomer components listed in Table 2 were added to the container and mixed. Next, 12 parts of AQUALON HS-10 (manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd.) and 127 parts of ion-exchanged water were added as a reactive surfactant to 200 parts of the prepared monomer components. manufactured by Kagaku Kogyo Co., Ltd.) was stirred at 6000 (rpm) for 5 minutes to perform forced emulsification to prepare a monomer emulsion (A-1).
[0226] In another container, 12 parts of AQUALON HS-10 (manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd.) and 382 parts of ion-exchanged water were added as a reactive surfactant to 600 parts of the monomer component prepared in the above ratio, and used It stirred at 6000 (rpm) for 5 minutes with a mass mixer (manufactured by Tokukuki Kagaku Kogyo Co., Ltd.), and forced emulsification was carried out to prepare a monomer emulsion (A-2).
[0227](Preparation of transparent resin layer ...
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