Method for improving organic matter adsorbing performance of activated carbon, product prepared thereby and application thereof

An activated carbon adsorption, organic matter technology, applied in chemical instruments and methods, inorganic chemistry, carbon compounds, etc., can solve the problems of increasing the cost of the preparation process, being difficult to be effectively controlled, and the process of surface chemical modification is cumbersome.

Active Publication Date: 2018-12-14
SHENZHEN GLOBAL GREENLAND NEW MATERIALS CO LTD
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  • Abstract
  • Description
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Problems solved by technology

There are two main ways to produce functional groups on the surface of activated carbon: one is the residue left by incomplete carbonization during the preparation of activated carbon, which is often unavoidable and difficult to be effectively controlled; the other is to use modifiers to modify the surface of activated carbon. However, the existing surface chemical modifi

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  • Method for improving organic matter adsorbing performance of activated carbon, product prepared thereby and application thereof

Examples

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preparation example Construction

[0067] The preparation method of the present invention will be further described in detail in conjunction with specific examples below. It should be understood that the following examples are only for illustrating and explaining the present invention, and should not be construed as limiting the protection scope of the present invention. All technologies realized based on the above contents of the present invention are covered within the scope of protection intended by the present invention.

[0068] The experimental methods used in the following examples are conventional methods unless otherwise specified; the reagents and materials used in the following examples can be obtained from commercial sources unless otherwise specified.

Embodiment 1

[0070] 1.1 Preparation of spherical polymer

[0071] Under argon protection, add 0.011mol 2,2 bis(trifluoromethyl)diaminobenzidine to 14.94g polar solvent N,N-dimethylacetamide in a 250mL three-necked flask equipped with mechanical stirring , after stirring to completely dissolve the diamine, add 0.01mol 3,3',4,4'-diphenyl ether tetracarboxylic dianhydride to the reaction system, react for 4 hours, add 0.0005mol norbornene anhydride, and continue the reaction for 24 hours to obtain Polyamic acid soluble.

[0072] The mixture of 2.26g triethylamine and 0.22g pyridine is used as a catalyst, the catalyst is added to the polyamic acid solution, and 9.24g dehydrating agent acetic anhydride is added, and the reaction is continued for 24 hours to obtain a polyimide prepolymer solution, and then the polyimide After diluting the imide prepolymer solution with the polar solvent N-methylpyrrolidone to an equal volume, drop it into methanol to obtain a precipitate, wash and filter the pr...

Embodiment 2

[0084] 2.1 step is the same as 1.1 in embodiment 1

[0085] 2.2 Carbonization

[0086] Put the spherical polymer in step 2.1 into an acid-resistant and alkali-resistant rotary tube furnace, and carry out the following carbonization treatment at a heating rate of 2°C / min under a nitrogen atmosphere and an ammonia atmosphere (flow ratio: 4:1):

[0087] Heat to 110°C and stay for 100 minutes;

[0088] Heat to 500°C and stay for 400 minutes;

[0089]Continue to heat up at a heating rate of 3°C / min, and carry out carbonization treatment in a mixed atmosphere with a volume percentage of 3% of oxygen. At this time, because ammonia gas is generated during the carbonization process of the spherical polymer, the amount of ammonia gas introduced is reduced to The flow ratio is 8:1:

[0090] Heat to 650°C and stay for 360 minutes;

[0091] Heat to 920°C and hold for 260 minutes. Lower the temperature to obtain carbonized products.

[0092] 2.3 Activation

[0093] In a rotary tube f...

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Abstract

The invention provides a method for improving the organic matter adsorbing performance of activated carbon, a product prepared thereby and the application thereof. The activated carbon prepared by themethod can effectively absorb organic matters; in the preparation process of the activated carbon, a technology is simple, modification treatment to the activated carbon can be completed through adjustment of the carbonization temperature and the carbonization atmosphere, and subsequent reprocessing is not required, so that by the technological process, the cost can be greatly reduced; in the modification treatment, alkaline gas generated by a spherical polymer itself is further used as a modifier, so that reasonable utilization of energy is achieved; in a manner in which the preparation andthe modification are carried out simultaneously, microporous structures on the surface of the activated carbon can be greatly increased and the specific surface area of the activated carbon is increased; compared with a treatment method of preparing the spherical activated carbon first and then modifying, the method provided by the invention has the advantages as follows: the preparation process is simple, and the prepared activated carbon has stronger adsorption capacity and has a wide application prospect.

Description

technical field [0001] The invention belongs to the technical field of activated carbon preparation, and in particular relates to a method for improving the performance of activated carbon for absorbing organic matter and the prepared product and use thereof. Background technique [0002] As a commonly used adsorbent, activated carbon has a wide range of applications. In order to obtain activated carbon with higher adsorption efficiency or better adsorption selectivity, it is often necessary to modify the surface functional groups. There are two main ways to generate functional groups on the surface of activated carbon: one is the residue left by incomplete carbonization during the preparation of activated carbon, which is often inevitable and difficult to be effectively controlled; the other is to use modifiers to modify the surface of activated carbon. However, the existing surface chemical modification method is cumbersome and requires the use of a large amount of oxidiz...

Claims

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Application Information

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IPC IPC(8): C01B32/318C01B32/336C08G73/10C08J3/12C08L79/08B01J20/20B01J20/30
CPCB01J20/20C01B32/318C01B32/336C08G73/1071C08J3/12C08J2379/08
Inventor 常明珠
Owner SHENZHEN GLOBAL GREENLAND NEW MATERIALS CO LTD
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